<div>High purity quartz (HPQ) is the only naturally occurring and economically viable source for the production of silicon. Silicon is a critical mineral, and a key component in modern technologies such as semiconductors and photovoltaic cells. Critical minerals support the move towards a greater reliance on electrification, renewable energy sources and economic security. The global transition to net zero carbon emissions means there is a growing need for new discoveries of HPQ to supply the silicon production chain. High purity quartz deposits are identified in a multitude of geological settings, including pegmatites, hydrothermal veins, sedimentary accumulations and quartzite; however, deposits of sufficient volume and quality are rare. Quartz is abundant throughout Australia, but the exploration and discovery of HPQ occurrences is notably under-reported, making assessment of the HPQ potential in Australia extremely difficult. This paper presents a much-needed summary of the state of the HPQ industry, exploration and deposit styles in Australia. <b>Citation:</b> Jennings, A., Senior, A., Guerin, K., Main, P., & Walsh, J. (2024). A review of high-purity quartz for silicon production in Australia. <i>Australian Journal of Earth Sciences</i>, 1–13. https://doi.org/10.1080/08120099.2024.2362296

The stabilities of uranyl-carbonate and uranyl-hydroxide aqueous complexes were experimentally determined at temperatures ranging from 25 to 125 °C using in situ UV–vis and Raman spectroscopic techniques. Combined with earlier determinations of the stability of chloride, sulfate, and hydroxide complexes at temperatures up to 250 °C, these data permit to create a consolidated dataset suitable for modeling of U(VI) mobilization in natural systems. The parameters of the Modified Ryzhenko-Bryzgalin and the Helgeson-Kirkham-Flowers (HKF) Equations of State (EoS) were derived based on this dataset and used for thermodynamic modeling different scenarios of U(VI) mobilization. These models suggest that at conditions relevant to natural systems, carbonate-mediated transport of U(VI) is likely suppressed by the high stability of solid UO2(OH)2 and Na2U2O7. In contrast, sulfate-mediated mobilization mechanisms are highly efficient at acidic and near-neutral pH conditions and can lead to effective hydrothermal mobilization of U(VI). <b>Citation:</b> A. Migdisov, E. Bastrakov, C. Alcorn, M. Reece, H. Boukhalfa, F.A. Capporuscio, C. Jove-Colon, A spectroscopic study of the stability of uranyl-carbonate complexes at 25–150 °C and re-visiting the data available for uranyl-chloride, uranyl-sulfate, and uranyl-hydroxide species, <i>Geochimica et Cosmochimica Acta</i>, 2024, ISSN 0016-7037, https://doi.org/10.1016/j.gca.2024.04.023.

<div>The footprint of a mineral system is potentially detectable at a range of scales and lithospheric depths, reflecting the size and distribution of its components. Magnetotellurics is one of a few techniques that can provide multiscale datasets to understand mineral systems. The Australian Lithospheric Architecture Magnetotelluric Project (AusLAMP) is a collaborative national survey that acquires long-period magnetotelluric data on a half-degree grid spacing (about 55 km) across Australia. This project aims to map the electrical conductivity/resistivity structure in the crust and mantle beneath the Australian continent. We have used AusLAMP as a first-order reconnaissance survey to resolve large-scale lithospheric architecture for mapping areas of mineral potential in Australia. AusLAMP results show a remarkable connection between conductive anomalies and giant mineral deposits in known highly endowed mineral provinces. Similar conductive features are mapped in greenfield areas where mineralisation has not been previously recognised. In these areas we can then undertake higher-resolution infill magnetotelluric surveys to refine the geometry of major structures, and to investigate if deep conductive structures are connected to the near surface by crustal-scale fluid-flow pathways.</div><div> We summarise the results from a 3D resistivity model derived from AusLAMP data in Northern Australia. This model reveals a broad conductivity anomaly in the lower crust and upper mantle that extends beneath an undercover exploration frontier between the producing Tennant Creek region and the prospective Murphy Province. This anomaly potentially represents a fertile source region for mineral systems. A subsequent higher-resolution infill magnetotelluric survey revealed two prominent conductors within the crust whose combined responses produced the lithospheric-scale conductivity anomaly mapped in the AusLAMP model. Integration of the conductivity structure with deep seismic reflection data revealed a favourable crustal architecture linking the lower, fertile source regions with potential depositional sites in the upper crust. Integration with other geophysical and geochronological datasets suggests high prospectivity for major mineral deposits in the vicinity of major faults.</div><div> This study demonstrates that the integration of geophysical data from multiscale surveys is an effective approach to scale reduction during mineral exploration in covered terranes.</div> This Abstract was submitted to and presented at the 6th International Archean Symposium Target 2023, 28 July (https://6ias.org/target2023/)

