<div>A regional hydrocarbon prospectivity assessment has been undertaken of the offshore Otway Basin by the Offshore Energy Systems Section. This program was designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the offshore Otway Basin and attract exploration investment to Australia. The inboard part of the basin is an established hydrocarbon province with onshore and shallow-water offshore discoveries, whereas the outboard deep-water region, where water depths range from 500 to 6300&nbsp;m, is comparatively underexplored and considered a frontier area.</div><div><br></div><div>As part of this program, molecular and noble gas isotopic analyses were undertaken by Smart Gas Sciences, under contract to Geoscience Australia on available gas samples from the Waarre Formation in the Shipwreck Trough in the offshore eastern Otway Basin, with data from these analyses being released in this report. This report provides additional compositional information for gases in the Waarre Formation reservoirs and builds on previously established gas-gas correlations and gas-oil correlations. Noble gas isotopic data can be used in conjunction with carbon and hydrogen isotopic data to determine the origin of both inorganic and organic (hydrocarbon) gases. This information can be used in future geological programs to determine the source and distribution of hydrogen and helium in natural gases and support acreage releases by the Australian Government.</div><div><br></div><div><br></div>

<div>The noble gas database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for molecular and noble gas isotopic analyses on natural gases sampled from boreholes and fluid inclusion gases from rocks sampled in boreholes and field sites. Data includes the borehole or field site location, sample depths, shows and tests, stratigraphy, analytical methods, other relevant metadata, and the molecular and noble gas isotopic compositions for the natural gas samples. The molecular data are presented in mole percent (mol%) and cubic centimetres (at Standard Pressure and Temperature) per cubic centimetre (ccSTP/cc). The noble gas isotopic values that can be measured are; Helium (He, ³He, ⁴He), Neon (Ne, ²⁰Ne, ²¹Ne, ²²Ne), Argon (Ar, ³⁶Ar, ³⁸Ar, ⁴⁰Ar), Krypton (Kr, ⁷⁸Kr, ⁸⁰Kr, ^82<Kr, ⁸³Kr, ⁸⁴Kr, ⁸⁶Kr) and Xenon (Xe, ¹²⁴Xe, ¹²⁶Xe, ¹²⁸Xe, ¹²⁹Xe, ¹³⁰Xe, ¹³¹Xe, ¹³²Xe, ¹³⁴Xe, ¹³⁶Xe) which are presented in cubic micrometres per cubic centimetre (mcc/cc), cubic nanometres per cubic centimetre (ncc/cc) and cubic picometres per cubic centimetre (pcc/cc). Acquisition of the molecular compounds are by gas chromatography (GC) and the isotopic ratios by mass spectrometry (MS). Compound concentrations that are below the detection limit (BDL) are reported as the value -99999.</div><div><br></div><div>These data provide source information about individual compounds in natural gases and can elucidate fluid migration pathways, irrespective of microbial activity, chemical reactions and changes in oxygen fugacity, which are useful in basin analysis with derived information being used to support Australian exploration for energy resources and helium. These data are collated from Geoscience Australia records and well completion reports. The noble gas data for natural gases and fluid inclusion gases are delivered in the Noble Gas Isotopes web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div><div><br></div><div><br></div>

The Source Rock and Fluids Atlas delivery and publication services provide up-to-date information on petroleum (organic) geochemical and geological data from Geoscience Australia's Organic Geochemistry Database (ORGCHEM). The sample data provides the spatial distribution of petroleum source rocks and their derived fluids (natural gas and crude oil) from boreholes and field sites in onshore and offshore Australian basins. The services provide characterisation of source rocks through the visualisation of Pyrolysis, Organic Petrology (Maceral Groups, Maceral Reflectance) and Organoclast Maturity data. The services also provide molecular and isotopic characterisation of source rocks and petroleum through the visualisation of Bulk, Whole Oil GC, Gas, Compound-Specific Isotopic Analyses (CSIA) and Gas Chromatography-Mass Spectrometry (GCMS) data tables. Interpretation of these data enables the characterisation of petroleum source rocks and identification of their derived petroleum fluids that comprise two key elements of petroleum systems analysis. The composition of petroleum determines whether or not it can be an economic commodity and if other processes (e.g. CO2 removal and sequestration; cryogenic liquefaction of LNG) are required for development.

