<div>Strontium isotopes (87Sr/86Sr) are useful to trace processes in the Earth sciences as well as in forensic, archaeological, palaeontological, and ecological sciences. As very few large-scale Sr isoscapes exist in Australia, we have identified an opportunity to determine 87Sr/86Sr ratios on archived fluvial sediment samples from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa; last access: 15 December 2022). The present study targeted the northern parts of Western Australia, the Northern Territory and Queensland, north of 21.5 °S. The samples were taken mostly from a depth of ~60-80 cm in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse (< 2 mm) grain-size fraction was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release <em>total</em> Sr. The Sr was then separated by chromatography and the 87Sr/86Sr ratio determined by multicollector-inductively coupled plasma mass spectrometry. Results demonstrate a wide range of Sr isotopic values (0.7048 to 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and smooth gradients), large-scale (> 100 km) patterns that appear to be broadly consistent with surface geology, regolith/soil type, and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a > 500 km-long northwest-southeast-trending unradiogenic anomaly (87Sr/86Sr < 0.7182). Where sedimentary carbonate or mafic/ultramafic igneous rocks dominate, low to moderate 87Sr/86Sr values are generally recorded (medians of 0.7387 and 0.7422, respectively). In proximity to the outcropping Proterozoic metamorphic basement of the Tennant, McArthur, Murphy and Mount Isa geological regions, conversely, radiogenic 87Sr/86Sr values (> 0.7655) are observed. A potential correlation between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith Sr isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g. weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting Sr isoscape and future models derived therefrom can also be utilised in forensic, archaeological, paleontological and ecological studies that aim to investigate, e.g., past and modern animal (including humans) dietary habits and migrations. The new spatial Sr isotope dataset for the northern Australia region is publicly available (de Caritat et al., 2022a; https://dx.doi.org/10.26186/147473; last access: 15 December 2022).</div> <b>Citation:</b> de Caritat, P., Dosseto, A., and Dux, F.: A strontium isoscape of northern Australia, <i>Earth Syst. Sci. Data</i>, 15, 1655–1673, https://doi.org/10.5194/essd-15-1655-2023, <b>2023</b>.

<div>The soil gas database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for gas analyses undertaken by Geoscience Australia's laboratory on soil samples taken from shallow (down to 1 m below the surface) percussion holes. Data includes the percussion hole field site location, sample depth, analytical methods and other relevant metadata, as well as the molecular and isotopic compositions of the soil gas with air included in the reported results. Acquisition of the molecular compounds are by gas chromatography (GC) and the isotopic ratios by gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS). The concentrations of argon (Ar), carbon dioxide (CO₂), nitrogen (N₂) and oxygen (O₂) are given in mole percent (mol%). The concentrations of carbon monoxide (CO), helium (He), hydrogen (H₂) and methane (C₁, CH₄) are given in parts per million (ppm). Compound concentrations that are below detection limit (BDL) are reported as the value -99999. The stable carbon (¹³C/¹²C) and nitrogen (¹⁵N/¹⁴N) isotopic ratios are presented in parts per mil (‰) and in delta notation as δ¹³C and δ¹⁵N, respectively.</div><div><br></div><div>Determining the individual sources and migration pathways of the components of natural gases found in the near surface are useful in basin analysis with derived information being used to support exploration for energy resources (petroleum and hydrogen) and helium in Australian provinces. These data are collated from Geoscience Australia records with the results being delivered in the Soil Gas web services on the Geoscience Australia Data Discovery portal at https://portal.ga.gov.au which will be periodically updated.</div>