We collected 38 groundwater and two surface water samples in the semi-arid Lake Woods region of the Northern Territory to better understand the hydrogeochemistry of this system, which straddles the Wiso, Tennant Creek and Georgina geological regions. Lake Woods is presently a losing waterbody feeding the underlying groundwater system. The main aquifers comprise mainly carbonate (limestone and dolostone), siliciclastic (sandstone and siltstone) and evaporitic units. The water composition was determined in terms of bulk properties (pH, electrical conductivity, temperature, dissolved oxygen, redox potential), 40 major, minor and trace elements as well as six isotopes (δ18Owater, δ2Hwater, δ13CDIC, δ34SSO4=, δ18OSO4=, 87Sr/86Sr). The groundwater is recharged through infiltration in the catchment from monsoonal rainfall (annual average rainfall ~600 mm) and runoff. It evolves geochemically mainly through evapotranspiration and water–mineral interaction (dissolution of carbonates, silicates, and to a lesser extent sulfates). The two surface waters (one from the main creek feeding the lake, the other from the lake itself) are extraordinarily enriched in 18O and 2H isotopes (δ18O of +10.9 and +16.4 ‰ VSMOW, and δ2H of +41 and +93 ‰ VSMOW, respectively), which is interpreted to reflect evaporation during the dry season (annual average evaporation ~3000 mm) under low humidity conditions (annual average relative humidity ~40 %). This interpretation is supported by modelling results. The potassium (K) relative enrichment (K/Cl mass ratio over 50 times that of sea water) is similar to that observed in salt-lake systems worldwide that are prospective for potash resources. Potassium enrichment is believed to derive partly from dust during atmospheric transport/deposition, but mostly from weathering of K-silicates in the aquifer materials (and possibly underlying formations). Further studies of Australian salt-lake systems are required to reach evidence-based conclusions on their mineral potential for potash, lithium, boron and other low-temperature mineral system commodities such as uranium. <b>Citation:</b> P. de Caritat, E. N. Bastrakov, S. Jaireth, P. M. English, J. D. A. Clarke, T. P. Mernagh, A. S. Wygralak, H. E. Dulfer & J. Trafford (2019) Groundwater geochemistry, hydrogeology and potash mineral potential of the Lake Woods region, Northern Territory, Australia, <i>Australian Journal of Earth Sciences</i>, 66:3, 411-430, DOI: 10.1080/08120099.2018.1543208

To meet the rising global demand for base metals – driven primarily by the transition to cleaner-energy sources – declining rates of discovery of new deposits need to be countered by advances in exploration undercover. Here, we report that 85% of the world’s sediment-hosted base metals, including all giant deposits (>10 Mt of metal), occur within 200 km of the edge of thick lithosphere, irrespective of the age of mineralisation. This implies long-term craton edge stability, forcing a reconsideration of basin dynamics and the sediment-hosted mineral system. We find that the thermochemical structure of thick lithosphere results in increased basin subsidence rates during rifting, coupled with low geothermal gradients, which ensure favourable metal solubility and precipitation. Sediments in such basins generally contain all necessary lithofacies of the mineral system. These considerations allow establishment of the first-ever national prospectus for sediment-hosted base metal discovery. Conservative estimates place the undiscovered resource of sediment-hosted base metals in Australia to be ~50–200 Mt of metal. Importantly, this work suggests that ~15% of Australia is prospective for giant sediment-hosted deposits; we suggest that exploration efforts should be focused in this area. <b>Citation:</b> Czarnota, K., Hoggard, M.J., Richards, F.D., Teh, M., Huston, D.L., Jaques, A.L. and Ghelichkhan, S., 2020. Minerals on the edge: sediment-hosted base metal endowment above steps in lithospheric thickness. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