<div>The onshore Canning Basin in Western Australia was the focus of a regional hydrocarbon prospectivity assessment undertaken by the Exploring for the Future&nbsp;(EFTF) program dedicated to increasing investment in resource exploration in northern Australia, with the objective being to acquire new data and information about the potential mineral, energy and groundwater resources concealed beneath the surface. Significant work has been carried out to deliver new pre-competitive data in the region including new seismic acquisition, drilling of a stratigraphic well, and geochemical analysis from historic exploration wells.</div><div><br></div><div>As part of this program, determination of the molecular and noble gas isotopic composition of natural gases from selected petroleum wells in the Canning Basin were undertaken by Smart Gas Sciences, under contract to Geoscience Australia, with results from these analyses being released in this report. This report provides additional data to determine the sources of natural gases in the Canning Basin and build on the availability of existing gas data, gas-gas correlations and gas-oil correlations. Noble gas isotopic data can be used in conjunction with carbon and hydrogen isotopic data to determine the origin of both inorganic and organic (hydrocarbon) gases. This information can be used in future geological programs to determine the source and distribution of hydrogen and helium in natural gases and support exploration programs.</div>

<div>Exploring for the Future (EFTF) is a program dedicated to exploring Australia’s resource potential and boosting investment. This program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of onshore basins and attract exploration investment to Australia. This record presents geochemical analyses of natural gases sampled from Nangwarry 1, located in the onshore Otway Basin, undertaken in partnership with the Department for Energy and Mining – Energy Resources, Government of South Australia, as part of the EFTF program Natural Hydrogen module. The Nangwarry Joint Venture drilled Nangwarry 1 to investigate the potential for the development of food grade, carbon dioxide production from this well. The results of the molecular and stable carbon and hydrogen isotopic analyses undertaken by Geoscience Australia are released in this report. The molecular data show that the gas composition in this well has an average of 96 mol% CO2 with an isotopic signature indicative of a magmatic origin, being comparable with previously produced gases from onshore Otway Basin wells (e.g. Boggy Creek 1, Caroline 1) for use by the food industry. The carbon and hydrogen isotopic composition of the C1–C5 hydrocarbon gases from Nangwarry 1 are suggestive of a source from within the Crayfish Supersequence.</div>

<div>The Gas Chromatography-Mass Spectrometry (GC-MS) biomarker database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the molecular (biomarker) compositions of source rock extracts and petroleum liquids (e.g., condensate, crude oil, bitumen) sampled from boreholes and field sites. These analyses are undertaken by various laboratories in service and exploration companies, Australian government institutions and universities using either gas chromatography-mass spectrometry (GC-MS) or gas chromatography-mass spectrometry-mass spectrometry (GC-MS-MS). Data includes the borehole or field site location, sample depth, shows and tests, stratigraphy, analytical methods, other relevant metadata, and the molecular composition of aliphatic hydrocarbons, aromatic hydrocarbons and heterocyclic compounds, which contain either nitrogen, oxygen or sulfur.</div><div><br></div><div>These data provide information about the molecular composition of the source rock and its generated petroleum, enabling the determination of the type of organic matter and depositional environment of the source rock and its thermal maturity. Interpretation of these data enable the determination of oil-source and oil-oil correlations, migration pathways, and any secondary alteration of the generated fluids. This information is useful for mapping total petroleum systems, and the assessment of sediment-hosted resources. Some data are generated in Geoscience Australia’s laboratory and released in Geoscience Australia records. Data are also collated from destructive analysis reports (DARs), well completion reports (WCRs), and literature. The biomarker data for crude oils and source rocks are delivered in the Petroleum and Rock Composition – Biomarker web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

<div>The Roebuck Basin on Australia’s offshore north-western margin is the focus of regional energy exploration activity. Drilling in the Roebuck Basin resulted in oil and gas discoveries at Phoenix South&nbsp;1 (2014), Roc&nbsp;1 (2015–2016) and Dorado&nbsp;1 (2018) in the Bedout Sub-basin (Figure 1‑2) and demonstrated the presence of a petroleum system in Lower Triassic strata. These discoveries have been evaluated for development and production with infill drilling at Roc&nbsp;2 (2016), Phoenix South&nbsp;2 (2016), Phoenix South&nbsp;3 (2018), Dorado&nbsp;2 (2019), and Dorado&nbsp;3 (2019). Recent drilling by Santos (2022) has resulted in the discovery of oil at Pavo&nbsp;1 (2022) and hydrocarbon shows at Apus&nbsp;1 (2022).</div><div><br></div><div>To complement this industry work, Geoscience Australia’s Offshore Energy Systems program produces pre-competitive information to assist with the evaluation of the energy and resource potential of the central North West Shelf, including both hydrogen and helium resources, and to attract exploration investment to Australia. As part of this program, determination of the molecular and noble gas isotopic composition of natural gases from selected petroleum wells in the Roebuck Basin were undertaken by Smart Gas Sciences, under contract to Geoscience Australia, with results from these analyses being released in this report. This report provides additional gas data to determine the sources of natural gases in the Roebuck Basin and build on previously established gas-gas correlations. Noble gas isotopic data can be used in conjunction with carbon and hydrogen isotopic data to determine the origin of both inorganic and organic (hydrocarbon) gases. This information can be used in future geological programs to determine the source and distribution of hydrogen and helium in natural gases and support acreage releases by the Australian Government.</div><div><br></div>

