<div>Strontium isotopes (87Sr/86Sr) are useful to trace processes in the Earth sciences as well as in forensic, archaeological, palaeontological, and ecological sciences. As very few large-scale Sr isoscapes exist in Australia, we have identified an opportunity to determine 87Sr/86Sr ratios on archived fluvial sediment samples from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa; last access: 15 December 2022). The present study targeted the northern parts of Western Australia, the Northern Territory and Queensland, north of 21.5 °S. The samples were taken mostly from a depth of ~60-80 cm in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse (< 2 mm) grain-size fraction was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release <em>total</em> Sr. The Sr was then separated by chromatography and the 87Sr/86Sr ratio determined by multicollector-inductively coupled plasma mass spectrometry. Results demonstrate a wide range of Sr isotopic values (0.7048 to 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and smooth gradients), large-scale (> 100 km) patterns that appear to be broadly consistent with surface geology, regolith/soil type, and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a > 500 km-long northwest-southeast-trending unradiogenic anomaly (87Sr/86Sr < 0.7182). Where sedimentary carbonate or mafic/ultramafic igneous rocks dominate, low to moderate 87Sr/86Sr values are generally recorded (medians of 0.7387 and 0.7422, respectively). In proximity to the outcropping Proterozoic metamorphic basement of the Tennant, McArthur, Murphy and Mount Isa geological regions, conversely, radiogenic 87Sr/86Sr values (> 0.7655) are observed. A potential correlation between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith Sr isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g. weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting Sr isoscape and future models derived therefrom can also be utilised in forensic, archaeological, paleontological and ecological studies that aim to investigate, e.g., past and modern animal (including humans) dietary habits and migrations. The new spatial Sr isotope dataset for the northern Australia region is publicly available (de Caritat et al., 2022a; https://dx.doi.org/10.26186/147473; last access: 15 December 2022).</div> <b>Citation:</b> de Caritat, P., Dosseto, A., and Dux, F.: A strontium isoscape of northern Australia, <i>Earth Syst. Sci. Data</i>, 15, 1655–1673, https://doi.org/10.5194/essd-15-1655-2023, <b>2023</b>.

<div>Magmatic arcs represent a critical source of modern civilisation’s mineral wealth, with their importance only enhanced by the ongoing global transition to a low-carbon society. The ~830-495 Ma Delamerian Orogen, formed at Australia’s eastern cratonic margin, represents rocks ascribed to rift/passive-margin, convergent margin arc, orogenic, and post-orogenic settings. However, poor exposure has limited exploration activity across much of the orogen, despite demonstrated potential for numerous mineral systems. To address this issue, an orogen-wide zircon Hf-O isotope and trace element survey was performed on 55 magmatic samples to constrain the crustal architecture, evolution, and fertility of the Delamerian Orogen, and in turn map parameters that can be used as a guide to mineral potential. These new data define two broad magmatic episodes at: (1) ~585-480 Ma, related to rift/passive margin, convergent arc, orogenic, and post-orogenic activity (Delamerian Cycle); and (2) magmatism associated with the ~490-320 Ma Lachlan Orogen, with peaks at ~420 Ma (onshore, Tabberabberan Cycle) and ~370 Ma (western Tasmania). Isotopic and geochemical mapping of these events show that the ~585-480 Ma Delamerian Cycle has significant orogen-wide variation in magmatic Hf-O isotopes and oxidation-state, suggesting a spatial variation in the occurrence and type of potential mineral systems. The ~420 Ma magmatic event involved predominantly mantle-like Hf-O and oxidised magmatism, whilst the ~370 Ma magmatism shows opposing features. In general, The potential to host Cu-Au porphyry and VMS mineralisation (e.g., Stavely, Koonenberry) is present, but restricted, whereas signatures favourable for Sn-W granite-hosted systems (e.g., Tasmania), are more common. These new data constrain time-space variations in magma composition that provide a valuable geological framework for mineral system fertility assessments across the Delamerian Orogen. Furthermore, these data and associated maps can used to assess time-space mineral potential and facilitate more effective exploration targeting in this covered region.</div> <b>Citation:</b> Mole, D., Bodorkos, S., Gilmore, P.J., Fraser, G., Jagodzinski, E.A., Cheng, Y., Clark, A.D., Doublier, M., Waltenberg, K., Stern, R.A., Evans, N.J., 2023. Architecture, evolution and fertility of the Delamerian Orogen: Insights from zircon. In: Czarnota, K. (ed.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, <a href+"https://dx.doi.org/10.26186/148981">https://dx.doi.org/10.26186/148981</a>