<div>Geoscience Australia’s Exploring for the Future (EFTF) program aims to enhance decision-making on Australia's mineral, energy, and groundwater resources by providing comprehensive geoscience data. Launched in 2016 with a $225m investment, the program has spawned various national projects, including the Australia's Resources Framework (ARF). The ARF focuses on a national perspective of Australia's surface and subsurface geology, supporting economic and social benefits, including transition to net-zero emissions.</div><div><br></div><div>One key sub-project within EFTF is the Geochemistry for Basin Prospectivity (G4BP) module. It explores Australian basins for basin-hosted base metal systems. The current focus (2020-2024) is on the Stuart Shelf region in South Australia, in collaboration with the Geological Survey of South Australia (GSSA) and CSIRO. The efforts aim to refine our understanding of sediment-hosted copper-cobalt-silver (Cu-Co-Ag) potential in this area.</div><div><br></div><div>This work has two primary objectives:</div><div><br></div><div>Geochemical fingerprinting and baseline data collection: Comprehensive data collection and reanalysis of existing samples aim to establish baseline geochemistry for stratigraphic units.</div><div>Mineral system components: Identification of potential metal sources, fluid sources, and trap rocks using a mineral systems approach.</div><div><br></div><div>This data release forms the second stage release of new geochemical data for the Stuart Shelf region; the first stage release was detailed in Champion et al. (2023b). There is also an earlier data release (Champion et al., 2023a) featuring reanalysis, by modern analytical methods, of legacy mineralised and/or altered Stuart Shelf and underlying basement samples held at Geoscience Australia.</div>

<p>This record presents new zircon and titanite U–Pb geochronological data, obtained via Sensitive High Resolution Ion Microprobe (SHRIMP) for twelve samples of plutonic and volcanic rocks from the Lachlan Orogen and the New England Orogen, and two samples of hydrothermal quartz veins from the Cobar region. Many of these new ages improve existing constraints on the timing of mineralisation in New South Wales, as part of an ongoing Geochronology Project (Metals in Time), conducted by the Geological Survey of New South Wales (GSNSW) and Geoscience Australia (GA) under a National Collaborative Framework (NCF) agreement. The results herein (summarised in Table 1.1 and Table 1.2) correspond to zircon and titanite U–Pb SHRIMP analysis undertaken on GSNSW mineral systems projects for the reporting period July 2016–June 2017. Lachlan Orogen <p>The Lachlan Orogen samples reported herein are sourced from operating mines, active prospects, or regions with historical workings. The new dates constrain timing of mineralisation by dating the units which host or crosscut mineralisation, thereby improving understanding of the mineralising systems, and provide stronger constraints for mineralisation models. <p>In the eastern Lachlan Orogen, the new dates of 403.9 ± 2.6 Ma for the Whipstick Monzogranite south of Bega, and 413.3 ± 1.8 Ma for the Banshea Granite north of Goulburn both provide maximum age constraints for the mineralisation they host (Whipstick gold prospect and Ruby Creek silver prospect, respectively). At the Paupong prospect south of Jindabyne, gold mineralisation is cut by a dyke with a magmatic crystallisation age of 430.9 ± 2.1 Ma, establishing a minimum age for the system. <p>The 431.1 ± 1.8 Ma unnamed andesite and the 428.4 ± 1.9 Ma unnamed felsic dyke at the Dobroyde prospect 10 km north of Junee are just barely distinguishable in age, in the order that is supported by field relationships. The andesite is the same age as the c. 432 Ma Junawarra Volcanics but has different geochemical composition, and is younger than the c. 437 Ma Gidginbung Volcanics. The two unnamed units pre-date mineralisation, and are consistent with Pb-dating indicating a Tabberaberran age for mineralisation at the Dobroyde gold deposit. <p>Similarly, the 430.5 ± 3.4 Ma leucogranite from Hickory Hill prospect (north of Albury) clarifies that this unit originally logged as Jindera Granite (since dated at 403.4 ± 2.6 Ma) is instead affiliated with the nearby Mount Royal Granite, which has implications for the extent of mineralisation hosted within this unit. <p>Cobar Basin <p>Titanite ages of 382.5 ± 2.6 Ma and 383.4 ± 2.9 Ma from hydrothermal quartz veins that crosscut and postdate the main phase of mineralisation at the Hera mine in the Cobar region constrain the minimum age for mineralisation. These ages are indistinguishable from a muscovite age of 381.9 ± 2.2 Ma interpreted to be related to late- or post-Tabberaberan deformation event, and these results indicate that mineralisation occurred at or prior to this deformation event. <p>New England Orogen <p>The new ages from granites of the New England Orogen presented in this record aid in classification of these plutons into various Suites and Supersuites, and these new or confirmed relationships are described in detail in Bryant (2017). Many of these plutons host mineralisation, so the new ages also provide maximum age constraints in the timing of that mineralisation. <p>The 256.1 ± 1.3 Ma age of the Deepwater Syenogranite 40 km north of Glen Innes indicates that it is coeval with the 256.4 ± 1.6 Ma (Black, 2006) Arranmor Ignimbrite Member (Emmaville Volcanics) that it intrudes, demonstrating that both intrusive and extrusive magmatism was occurring in the Deepwater region at the same time. The 252.0 ± 1.2 Ma age for the Black Snake Creek Granite northeast of Tenterfield is consistent with its intrusive relationship with the Dundee Rhyodacite (254.34 ± 0.34 Ma; Brownlow et al., 2010). Similarly, the 251.2 ± 1.3 Ma age for the Malara Quartz Monzodiorite southeast of Tenterfield is consistent with field relationships that demonstrate that it intrudes the Drake Volcanics (265.3 ± 1.4 Ma–264.4 ± 2.5 Ma, Cross and Blevin, 2010; Waltenberg et al., 2016). <p>The 246.7 ± 1.5 Ma Cullens Creek Granite north of Drake was dated in an attempt to provide a stronger age constraint on mineral deposits that also cut the Rivertree and Koreelan Creek plutons (249.1 ± 1.3 Ma and 246.3 ± 1.4 Ma respectively, Chisholm et al., 2014a). However, the new age is indistinguishable from the Koreelan Creek Granodiorite, and timing of mineralisation is not further constrained, but the new age demonstrates a temporal association between the Cullens Creek and Koreelan Creek plutons. <p>The 239.1 ± 1.2 Ma age for the Mann River Leucogranite west of Grafton is indistinguishable in age from plutons in the Dandahra Suite and supports its inclusion in this grouping. The new age also constrains the timing of the distal part of the Dalmorton Gold Field, and implies that the gold vein system postdates the Hunter-Bowen orogeny. <p>The 232.7 ± 1.0 Ma Botumburra Range Monzogranite east of Armidale is younger than most southern New England granites, but this age is very consistent with the Coastal Granite Association (CGA), and the new age, along with the previously noted petrographic similarities (Leitch and McDougall, 1979) supports incorporation of the Botumburra Range Monzogranite into the Carrai Supersuite of the CGA (Bryant, 2017).