The Australian Government’s $225 million Exploring for the Future (EFTF) program is committed to supporting a strong economy, resilient society and sustainable environment for the benefit of Australians (https://www.ga.gov.au/eftf). At its heart, the program is about stimulating industry now to ensure a sustainable, long-term future for Australia through an improved understanding of the nation’s minerals, energy and groundwater resource potential. By gathering and analysing geological and geophysical data and making the results publicly available, the program supports regional development and informed decision making across Australia, resulting in jobs and growth. The Energy component of this program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of onshore basins and attract exploration investment to Australia. As part of the EFTF Natural Hydrogen module, molecular and isotopic analyses were undertaken by Geoscience Australia on natural gas samples from the wells Canunda 2 and Ralgnal 1 from the southwestern margin of the Patchawarra Trough in the Cooper Basin, with the raw data from these analyses being released in this report. Some data from these wells were included in the nationwide studies of helium and hydrogen, as published by Boreham et al. (2018; 2021), and build on previous studies that document the composition of Australian natural gases (Boreham et al., 2001). These data are available through the Geoscience Australia portal at https://portal.ga.gov.au/

<div>The pyrolysis-gas chromatography database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) database and supporting oracle databases for open system pyrolysis-gas chromatography (pyrolysis-GC) analyses performed on either source rocks or kerogen samples taken from boreholes and field sites. Sedimentary rocks that contain organic matter are referred to as source rocks (e.g., organic-rich shale, oil shale and coal) and the organic matter within the rock matrix that is insoluble in organic solvents is named kerogen. The analyses are undertaken by various laboratories in service and exploration companies using a range of instruments. Data includes the borehole or field site location, sample depth, stratigraphy, analytical methods, other relevant metadata, and the molecular composition of the pyrolysates. The concentrations of the aliphatic hydrocarbon, aromatic hydrocarbon and organic sulfur compounds are given in several units of measure [e.g., percent (resolved compounds) in the S2 peak (wt% S2), milligrams per gram of rock (mg/g rock), micrograms per gram of kerogen (mg/g kerogen) etc.].</div><div><br></div><div>These data are used to determine the organic richness, kerogen type and thermal maturity of source rocks in sedimentary basins. The results are used as input parameters in basin analysis and petroleum systems modelling to evaluate the potential for hydrocarbon generation in a sedimentary basin. These data are collated from destructive analysis reports (DARs), well completion reports (WCRs) and literature. The data are delivered in the Source Rock Pyrolysis-Gas Chromatography web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div><div><br></div>

<div>The soil gas database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for gas analyses undertaken by Geoscience Australia's laboratory on soil samples taken from shallow (down to 1 m below the surface) percussion holes. Data includes the percussion hole field site location, sample depth, analytical methods and other relevant metadata, as well as the molecular and isotopic compositions of the soil gas with air included in the reported results. Acquisition of the molecular compounds are by gas chromatography (GC) and the isotopic ratios by gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS). The concentrations of argon (Ar), carbon dioxide (CO₂), nitrogen (N₂) and oxygen (O₂) are given in mole percent (mol%). The concentrations of carbon monoxide (CO), helium (He), hydrogen (H₂) and methane (C₁, CH₄) are given in parts per million (ppm). Compound concentrations that are below detection limit (BDL) are reported as the value -99999. The stable carbon (¹³C/¹²C) and nitrogen (¹⁵N/¹⁴N) isotopic ratios are presented in parts per mil (‰) and in delta notation as δ¹³C and δ¹⁵N, respectively.</div><div><br></div><div>Determining the individual sources and migration pathways of the components of natural gases found in the near surface are useful in basin analysis with derived information being used to support exploration for energy resources (petroleum and hydrogen) and helium in Australian provinces. These data are collated from Geoscience Australia records with the results being delivered in the Soil Gas web services on the Geoscience Australia Data Discovery portal at https://portal.ga.gov.au which will be periodically updated.</div>