<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to a low emissions economy, strong resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, is an eight year, $225 m investment by the Australian Government. </div><div>As part of this program, Geoscience Australia led two deep crustal reflection seismic surveys in the South Nicholson region, revealing the existence of the Carrara Sub-basin, a large sedimentary depocentre up to 8 km deep, beneath the Georgina Basin (Carr et al., 2019; 2020). The depocentre is believed to contain thick sequences of highly prospective Proterozoic rocks for base metals and unconventional hydrocarbons. To confirm geological interpretations and assess resource potential, the National Drilling Initiative, NDI Carrara 1 stratigraphic drill hole was completed in late 2020, as a collaboration between Geoscience Australia, the Northern Territory Geological Survey (NTGS) and the MinEx CRC (Geoscience Australia, 2021). NDI Carrara 1 is located on the western flank of the Carrara Sub-basin on the South Nicholson seismic line (17GA-SN1) (Figure 1.1; Figure 1.2), reaching a total depth of 1751 m, intersecting sedimentary rocks comprising ca. 630 m of Cambrian calcareous shales of the Georgina Basin and ca. 1100 m of Proterozoic carbonates and siliciclastics that include black shales of the Carrara Sub-basin.</div><div>This report presents data on selected rock samples from NDI Carrara&nbsp;1, conducted by the Mawson Analytical Spectrometry Services, University of Adelaide, under contract to Geoscience Australia. These results include bulk carbon isotope ratios (δ13C) of bitumens and isolated kerogens. In addition, a selection of 10 samples was analysed at Geoscience Australia for comparison purposes.</div><div><br></div>

<div>This dataset comprises hydrochemistry results for groundwater, surface water, and rainwater samples collected as part of the Upper Darling Floodplain groundwater study. Associated methods, interpretation, and integration with other datasets are found in the Upper Darling Floodplain geological and hydrogeological assessment (Geoscience Australia Ecat ID:149689). This project is part of the Exploring for the Future (EFTF) program, an eight-year, $225 million Australian Government funded geoscience data and precompetitive information acquisition program. The dataset contains 68 groundwater samples, 17 surface water samples, and four rainwater samples. Groundwater samples are from the Cenozoic formations within the alluvium of the Darling River, the Great Artesian Basin, and the Murray geological basin. Surface water samples are from the Darling River, and rainwater samples were taken within the study area. Subsets of the samples were analysed for major ions and trace metals, stable isotopes of water (δ2H and δ18O), radiocarbon (14C), stable carbon isotopes (δ13C), strontium isotopes (87Sr/86Sr), sulfur hexafluoride (SF6), chlorofluorocarbon (CFC) isotopes, chlorine-36 (36Cl), noble gases, and Radon-222. The results were used to inform a range of hydrogeological questions including aquifer distribution and quality, inter-aquifer connectivity, and groundwater-surface water connectivity.&nbsp;</div><div><br></div>

<div>The Roebuck Basin on Australia’s offshore north-western margin is the focus of regional energy exploration activity. Drilling in the Roebuck Basin resulted in oil and gas discoveries at Phoenix South&nbsp;1 (2014), Roc&nbsp;1 (2015–2016) and Dorado&nbsp;1 (2018) in the Bedout Sub-basin (Figure 1‑2) and demonstrated the presence of a petroleum system in Lower Triassic strata. These discoveries have been evaluated for development and production with infill drilling at Roc&nbsp;2 (2016), Phoenix South&nbsp;2 (2016), Phoenix South&nbsp;3 (2018), Dorado&nbsp;2 (2019), and Dorado&nbsp;3 (2019). Recent drilling by Santos (2022) has resulted in the discovery of oil at Pavo&nbsp;1 (2022) and hydrocarbon shows at Apus&nbsp;1 (2022).</div><div><br></div><div>To complement this industry work, Geoscience Australia’s Offshore Energy Systems program produces pre-competitive information to assist with the evaluation of the energy and resource potential of the central North West Shelf, including both hydrogen and helium resources, and to attract exploration investment to Australia. As part of this program, determination of the molecular and noble gas isotopic composition of natural gases from selected petroleum wells in the Roebuck Basin were undertaken by Smart Gas Sciences, under contract to Geoscience Australia, with results from these analyses being released in this report. This report provides additional gas data to determine the sources of natural gases in the Roebuck Basin and build on previously established gas-gas correlations. Noble gas isotopic data can be used in conjunction with carbon and hydrogen isotopic data to determine the origin of both inorganic and organic (hydrocarbon) gases. This information can be used in future geological programs to determine the source and distribution of hydrogen and helium in natural gases and support acreage releases by the Australian Government.</div><div><br></div>

