<div><strong>Output Type: </strong>Exploring for the Future Extended Abstract</div><div><br></div><div><strong>Short Abstract: </strong>Groundwater geochemistry is an important and often under-appreciated medium to understand geology below surface and is a valuable tool as part of a regional mineral exploration program. This study presents an assessment of hydrogeochemical results from the Curnamona and Mundi region with respect to their insights into mineral prospectivity and characterisation of groundwater baselines. The work is a collaboration with the Mineral Exploration Cooperative Research Centre (MinEx CRC), the Geological Survey of New South Wales and the Geological Survey of South Australia as part of Geoscience Australia’s Exploring for the Future program. It combines new and legacy groundwater chemistry from 297 samples to identify multiple elevated multi-element anomalies (Ag, Pb, Cd) and signatures of sulfide mineralisation (d34S and sulfur excess), which are interpreted as potential features from subsurface Broken Hill Type mineralisation (Pb-Zn-Ag). Additional multi-element anomalies (Cu, Mo, Co, Au) may be attributable to Cu-Au, Cu-Mo and Au mineralisation. We then apply hierarchical cluster analysis to understand sample hydrostratigraphy and characterise robust hydrogeochemical baselines for the major aquifer systems in the region. This reveals that the majority of anomalies are restricted to groundwaters derived from basement fractured rock aquifer systems, with a couple anomalies observed in the Lake Eyre Basin cover, which helps narrow the search-space for future groundwater-based mineral exploration in this region (to prioritise these aquifers and anomalies). In addition, we demonstrate the capability of these local hydrogeochemical baselines to support more sensitive resolution of hydrogeochemical anomalies relating to mineralisation, as well as reveal hydrogeological processes such as mixing.</div><div><br></div><div><strong>Citation: </strong>Reid, N., Schroder, I., Thorne, R., Folkes, C., Hore, S., Eastlake, M., Petts, A., Evans, T., Fabris, A., Pinchand, T., Henne A., & Palombi, B.R., 2024. Hydrogeochemistry of the Curnamona and Mundi region. In: Czarnota, K. (ed.) Exploring for the Future: Extended Abstracts. Geoscience Australia, Canberra. https://doi.org/10.26186/149509</div>

<div>NDI Carrara 1 is a deep stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first test of the Carrara Sub-Basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) recently acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1100 m of Proterozoic sedimentary rocks uncomformably overlain by 630 m of Cambrian Georgina Basin carbonates. A comprehensive geochemical program designed to provide information about the region’s resource potential was carried out on samples collected at up to 4 meter intervals. This report presents data from Rock-Eval pyrolysis analyses undertaken by Geoscience Australia on selected rock samples to establish their total organic carbon content, hydrocarbon-generating potential and thermal maturity.</div>

A comprehensive geochemical program was carried out on rock samples collected in the NDI Carrara 1 drill hole, the first stratigraphic test of the newly discovered Carrara Sub-basin located in the South Nicholson region of northern Australia. The drill hole recovered continuous core from 284 m to total depth at 1750 m and intersected approximately 1120 m of Proterozoic sedimentary rocks, unconformably overlain by 630 m of Cambrian Georgina Basin carbonate-rich rocks. Total organic carbon (TOC) contents from Rock-Eval pyrolysis highlight the potential for several thick black shales to be a source of petroleum for conventional and unconventional plays. Cambrian rocks contain an organic-rich section with TOC contents of up to 4.7 wt.% and excellent oil-generating potential. The Proterozoic section is overmature for oil generation but mature for gas generation, with potential for generating gas in carbonaceous mudstones showing TOC contents up to 5.5 wt.% between 680 and 725 m depth. A sustained release of methane (up to 2%) recorded during drilling from 1150 to 1500 m suggests potential for an unconventional gas system in the Proterozoic rocks from 950 to 1415 m depth, which exhibit favourable organic richness and thermal maturity. The Proterozoic rocks, which are comparable in age to the sediment-hosted deposits of the Century Mine, contain local occurrences of lead, zinc and copper sulfide minerals providing hints of mineralisation. The combined geochemical results offer the promise of a potential new resource province in northern Australia. <b>Citation:</b> E. Grosjean, A.J.M. Jarrett, C.J. Boreham, L. Wang, L. Johnson, J.M. Hope, P. Ranasinghe, J.J. Brocks, A.H.E. Bailey, G.A. Butcher, C.J. Carson, Resource potential of the Proterozoic–Paleozoic Carrara depocentre, South Nicholson region, Australia: Insights from stratigraphic drilling, <i>Organic Geochemistry</i>, Volume 186, 2023, 104688, ISSN 0146-6380, DOI: https://doi.org/10.1016/j.orggeochem.2023.104688.

