Pyrolysis
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<p>Geoscience Australia's Oracle organic geochemical database comprises analytical results for samples relevant to petroleum exploration, including source rocks, crude oils and natural gases collected across the Australian continent. The data comprises organic chemical analyses of hydrocarbon-bearing earth materials as well as including connectivity to some inorganic analyses. These data enable petroleum fluids to be typed into families and correlated to their source rock, from which depositional environment, age, and migration distances can be determined, and hence the extent of the total petroleum system can be mapped. This comprehensive data set is useful to government for evidence-based decision making on natural resources and the petroleum industry for de-risking conventional and unconventional petroleum exploration programs. <p>The data are produced by a wide range of analytical techniques. For example, source rocks are evaluated for their bulk compositional characteristics by programmed pyrolysis, pyrolysis-gas chromatography and organic petrology. Natural gases are analysed for their molecular and isotopic content by gas chromatography (GC) and gas chromatography-temperature conversion-mass spectrometry (GC-TC-IRMS). Crude oils and the extracts of source rocks are analysed for their bulk properties (API gravity; elemental analysis) and their molecular (biomarkers) and isotopic (carbon and hydrogen) content by GC, gas chromatography-mass spectrometry (GCMS) and GC-TC-IRMS. <p>The sample data originate from physical samples, well completion reports, and destructive analysis reports provided by the petroleum industry under the Offshore Petroleum and Greenhouse Gas Storage Act (OPGGSA) 2006 and previous Petroleum (submerged Lands) Act (PSLA) 1967. The sample data are also sourced from geological sampling programs in Australia by Geoscience Australia and its predecessor organisation's Australian Geological Survey Organisation (AGSO) and Bureau of Mineral Resources (BMR), and from the state and territory geological organisations. Geoscience Australia generates data from its own laboratories. Other open file data from publications, university theses and books are also included <b>Value:</b> The organic geochemistry database enables digital discoverability and accessibility to key petroleum geochemical datasets. It delivers open file, raw petroleum-related analytical results to web map services and web feature services in Geoscience Australia’s portal. Derived datasets and value-add products are created based on calculated values and geological interpretations to provide information on the subsurface petroleum prospectivity of the Australian continent. For example, the ‘Oils of Australia’ series and the ‘characterisation of natural gas’ reports document the location, source and maturity of Australia’s petroleum resources. Details of the total petroleum systems of selected basins studied under the Exploring for the Future project can be found in the Petroleum Systems Summaries Tool in Geoscience Australia’s portal. Related Geoscience Australia Records and published papers can be obtained from eCat. <b>Scope:</b> The collection initially comprised organic geochemical and petrological data on organic-rich sedimentary rocks, crude oils and natural gas from petroleum wells drilled in the onshore and offshore Australian continent. Over time, other sample types (ground water, fluid inclusions, mineral veins, bitumen) from other borehole types (minerals, stratigraphic – including the Integrated Ocean Drilling Program), marine dredge samples and field sites (outcrop, mines, surface seepage samples) have been analysed for their hydrocarbon content and are captured in the database. Results for many of the oil and gas samples held in the Australian National Offshore Wells Data Collection are included in this database.
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<div>The pyrolysis-reflectance tie database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases, which combine key properties related to thermal maturity. These data are typically used as input parameters in basin analysis and petroleum systems modelling to assist with the discovery and evaluation of sediment-hosted energy resources. The programmed pyrolysis analyses and the maceral reflectance analyses undertaken using reflected light microscopy are conducted on rock samples, either as cores, cuttings or rock chips, taken from boreholes and field sites in Australian sedimentary basins. The full datasets are available in the pyrolysis, vitrinite reflectance, maceral reflectance and organoclast maturity web services. These analyses are performed by various laboratories in service and exploration companies, Australian government institutions and universities using a range of instruments.</div><div><br></div><div>These data are collated from destructive analysis reports (DARs), well completion reports (WCRs), and literature. The data are delivered in the Combined Pyrolysis and Vitrinite Reflectance web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>
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<div>The pyrolysis-gas chromatography database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) database and supporting oracle databases for open system pyrolysis-gas chromatography (pyrolysis-GC) analyses performed on either source rocks or kerogen samples taken from boreholes and field sites. Sedimentary rocks that contain organic matter are referred to as source rocks (e.g., organic-rich shale, oil shale and coal) and the organic matter within the rock matrix that is insoluble in organic solvents is named kerogen. The analyses are undertaken by various laboratories in service and exploration companies using a range of instruments. Data includes the borehole or field site location, sample depth, stratigraphy, analytical methods, other relevant metadata, and the molecular composition of the pyrolysates. The concentrations of the aliphatic hydrocarbon, aromatic hydrocarbon and organic sulfur compounds are given in several units of measure [e.g., percent (resolved compounds) in the S2 peak (wt% S2), milligrams per gram of rock (mg/g rock), micrograms per gram of kerogen (mg/g kerogen) etc.].</div><div><br></div><div>These data are used to determine the organic richness, kerogen type and thermal maturity of source rocks in sedimentary basins. The results are used as input parameters in basin analysis and petroleum systems modelling to evaluate the potential for hydrocarbon generation in a sedimentary basin. These data are collated from destructive analysis reports (DARs), well completion reports (WCRs) and literature. The data are delivered in the Source Rock Pyrolysis-Gas Chromatography web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div><div><br></div>
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The Source Rock and Fluids Atlas delivery and publication services provide up-to-date information on petroleum (organic) geochemical and geological data from Geoscience Australia's Organic Geochemistry Database (ORGCHEM). The sample data provides the spatial distribution of petroleum source rocks and their derived fluids (natural gas and crude oil) from boreholes and field sites in onshore and offshore Australian basins. The services provide characterisation of source rocks through the visualisation of Pyrolysis, Organic Petrology (Maceral Groups, Maceral Reflectance) and Organoclast Maturity data. The services also provide molecular and isotopic characterisation of source rocks and petroleum through the visualisation of Bulk, Whole Oil GC, Gas, Compound-Specific Isotopic Analyses (CSIA) and Gas Chromatography-Mass Spectrometry (GCMS) data tables. Interpretation of these data enables the characterisation of petroleum source rocks and identification of their derived petroleum fluids that comprise two key elements of petroleum systems analysis. The composition of petroleum determines whether or not it can be an economic commodity and if other processes (e.g. CO2 removal and sequestration; cryogenic liquefaction of LNG) are required for development.
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<div>The Birrindudu Basin is a region of focus for the second phase of the Geoscience Australia’s Exploring for the Future (EFTF) program (2020–2024). The Paleo to Mesoproterozoic Birrindudu Basin is an underexplored frontier basin located in northwestern Northern Territory and northeastern Western Australia. Interpretation of industry seismic data indicates it contains strata of similar age to the prospective McArthur Basin, South Nicholson region and Mount Isa Province, but remains comparatively poorly understood. Furthermore, much of the age of the stratigraphy of the Birrindudu Basin, particularly the younger stratigraphic units, and regional correlations to the greater McArthur Basin remains provisional and speculative. </div><div><br></div><div>This report presents data from Rock-Eval pyrolysis analyses undertaken by Geoscience Australia on selected rock samples to establish their total organic carbon content, hydrocarbon-generating potential and thermal maturity from 178 drill core samples from six drill holes intersecting units of the Birrindudu Basin including: 99VRNTGSDD1, 99VRNTGSDD2, WLMB001B, LBD2, LMDH4, and ANT003. </div><div><br></div>