<div>The Yilgarn Craton of Western Australia represents one of the largest pieces of Precambrian crust on Earth, and a key repository of information on the Meso-Neoarchean period. Understanding the crustal, tectonic, thermal, and chemical evolution of the craton is critical in placing these events into an accurate geological context, as well as developing holistic tectonic models for the Archean Earth. In this study, we collected a large U-Pb (420 collated samples) and Hf isotopic (2163 analyses) dataset on zircon to investigate the evolution of the craton. These data provide strong evidence for a Hadean-Eoarchean origin for the Yilgarn Craton from mafic crust at ca. 4000 Ma. This ancient cratonic nucleus was subsequently rifted, expanded and reworked by successive crustal growth events at ca. 3700 Ma, ca. 3300 Ma, 3000-2900 Ma, 2825-2800 Ma, and ca. 2730-2620 Ma. The <3050 Ma crustal growth events correlate broadly with known komatiite events, and patterns of craton evolution, revealed by Hf isotope time-slice mapping, image the periodic break-up of the Yilgarn proto-continent and the formation of rift-zones between the older crustal blocks. Crustal growth and new magmatic pulses were focused into these zones and at craton margins, resulting in continent growth via internal (rift-enabled) expansion, and peripheral (crustal extraction at craton margins) magmatism. Consequently, we interpret these major geodynamic processes to be analogous to plume-lid tectonics, where the majority of tonalite-trondhjemite-granodiorite (TTG) felsic crust, and later granitic crust, was formed by reworking of hydrated mafic rocks and TTGs, respectively, via a combination of infracrustal and/or drip-tectonic settings. While this process of crust formation and evolution is not necessarily restricted to a specific geodynamic system, we find limited direct evidence that subduction-like processes formed a major tectonic component, aside from re-docking the Narryer Terrane to the craton at ca. 2740 Ma. Overall, these 'rift-expansion' and 'craton margin' crustal growth process led to an intra-cratonic architecture of younger, juvenile terranes located internal and external to older, long-lived, reworked crustal blocks. This framework provided pathways that localized later magmas and fluids, driving the exceptional mineral endowment of the Yilgarn Craton.</div> This Abstract/Poster was submitted to & presented at the 2023 6th International Archean Symposium (6IAS) 25 - 27 July (https://6ias.org/)

<div>The noble gas database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for molecular and noble gas isotopic analyses on natural gases sampled from boreholes and fluid inclusion gases from rocks sampled in boreholes and field sites. Data includes the borehole or field site location, sample depths, shows and tests, stratigraphy, analytical methods, other relevant metadata, and the molecular and noble gas isotopic compositions for the natural gas samples. The molecular data are presented in mole percent (mol%) and cubic centimetres (at Standard Pressure and Temperature) per cubic centimetre (ccSTP/cc). The noble gas isotopic values that can be measured are; Helium (He, ³He, ⁴He), Neon (Ne, ²⁰Ne, ²¹Ne, ²²Ne), Argon (Ar, ³⁶Ar, ³⁸Ar, ⁴⁰Ar), Krypton (Kr, ⁷⁸Kr, ⁸⁰Kr, ^82<Kr, ⁸³Kr, ⁸⁴Kr, ⁸⁶Kr) and Xenon (Xe, ¹²⁴Xe, ¹²⁶Xe, ¹²⁸Xe, ¹²⁹Xe, ¹³⁰Xe, ¹³¹Xe, ¹³²Xe, ¹³⁴Xe, ¹³⁶Xe) which are presented in cubic micrometres per cubic centimetre (mcc/cc), cubic nanometres per cubic centimetre (ncc/cc) and cubic picometres per cubic centimetre (pcc/cc). Acquisition of the molecular compounds are by gas chromatography (GC) and the isotopic ratios by mass spectrometry (MS). Compound concentrations that are below the detection limit (BDL) are reported as the value -99999.</div><div><br></div><div>These data provide source information about individual compounds in natural gases and can elucidate fluid migration pathways, irrespective of microbial activity, chemical reactions and changes in oxygen fugacity, which are useful in basin analysis with derived information being used to support Australian exploration for energy resources and helium. These data are collated from Geoscience Australia records and well completion reports. The noble gas data for natural gases and fluid inclusion gases are delivered in the Noble Gas Isotopes web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div><div><br></div><div><br></div>

