The purpose of this study was to constrain the processes of Paleoproterozoic crustmantle evolution by investigating the Lu-Hf, Sm-Nd and oxygen isotope systematics of igneous rocks of the Lamboo Province of the Halls Creek and King Leopold Orogens, in the Kimberley region of Western Australia. The specific objectives were to: 1. Ascertain the nature of the source rocks of the granites, and to test whether granite formation involved the reworking of ancient meta-igneous protoliths in an intra-plate environment or complex crust-mantle interaction processes typical of modern plate tectonic settings; 2. Use data from granite-hosted zircons to quantify the proportion of new crust formed during discrete magmatic events, and to link this with the longer-term record of crustal evolution preserved by detrital zircons, and 3. Constrain the tectonic setting of the Lamboo Province, and thus the geodynamic controls on global crustal growth in this key time period.

The values and distribution patterns of the strontium (Sr) isotope ratio 87Sr/86Sr in Earth surface materials is of use in the geological, environmental and social sciences. Ultimately, the 87Sr/86Sr ratio of any mineral or biological material reflects its value in the rock that is the parent material to the local soil and everything that lives in and on it. In Australia, there are few large-scale surveys of 87Sr/86Sr available, and here we report on a new, low-density dataset using 112 catchment outlet (floodplain) sediment samples covering 529,000 km2 of inland southeastern Australia (South Australia, New South Wales, Victoria). The coarse (<2 mm) fraction of bottom sediment samples (depth ~0.6-0.8 m) from the National Geochemical Survey of Australia were fully digested before Sr separation by chromatography and 87Sr/86Sr determination by multicollector-inductively coupled plasma-mass spectrometry. The results show a wide range of 87Sr/86Sr values from a minimum of 0.7089 to a maximum of 0.7511 (range 0.0422). The median 87Sr/86Sr (± robust standard deviation) is 0.7199 (± 0.0112), and the mean (± standard deviation) is 0.7220 (± 0.0106). The spatial patterns of the Sr isoscape observed are described and attributed to various geological sources and processes. Of note are the elevated (radiogenic) values (≥~0.7270; top quartile) contributed by (1) the Palaeozoic sedimentary country rock and (mostly felsic) igneous intrusions of the Lachlan geological region to the east of the study area; (2) the Palaeoproterozoic metamorphic rocks of the central Broken Hill region; both these sources contribute fluvial sediments into the study area; and (3) the Proterozoic to Palaeozoic rocks of the Kanmantoo, Adelaide, Gawler and Painter geological regions to the west of the area; these sources contribute radiogenic material to the region mostly by aeolian processes. Regions of low 87Sr/86Sr (≤~0.7130; bottom quartile) belong mainly to (1) a few central Murray Basin catchments; (2) some Darling Basin catchments in the northeast; and (3) a few Eromanga geological region-influenced catchments in the northwest of the study area. The new spatial dataset is publicly available through the Geoscience Australia portal (https://portal.ga.gov.au/restore/cd686f2d-c87b-41b8-8c4b-ca8af531ae7e).

Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g., recognising geological provinces, studying geological processes) as well in archaeological (e.g., informing on past human migrations), palaeontological/ecological (e.g., investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g., validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa). The initial study targeted the northern parts of the Northern Territory and Queensland in Australia. The samples were taken from a depth of ~60-80 cm depth in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse grain-size fraction (<2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Preliminary results demonstrate a wide range of strontium isotopic values (0.7048 < 87Sr/86Sr < 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and gradients), large-scale (>100 km) patterns that appears to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a >500 km-long northwest-southeast trending low anomaly (87Sr/86Sr < 0.7182). Where carbonate or mafic igneous rocks dominate, a low to moderate strontium isotope signature is observed. In proximity to the outcropping Proterozoic metamorphic provinces of the Tennant, McArthur, Murphy and Mount Isa geological regions, high 87Sr/86Sr values (> 0.7655) are observed. A potential link between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g., weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations.