Over 900 Australian mineral deposits, location and age data, combined with deposit classifications, have been used to assess temporal and spatial patterns of mineral deposits associated with convergent margins and allow assessment of the potential of poorly exposed or undercover mineral provinces and identification of prospective tracts within known mineral provinces. Here we present results of this analysis for the Eastern Goldfields Superterrane and the Tasman Element, which illustrate end-members of the spectrum of convergent margin metallogenic provinces. Combining our Australian synthesis with global data suggest that after ~3000 Ma these provinces are characterised by a reasonably consistent temporal pattern of deposit formation, termed the convergent margin metallogenic cycle (CMMC): volcanic-hosted massive sulfide – calc-alkalic porphyry copper – komatiite-associated nickel sulfide → orogenic gold → alkalic porphyry copper – granite-related rare metal (Sn, W and Mo) – pegmatite. Between ca 3000 Ma and ca 800 Ma, virtually all provinces are characterised by a single CMMC, but after ca 800 Ma, provinces mostly have multiple CMMCs. We interpret this change in metallogeny to reflect secular changes in tectonic style, with single-CMMC provinces associated with warm, shallow break-off subduction, and multiple-CMMC provinces associated with modern-style cold, deep break-off subduction. These temporal and spatial patterns can be used to infer potential for mineralisation outside well-established metallogenic tracts. <b>Citation:</b> Huston D. L., Doublier M. P., Eglington B., Pehrsson S., Mercier-Langevin P. & Piercey S., 2022. Convergent margin metallogenic cycling in the Eastern Goldfields Superterrane and Tasman Element. In: Czarnota, K. (ed.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, https://dx.doi.org/10.26186/147037