<div>The South Nicholson National Drilling Initiative (NDI) Carrara 1 stratigraphic drill hole was completed in late 2020, as a collaboration between Geoscience Australia, the Northern Territory Geological Survey (NTGS), and the MinEx CRC. The drilling aimed to gather new subsurface data on the potential mineral and energy resources in the newly identified Carrara Sub-basin. NDI Carrara 1 is located in the eastern Northern Territory, on the western flanks of the Carrara Sub-basin on the South Nicholson Seismic line, reaching a total depth of 1751 m, intersecting ca. 630 m of Cambrian Georgina Basin overlying ca. 1100 m of Proterozoic carbonates, black shales and minor siliciclastics (https://portal.ga.gov.au/bhcr/minerals/648482).</div><div>&nbsp;</div><div>Following a public data release of the borehole completion report, CSIRO was contracted by Geoscience Australia (GA) under the Exploring for the Future program to analyse samples from NDI Carrara 1 for quantitative bulk and clay fraction analysis. This report presents results for quantitative bulk and clay (<2 µm) fraction analysis by X-ray powder diffraction (XRD) on 32 bulk core samples from the NDI Carrara 1. Samples were prepared and analysed at the CSIRO’s Waite Laboratories in South Australia.</div><div><br></div>

<div>This study was commissioned by Geoscience Australia (GA) to produce a report on seal capacity of select samples from the deep stratigraphic hole NDI Carrara 1, located in the Proterozoic Carrara Sub-basin in the Northern Territory. Plugs were taken from depths of interest and analysed via mercury injection capillary pressure testing. Results were provided as two reports, Part A and Part B and demonstrate that the analysed samples are capable of sealing very large columns of both methane and carbon dioxide.</div>

<div>NDI Carrara 1 is a deep stratigraphic borehole that was drilled in 2020 under the MinEx CRC’s National Drilling Initiative (NDI) program in collaboration with Geoscience Australia and the Northern Territory Geological Survey. NDI Carrara 1 is the first stratigraphic test of the recently described Carrara Sub-basin, a Proterozoic aged depocentre located in the South Nicholson region of northwest Queensland and the Northern Territory. The borehole was drilled to a total depth of 1751 m and penetrated a succession of Cambrian aged Georgina Basin carbonate and siliciclastic rocks that unconformably overly a thick succession of Proterozoic age siliciclastic and carbonate-rich sediments. Although drilled on the western flank of the Carrara Sub-basin, NDI Carrara 1 did not penetrate to basement. Interpretation of the L210 deep-crustal seismic survey suggests that further Proterozoic sedimentary packages known from the northern Lawn Hill Platform in northwest Queensland are likely to be found underlying the succession intersected in NDI Carrara 1. The borehole was continuously cored from 283 m to total depth, and an extensive suite of wireline logs was acquired. Geoscience Australia and partners have undertaken an extensive analytical program to understand the depositional, structural, and diagenetic history of the sediments intersected in NDI Carrara 1. This program includes a targeted geomechanical study that aims to characterise the physical properties of these Proterozoic rocks through laboratory analysis of core samples, the results of which are summarised in this data release.</div><div><br></div><div>This data release provides data from new unconfined compressive strength (UCS), single-stage triaxial testing, and laboratory ultrasonic testing for 36 sample plugs from NDI Carrara 1. These tests were performed at the CSIRO Geomechanics and Geophysics Laboratory in Perth, during January to June 2022. The full results as provided by CSIRO to Geoscience Australia are provided as an attachment to this document.&nbsp;</div>