The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the Offshore Energy Systems Section. This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and attract exploration investment to Australia. The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018), Dorado 1 (2018) and Dorado 2–3 (2019) in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata (Grosjean et al., 2021; Rollet et al., 2019). As part of this program, a range of organic geochemical analyses were acquired on petroleum fluids from the Dorado 1 and Roc 2 wells with these data released in this report.

Paleoproterozoic arc and backarc assemblages accreted to the south Laurentian margin between 1800 Ma and 1600 Ma, and previously thought to be indigenous to North America, more likely represent fragments of a dismembered marginal sea developed outboard of the formerly opposing Australian-Antarctic plate. Fugitive elements of this arc-backarc system in North America share a common geological record with their left-behind Australia-Antarctic counterparts, including discrete peaks in tectonic and/or magmatic activity at 1780 Ma, 1760 Ma, 1740 Ma, 1710-1705 Ma, 1690-1670 Ma, 1650 Ma and 1620 Ma. Subduction rollback, ocean basin closure and the arrival of Laurentia at the Australian-Antarctic convergent margin first led to arc-continent collision at 1650-1640 Ma and then continent-continent collision by 1620 Ma as the last vestiges of the backarc basin collapsed. Collision induced obduction and transfer of the arc and more outboard parts of the Australian-Antarctic backarc basin onto the Laurentian margin where they remained following later breakup of the Neoproterozoic Rodinia supercontinent. North American felsic rocks generally yield Nd depleted mantle model ages consistent with arc and backarc assemblages built on early Paleoproterozoic Australian crust as opposed to older Archean basement making up the now underlying Wyoming and Superior cratons. Appeared in Lithosphere (2019) 11 (4): 551–559, June 10, 2019.

<p>The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the North West Margin Energy Studies Section (NWMES). This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and attract exploration investment to Australia. <p>The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018) and Dorado 1 (2018) in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata. The current study aims to better understand this new petroleum system and establish its extent. <p>As part of this program, compositional and isotopic analyses were undertaken by Geoscience Australia on gas samples from the wells Roc 1 and Roc 2 and data from these analyses are released in this dataset.

Radiogenic isotopes decay at known rates and can be used to interpret ages for minerals, rocks and geologic processes. Different isotopic systems provide information related to different time periods and geologic processes, systems include: U-Pb and Ar/Ar, Sm-Nd, Pb-Pb, Lu-Hf, Rb-Sr and Re-Os isotopes. The GEOCHRON database stores full analytical U-Pb age data from Geoscience Australia's (GA) Sensitive High Resolution Ion Micro-Probe (SHRIMP) program. The ISOTOPE database is designed to expand GA's ability to deliver isotopic datasets, and stores compiled age and isotopic data from a range of published and unpublished (GA and non-GA) sources. OZCHRON is a depreciated predecessor to GEOCHRON and ISOTOPE, the information once available in OZCHRON is in the process of migration to the two current databases. The ISOTOPE compilation includes sample and bibliographic links through the A, FGDM, and GEOREF databases. The data structure currently supports summary ages (e.g., U-Pb and Ar/Ar) through the INTERPRETED_AGES tables, as well as extended system-specific tables for Sm-Nd, Pb-Pb, Lu-Hf and O- isotopes. The data structure is designed to be extensible to adapt to evolving requirements for the storage of isotopic data. ISOTOPE and the data holdings were initially developed as part of the Exploring for the Future (EFTF) program - particularly to support the delivery of an Isotopic Atlas of Australia. During development of ISOTOPE, some key considerations in compiling and storing diverse, multi-purpose isotopic datasets were developed: 1) Improved sample characterisation and bibliographic links. Often, the usefulness of an isotopic dataset is limited by the metadata available for the parent sample. Better harvesting of fundamental sample data (and better integration with related national datasets such as Australian Geological Provinces and the Australian Stratigraphic Units Database) simplifies the process of filtering an isotopic data compilation using spatial, geological and bibliographic criteria, as well as facilitating 'audits' targeting missing isotopic data. 2) Generalised, extensible structures for isotopic data. The need for system-specific tables for isotopic analyses does not preclude the development of generalised data-structures that reflect universal relationships. GA has modelled relational tables linking system-specific Sessions, Analyses, and interpreted data-Groups, which has proven adequate for all of the Isotopic Atlas layers developed thus far. 3) Dual delivery of 'derived' isotopic data. In some systems, it is critical to capture the published data (i.e. isotopic measurements and derived values, as presented by the original author) and generate an additional set of derived values from the same measurements, calculated using a single set of reference parameters (e.g. decay constant, depleted-mantle values, etc.) that permit 'normalised' portrayal of the data compilation-wide. 4) Flexibility in data delivery mode. In radiogenic isotope geochronology (e.g. U-Pb, Ar-Ar), careful compilation and attribution of 'interpreted ages' can meet the needs of much of the user-base, even without an explicit link to the constituent analyses. In contrast, isotope geochemistry (especially microbeam-based methods such as Lu-Hf via laser ablation) is usually focused on the individual measurements, without which interpreted 'sample-averages' have limited value. Data delivery should reflect key differences of this kind. <b>Value: </b>Used to provide ages and isotope geochemistry data for minerals, rocks and geologic processes. <b>Scope: </b>Australian jurisdictions and international collaborative programs involving Geoscience Australia