<p>Iron oxide copper-gold (IOCG) deposits are consequences of lithospheric- to deposit-scale earth processes, and form where there was a coincidence of ore-forming processes in space and time. Building on previous conceptualisations we view a ‘mineral system’ as an ore-forming geological system in which four components are required to have operated efficiently and coincidentally, namely: (1) available sources of ore metals (i.e., copper, gold, uranium, rareearth elements) and hydrothermal fluids; (2) energy sources to drive fluids in the ore-forming system; (3) active crustal and mantle lithospheric architecture, representing hydrothermal fluid and/or magma flow pathways; and (4) physico-chemical gradients along which ore metals were deposited to form ore bodies. <p>This holistic multi-scale mineral systems framework has been used to develop a practical, knowledge-based yet data-rich, prospectivity mapping method applicable at regional to continental scales for hydrothermal and orthomagmatic ore-forming systems. We demonstrate how the mineral system components can be translated into mappable criteria and show how maps of mineral potential are generated by integrating diverse and rich input data sets. The method enables prediction of mineral potential not only in brownfields areas but also in greenfields and covered terranes with no previously known mineralisation. Here we report the application of this methodology in regional-scale mapping of the potential for iron oxide Cu-Au (IOCG) deposits in Australia, using examples from five studies over the last decade in northern Queensland, eastern South Australia, and southern and central-eastern Northern Territory. Uncertainties in the results arising from assignment of weightings to input data layers were investigated by the application of Monte Carlo-type probabilistic simulations. The results of 500 iterations using randomly assigned weightings overall support the deterministic results but also show that modelled prospectivity is controlled mainly by variations in intrinsic values of the input geoscientific data sets (e.g. highs and lows of gravity values) rather than by the weightings. <p>The results of the knowledge-driven data-rich analyses of IOCG potential have been validated against known IOCG deposits (not used directly in the analysis). We find in all five studies (Queensland, South Australia and Northern Territory) a good spatial correspondence, with few exceptions. Statistical analysis of prospectivity mapping results from the Tennant Creek – Mt Isa study area demonstrate that 15 of 16 IOCG deposits occur in the highest modelled prospectivity areas within 4.2% of the study area, representing an area reduction of 95.8%. Moreover, several new discoveries of Cu-Au mineralisation have been made within areas previously highlighted as highly prospective. This success and validation support the utility of Geoscience Australia’s approach as a decision-support tool to assist exploration companies and governments in cratonto regional-scale area selection for discovery of IOCG and other mineral systems.

<div>The Exploring for the Future (EFTF) program is an Australian government initiative aimed at stimulating investment in resource exploration and development. It operates multiple interconnected projects, such as the Australia’s Resources Framework (ARF), a continental-scale endeavor to enhance understanding of Australia's geology and resource potential. A module of ARF, the Geochemistry for Basin Prospectivity (G4BP), studies Australian basins with prospective base metal mineral systems. </div><div><br></div><div>The current report focuses on the Neoproterozoic segment of the Stuart Shelf region in South Australia, a part of the Adelaide Rift Complex. This research is conducted collaboratively with the Geological Survey of South Australia, examining sediment-hosted copper potential in the rift complex.</div><div><br></div><div>The Adelaide Rift Complex is a geological formation that underwent extensive sedimentation from the Neoproterozoic to early Cambrian, particularly within the rift zone. Stuart Shelf sediments overlay Mesoproterozoic magmatic and Paleoproterozoic metasediment layers. The complex hosts multiple copper deposits, which are usually associated with movement of basinal brines that leach metals from lower basinal layers or rift-related volcanic rocks.</div><div><br></div><div>To improve understanding of the geology of the Stuart Shelf and related copper mineralisation, two primary objectives were set: </div><div><br></div><div>1. Geochemical fingerprinting and baseline data collection: This involves compilation and reanalysis of existing data, along with new data collection aimed at providing comprehensive geochemical data for stratigraphic units within the Stuart Shelf.</div><div><br></div><div>2. Identification of mineral system components: Utilising data from the first objective, this phase aims to identify potential metal and fluid sources and potential sites of metal deposition. </div><div>In conjunction with these efforts, a GA-GSSA geochemical sampling project is underway, tying geochemistry to lithostratigraphic units and facies. The newly acquired geochemical data will be integrated into the overall GSSA-CSIRO project to contribute to a more comprehensive understanding of the sediment-hosted stratabound mineral system.</div><div><br></div>