<div>The bulk oils database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the bulk properties of petroleum liquids (e.g., condensate, crude oil, bitumen) sampled from boreholes and field sites. The analyses are performed by various laboratories in service and exploration companies, Australian government institutions, and universities using a range of instruments. Petroleum is composed primarily of hydrocarbons (carbon and hydrogen) with minor quantities of heterocyclic compounds containing either nitrogen, oxygen or sulfur. Data includes the borehole or field site location, sample depth, shows and tests, stratigraphy, analytical methods, other relevant metadata, and various data types including; API gravity, elemental composition and photographs of the samples. The stable carbon (¹³C/¹²C) and hydrogen (²H/¹H) isotopic ratios of crude oil and derivative saturated and aromatic hydrocarbon fractions are presented in parts per mil (‰) and in delta notation as &delta;¹³C and &delta;²H, respectively. Results are also included from methods that separate crude oils into bulk components, such as the quantification of saturated hydrocarbon, aromatic hydrocarbon, resin, and asphaltene (SARA) fractions according to their polarity.</div><div><br></div><div>These data provide information about the petroleum fluid’s composition, source, thermal maturity, secondary alteration, and fluid migration pathways. They are also useful for enhanced oil recovery assessments, petroleum systems mapping and basin modelling. Hence, these sample-based datasets are used for the discovery and evaluation of sediment-hosted resources. Some data are generated in Geoscience Australia’s laboratory and released in Geoscience Australia records. Data are also collated from destructive analysis reports (DARs), well completion reports (WCRs), and literature. The bulk oils data are delivered in the Petroleum Bulk Properties and Stable Isotopes web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

<div>Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g. recognising geological provinces, studying geological processes) as well in archaeological (e.g. informing on past human migrations), palaeontological/ecological (e.g. investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g. validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected mostly from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa), with a few additional Northern Australia Geochemical Survey infill samples. The present study targeted the northern parts of Western Australia, the Northern Territory and Queensland in Australia, north of 21.5 °S. The samples were taken mostly from a depth of ~60-80 cm depth in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse grain-size fraction (&lt;2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Preliminary results demonstrate a wide range of strontium isotopic values (0.7048 &lt; 87Sr/86Sr &lt; 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and smooth gradients), large-scale (&gt;100 km) patterns that appears to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a &gt;500 km-long northwest-southeast-trending low anomaly (87Sr/86Sr &lt; 0.7182). Where carbonate or mafic igneous rocks dominate, a low to moderate strontium isotope signature is observed. In proximity to the outcropping Proterozoic metamorphic provinces of the Tennant, McArthur, Murphy and Mount Isa geological regions, conversely, high 87Sr/86Sr values (&gt; 0.7655) are observed. A potential link between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g. weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape and model derived therefrom can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations. &nbsp;The new spatial dataset is publicly available through the Geoscience Australia portal https://portal.ga.gov.au/.</div>

<div>Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g. recognising geological provinces, studying geological processes) as well in archaeological (e.g. informing on past human migrations), palaeontological/ecological (e.g. investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g. validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected mostly from the low-density National Geochemical Survey of Australia (NGSA; www.ga.gov.au/ngsa). The present study targeted the Yilgarn geological region in southwestern Australia. The samples were mostly taken from a depth of ~60-80 cm (Bottom Outlet Sediments, BOS) in floodplain deposits at or near the outlet of large catchments (drainage basins). A small number of surface (0-10 cm) samples (Top Outlet Sediments, TOS) were also included in the study. For all, a coarse grain-size fraction (<2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Overall, 107 NGSA BOS < 2 mm and 13 NGSA TOS < 2 mm were analysed for Sr isotopes. Given that there are ~10 % field duplicates in the NGSA, all those samples originate from within 97 NGSA catchments, which together cover 533 000 km2 of southwestern Australia. Preliminary results for the BOS samples demonstrate a wide range of strontium isotopic values (0.7152 < 87Sr/86Sr < 1.0909) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and smooth gradients), large-scale (>100 km) patterns that appear to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, catchments in the western and central Yilgarn dominated by felsic intrusive basement geology have radiogenic 87Sr/86Sr signatures in the floodplain sediments consistent with published whole-rock data. Similarly, unradiogenic signatures in sediments in the eastern Yilgarn are in agreement with published whole-rock data. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g. weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape and model derived therefrom can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations.&nbsp; The new spatial dataset is publicly available through the Geoscience Australia portal https://portal.ga.gov.au/.</div>