Plutonium (Pu) interactions in the environment are highly complex. Site-specific variables play an integral role in determining the chemical and physical form of Pu, and its migration, bioavailability, and immobility. This paper aims to identify the key variables that can be used to highlight regions of radioecological sensitivity and guide remediation strategies in Australia. Plutonium is present in the Australian environment as a result of global fallout and the British nuclear testing program of 1952 – 1958 in central and west Australia (Maralinga and Monte Bello islands). We report the first systematic measurements of 239+240Pu and 238Pu activity concentrations in distal (≥1,000 km from test sites) catchment outlet sediments from Queensland, Australia. The average 239+240Pu activity concentration was 0.29 mBq.g -1 (n = 73 samples) with a maximum of 4.88 mBq.g -1. 238Pu/239+240Pu isotope ratios identified a large range (0.02 – 0.29 (RSD: 74%)) which is congruent with the heterogeneous nuclear material used for the British nuclear testing programme at Maralinga and Montebello Islands. The use of a modified PCA relying on non-linear distance correlation (dCorr) provided broader insight into the impact of environmental variables on the transport and migration of Pu in this soil system. Primary key environmental indicators of Pu presence were determined to be actinide/lanthanide/heavier transition metals, elevation, electrical conductivity (EC), CaO, SiO2, SO3, landform, geomorphology, land use, and climate explaining 81.7% of the variance of the system. Overall this highlighted that trace level Pu accumulations are associated with the coarse, refractive components of Australian soils, and are more likely regulated by the climate of the region and overall soil type. <b>Citation:</b> Megan Cook, Patrice de Caritat, Ross Kleinschmidt, Joёl Brugger, Vanessa NL. Wong, Future migration: Key environmental indicators of Pu accumulation in terrestrial sediments of Queensland, Australia,<i> Journal of Environmental Radioactivity</i>, Volumes 223–224, 2020, 106398,ISSN 0265-931X, https://doi.org/10.1016/j.jenvrad.2020.106398