<div>NDI Carrara 1 is a deep stratigraphic borehole that was drilled in 2020 under the MinEx CRC’s National Drilling Initiative (NDI) program in collaboration with Geoscience Australia and the Northern Territory Geological Survey. NDI Carrara 1 is the first stratigraphic test of the recently described Carrara Sub-basin, a Proterozoic aged depocentre located in the South Nicholson region of northwest Queensland and the Northern Territory. The borehole was drilled to a total depth of 1751 m and penetrated a succession of Cambrian aged Georgina Basin carbonate and siliciclastic rocks that unconformably overly a thick succession of Proterozoic age siliciclastic and carbonate-rich sediments. Although drilled on the western flank of the Carrara Sub-basin, NDI Carrara 1 did not penetrate to basement. Interpretation of the L210 deep-crustal seismic survey suggests that further Proterozoic sedimentary packages known from the northern Lawn Hill Platform in northwest Queensland are likely to be found underlying the succession intersected in NDI Carrara 1. The borehole was continuously cored from 283 m to total depth, and an extensive suite of wireline logs was acquired. Geoscience Australia and partners have undertaken an extensive analytical program to understand the depositional, structural, and diagenetic history of the sediments intersected in NDI Carrara 1. This program includes a targeted petrophysical study that aims to characterise the physical properties of these Proterozoic rocks through laboratory analysis of core samples, the results of which are summarised in this data release.</div><div><br></div><div>This data release provides data from new X-ray Computerised Tomography (XCT) scanning and gas porosity and permeability testing for 32 samples from NDI Carrara 1. Additional low permeability tests were undertaken on select samples that were identified as being ultra-tight (permeability <1 μD). These tests were performed at the CSIRO Geomechanics and Geophysics Laboratory in Perth, during January to June 2022. The full results as provided by CSIRO to Geoscience Australia are provided as an attachment to this document.&nbsp;</div>

<div>This report presents thermal property data (thermal conductivity data, calculated heat production data, and calculated surface heat flow) from the deep (1751 m) stratigraphic drill hole, NDI Carrara 1. Thermal conductivity analyses were undertaken at the University of Melbourne. Heat production values were calculated from existing whole rock geochemical data. Surface heat flow was determined using the laboratory thermal conductivity data together with in situ downhole temperature data collected previously.</div>

<div>This Record presents new zircon U-Pb geochronological data, obtained via Sensitive High Resolution Ion Microprobe (SHRIMP), for 12 samples of igneous rocks from central and southern New South Wales, as part of an ongoing Geochronology Project conducted by the Geological Survey of New South Wales (GSNSW) and Geoscience Australia (GA) under a National Collaborative Framework agreement. Eight samples were selected to better understand the geological evolution and mineralisation history of areas prioritised for investigation by the MinEx Co-operative Research Centre (MinEx CRC) under its National Drilling Initiative (NDI) program. Three samples are from the northern Molong Volcanic Belt east of Dubbo (‘MXDU’), and five are from the eastern Lachlan Orogen near Forbes (‘MXFO’). The remaining four samples are from the central Lachlan Orogen in southern NSW, in support of GSNSW’s East Riverina mapping program (‘ERIV’). The results herein correspond to U-Pb SHRIMP zircon analyses undertaken by the GSNSW-GA Geochronology Project during the July 2020–June 2021 reporting period. All quoted uncertainties are 95% confidence intervals.</div> <b>Bibliographic reference: </b> Jones, S.L., Bodorkos, S., Eastlake, M.A.S., Campbell, L.M., Hughes, K.S., Blevin, P.L. and Fitzherbert, J.A., 2023. <i>New SHRIMP U-Pb zircon ages from the Lachlan Orogen, NSW: Dubbo, Forbes and East Riverina areas, July 2020–June 2021. </i>Record 2023/36, Geoscience Australia, Canberra. Report GS2023/0017, Geological Survey of New South Wales, Maitland. https://doi.org/10.26186/147971

<div>The Carrara Sub-basin, discovered in 2017 based on interpretation of 2D deep seismic surveys acquired by Geoscience Australia, is a large sedimentary depocentre in the South Nicholson region straddling the Northern Territory and Queensland. It was interpreted to contain up to 8 km of Paleoproterozoic to Cambrian rocks including stratigraphic equivalents to the Isa Superbasin, South Nicholson Group and Georgina Basin. In order to validate these stratigraphic interpretations and assess the resource prospectivity of the Carrara Sub-basin, the South Nicholson National Drilling Initiative (NDI) Carrara 1 stratigraphic drill hole was completed in late 2020 as a collaboration between the MinEx Cooperative Research Centre, Geoscience Australia and the Northern Territory Geological Survey. NDI Carrara 1 was drilled on the western flanks of the Carrara Sub-basin and reached a total depth of 1751&nbsp;m, intersecting ca. 630&nbsp;m of Cambrian Georgina Basin overlying ca. 1100&nbsp;m of Proterozoic carbonates, black shales and minor siliciclastics. More than 400 NDI Carrara&nbsp;1 physical samples were analysed as part of an extensive geochemical program, including Rock-Eval pyrolysis and compositional analyses of hydrocarbon shows, whose results and implications for energy prospectivity are summarised here.</div> This Abstract was submitted/presented to the 2022 Australian Organic Geochemistry Conference 27-29 November (https://events.csiro.au/Events/2022/October/5/Australian-Organic-Geochemistry-Conference)