<div>We have investigated whether water-saturated residual oil zones (ROZs), sometimes associated with conventional Australian hydrocarbon plays, could provide a CO2 storage resource and supplement depleted field storage. Our petrophysical study demonstrates that ROZs occur in Australia’s hydrocarbon-rich regions, particularly in the Cooper-Eromanga Basin. ROZs with more than 10% residual oil saturation are uncommon, likely due to small original oil columns and lower residual saturations retained in sandstone reservoirs than in classic, carbonate-hosted North American ROZs. Extensive, reservoir-quality rock is found below the deepest occurring conventional oil in many of the fields in the Eromanga Basin, potentially offering significant CO2 storage capacity. Multiphase compositional flow modelling was used to estimate the CO2 storage efficiency of typical Australian ROZs. We developed a novel modelling methodology that first captures oil migration events leading to the formation of ROZs. Modelling CO2 storage over a 20-year injection period demonstrates that CO2-oil interactions increase the density and viscosity of CO2, enhancing CO2 sweep efficiency and lateral flow, improving storage efficiency. The extent of these effects depends on the quantity and spatial distribution of residual oil in place and the miscibility of CO2 at reservoir conditions. Presented at the Australian Energy Producers (AEP) Conference & Exhibition (https://energyproducersconference.au/conference/)

This report represents the first output from a study designed to understand and identify residual oil zones in Australia, with the aim of developing this potential resource using CO2 –EOR techniques. This work is part of the Residual Oil Zone (ROZ) module in the Exploring For The Future (EFTF) programme, which runs from 2020-2024. The work presented here is a collaborative study between Geoscience Australia and CSIRO. ROZ potentially represent a new and viable oil resource for Australia, while at the same time providing an additional CO2 storage avenue through application of CO2 enhanced oil recovery (CO2-EOR). These water-saturated reservoirs, which contain a moderate amount of residual oil and resemble water-flooded conventional oil fields, can be associated with conventional fields (brownfields) or occur with no associated main pay zone (greenfields). Both types of ROZ are currently produced commercially through CO2-EOR in the Permian Basin, USA, and are of growing interest internationally, but our understanding of ROZ in the Australian context is lacking. The first section of this report identifies and discusses the key parameters and factors that influence the efficiency with which ROZ can be produced. These include fluid-rock and fluid-fluid interactions, which may affect injectivity and sweep of hydrocarbons. We also discuss the effects of reservoir heterogeneity as it relates to flow dynamics and also the effects of pore space configuration. The first section concludes with a discussion of CO2 storage associated with ROZ development. In the second section, we discuss two different injection strategies with which to develop ROZ; carbonated brine injection and water alternating gas injection. The final section outlines details of the workflow that will be applied in the EFTF ROZ module over the coming years. Our proposed workflow is a three pronged approach which involves core flooding experiments, pore scale modelling and petrophysical analysis to identify potential ROZ in key Australian basins. In addition to plain CO2 injection, two other promising EOR techniques namely CO2-WAG and carbonated brine injection are also considered in this workflow. The main objectives of this workflow are to: • assess and identifying estimated oil recovery potential from a target ROZ by either of three EOR injection strategies, • identify the best injection strategy for a ROZ • identify the CO2 storage and utilization potential

<div>The “Australia’s Future Energy Resources” (AFER) project, funded under the Government’s “Exploring for the Future” (EFTF) program has been completed. The project’s four modules have evaluated a mixture of energy resource commodities, including natural gas, hydrogen, subsurface storage opportunities for carbon dioxide and hydrogen. They are complimented by several targeted basin inventories which outline the current geological knowledge of energy resources in underexplored, data-poor regions. Several publicly available data sets have been generated and published under the AFER project, including 3,750&nbsp;line-km of reprocessed 2D seismic data, acquired in the Pedirka and western Eromanga basins, of which key lines have been interpreted and integrated with geological and petrophysical well log data. Relative prospectivity maps have been produced for five energy resource commodities from 14&nbsp;play intervals to show the qualitative variability in prospectivity of these resources, including quantitative resource assessments where warranted. Results from the AFER project have helped to identify and geologically characterise the required energy resource commodities to accelerate Australia’s path to net zero emissions.</div> Presented at the Australian Energy Producers (AEP) Conference & Exhibition (https://energyproducersconference.au/conference/)

This Record forms part of a study under the Exploring For The Future (EFTF) program (2020-2024). The Residual Oil Zone Project was designed to understand and identify residual oil zones in Australia, with the aim of developing this potential hydrocarbon and CO2 geological storage resource through CO2–Enhanced Oil Recovery. The work presented here is a collaborative study between Geoscience Australia and GeoGem Consultants. Residual Oil Zones (ROZ) represent a new and potentially viable oil resource for Australia, while at the same time providing a means to use and store carbon dioxide (CO2) through the application of CO2 enhanced oil recovery (CO2-EOR). These naturally water-flooded and water-saturated reservoirs, which contain a moderate amount of residual oil, can be associated with conventional fields (brownfields) or occur with no associated main pay zone (greenfields). Both types of ROZ are currently produced commercially through CO2-EOR in the USA, and are of growing interest internationally, but have not yet been explored in Australia. CO2-EOR has been in widespread practice in the USA since the oil shocks of the 1970’s. While tertiary CO2 injection usually targets oil remaining in fields that have been subject to water-flooding, there has been a parallel adoption of practices to recover vast amounts of paleo-oil that existed when many of these reservoirs were much fuller, before relatively recent (in geologic time) events caused structural and seal changes, resulting in natural water-flooding and/or migration of much of the oil out of the reservoir. The Permian Basin in Texas contains many examples where such Residual Oil Zones (ROZ’s) were found beneath conventional oil reservoirs. These ROZ are unproductive to conventional water flood operations but offer the possibility of an extra 9-15% recovery (of the ROZ OIP at discovery). This work reviews the lessons or insights that can be gained from the USA regarding ROZ field developments.