<div>The first ca. 2.2 billion years of Earth history saw significant change; from a water-world dominated by an anoxic atmosphere and tonalitic continents, to the exposed landmasses, oxygenated atmosphere, and granitic crust of the Paleoproterozoic. Precisely when, and how, these major changes occurred, remain some of the most important and controversial questions in modern geoscience. Here, we present an extensive new zircon U-Pb-Hf-O isotopic and trace element dataset from Earth’s largest preserved Archean continent, the Superior Craton, Canada. These data record a number of fundamental geochemical changes through time and indicate a major geological and geodynamic transition occurred toward the end of Archean, at ca. 2.7 Ga. Our data show that, at&nbsp;&gt;2704–2695&nbsp;Ma, the southern Superior Craton had juvenile εHf, light to mantle-like δ18O, low (Eu/Eu*)/Y (drier/shallower crust), reduced ΔFMQ, less continental initial-U (Ui)/Yb, and more mantle-like Ui/Nb. At ca. 2704–2695&nbsp;Ma, there is a marked transition in multiple datasets, including increases in δ18O, (Eu/Eu*)/Y, ΔFMQ, Ui/Yb and Ui/Nb data, together with more distinct arc-like trace element trends. These data reveal that at 2.7 Ga there was an increase in: (1) continental surface weathering, supported by increased sedimentation at &lt;2.68 Ga, (2) oxidized and hydrous magmatism, and (3) surface material in magma sources. Together, these observations suggest a major geodynamic transition from ‘vertical’ tectonics (sagduction, drips) to north-dipping subduction at 2.7 Ga. The increase in δ18O suggests that proximal continental crust, probably in the northern Superior Craton, became emergent at this time, an inference supported by detrital zircon geochronology. Hence, this dataset links major geodynamic change to the emergence of continental crust and the rise of more oxidized magmatism. These fundamental changes to the Earth’s surface environment, tectonics, and atmosphere at 2.7 Ga, provide evidence for an Earth systems turning-point at the end of the Neoarchean.</div> This Abstract was submitted/presented to the 2022 Specialist Group in Geochemistry, Mineralogy and Petrology (SGGMP) Conference 7-11 November (https://gsasggmp.wixsite.com/home/biennial-conference-2021)

<div>The Australian continent comprises a broad dichotomy of crustal settings; from the Archean–Proterozoic cratonic core in the centre and west, to the accretionary margin of the Tasmanides in the east. These continental blocks meet at the Tasman Line, where successive arc systems built the eastern third of Australia in ca. 250 Myrs. This interface represents one of Australia’s most fundamental crustal boundaries and is marked by the ca. 520–490 Ma Delamerian Orogen in south-eastern Australia. Despite its first-order crustal control on tectonism, magmatism, deformation, and mineral systems in the area, the Delamerian Orogen remains poorly understood. Here, we present new zircon Hf-O isotopic and trace element data on 32 samples across the south-east Tasman Line. This initial dataset, which will grow over the next 12 months as part of Geoscience Australia’s Exploring for the Future program, will be used to constrain the time-space crustal architecture and evolution of Australia’s south-eastern Precambrian cratonic margin. These first samples include Paleoarchean to Devonian felsic magmatic rocks from the eastern Gawler Craton, across the Delamerian Orogen, to the Central Lachlan Orogen, and show that the crust of south-east Australia has a significant pre-history, with crustal reworking a major feature across the region. Delamerian arc magmatism appears to have involved significant reworking of Australia’s south-eastern Precambrian margin, as recorded by sub-chondritic Hf-isotope data. Assuming a significant mantle-component in the initial arc magmas, contamination by the ancient overlying continental rocks, some as old as ca. 3250 Ma, resulted in less juvenile compositions. This observation suggests Australia’s south-eastern Gondwanan margin may have consisted of a west-dipping continental arc, rather than an offshore island arc. The ‘heavy’ supracrustal δ18O of magmatic rocks across the area since the Paleoproterozoic is testament to the long-lived terrestrial nature of this continental margin, and its influence on magmatism across >1 billion years of Earth history.&nbsp;</div> This Abstract was submitted/presented to the 2022 Specialist Group in Geochemistry, Mineralogy and Petrology (SGGMP) Conference 7-11 November (https://gsasggmp.wixsite.com/home/biennial-conference-2021)