<div>Magmatic arcs represent a critical source of modern civilisation’s mineral wealth, with their importance only enhanced by the ongoing global transition to a low-carbon society. The ~830-495 Ma Delamerian Orogen, formed at Australia’s eastern cratonic margin, represents rocks ascribed to rift/passive-margin, convergent margin arc, orogenic, and post-orogenic settings. However, poor exposure has limited exploration activity across much of the orogen, despite demonstrated potential for numerous mineral systems. To address this issue, an orogen-wide zircon Hf-O isotope and trace element survey was performed on 55 magmatic samples to constrain the crustal architecture, evolution, and fertility of the Delamerian Orogen, and in turn map parameters that can be used as a guide to mineral potential. These new data define two broad magmatic episodes at: (1) ~585-480 Ma, related to rift/passive margin, convergent arc, orogenic, and post-orogenic activity (Delamerian Cycle); and (2) magmatism associated with the ~490-320 Ma Lachlan Orogen, with peaks at ~420 Ma (onshore, Tabberabberan Cycle) and ~370 Ma (western Tasmania). Isotopic and geochemical mapping of these events show that the ~585-480 Ma Delamerian Cycle has significant orogen-wide variation in magmatic Hf-O isotopes and oxidation-state, suggesting a spatial variation in the occurrence and type of potential mineral systems. The ~420 Ma magmatic event involved predominantly mantle-like Hf-O and oxidised magmatism, whilst the ~370 Ma magmatism shows opposing features. In general, The potential to host Cu-Au porphyry and VMS mineralisation (e.g., Stavely, Koonenberry) is present, but restricted, whereas signatures favourable for Sn-W granite-hosted systems (e.g., Tasmania), are more common. These new data constrain time-space variations in magma composition that provide a valuable geological framework for mineral system fertility assessments across the Delamerian Orogen. Furthermore, these data and associated maps can used to assess time-space mineral potential and facilitate more effective exploration targeting in this covered region.</div> <b>Citation:</b> Mole, D., Bodorkos, S., Gilmore, P.J., Fraser, G., Jagodzinski, E.A., Cheng, Y., Clark, A.D., Doublier, M., Waltenberg, K., Stern, R.A., Evans, N.J., 2023. Architecture, evolution and fertility of the Delamerian Orogen: Insights from zircon. In: Czarnota, K. (ed.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, <a href+"https://dx.doi.org/10.26186/148981">https://dx.doi.org/10.26186/148981</a>

<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to a low emissions economy, strong resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, is an eight year, $225 m investment by the Australian Government. </div><div>As part of this program, Geoscience Australia led two deep crustal reflection seismic surveys in the South Nicholson region, revealing the existence of the Carrara Sub-basin, a large sedimentary depocentre up to 8 km deep, beneath the Georgina Basin (Carr et al., 2019; 2020). The depocentre is believed to contain thick sequences of highly prospective Proterozoic rocks for base metals and unconventional hydrocarbons. To confirm geological interpretations and assess resource potential, the National Drilling Initiative, NDI Carrara 1 stratigraphic drill hole was completed in late 2020, as a collaboration between Geoscience Australia, the Northern Territory Geological Survey (NTGS) and the MinEx CRC (Geoscience Australia, 2021). NDI Carrara 1 is located on the western flank of the Carrara Sub-basin on the South Nicholson seismic line (17GA-SN1) (Figure 1.1; Figure 1.2), reaching a total depth of 1751 m, intersecting sedimentary rocks comprising ca. 630 m of Cambrian calcareous shales of the Georgina Basin and ca. 1100 m of Proterozoic carbonates and siliciclastics that include black shales of the Carrara Sub-basin.</div><div>This report presents data on selected rock samples from NDI Carrara&nbsp;1, conducted by the Mawson Analytical Spectrometry Services, University of Adelaide, under contract to Geoscience Australia. These results include bulk carbon isotope ratios (δ13C) of bitumens and isolated kerogens. In addition, a selection of 10 samples was analysed at Geoscience Australia for comparison purposes.</div><div><br></div>

<div>This dataset comprises hydrochemistry results for groundwater, surface water, and rainwater samples collected as part of the Upper Darling Floodplain groundwater study. Associated methods, interpretation, and integration with other datasets are found in the Upper Darling Floodplain geological and hydrogeological assessment (Geoscience Australia Ecat ID:149689). This project is part of the Exploring for the Future (EFTF) program, an eight-year, $225 million Australian Government funded geoscience data and precompetitive information acquisition program. The dataset contains 68 groundwater samples, 17 surface water samples, and four rainwater samples. Groundwater samples are from the Cenozoic formations within the alluvium of the Darling River, the Great Artesian Basin, and the Murray geological basin. Surface water samples are from the Darling River, and rainwater samples were taken within the study area. Subsets of the samples were analysed for major ions and trace metals, stable isotopes of water (δ2H and δ18O), radiocarbon (14C), stable carbon isotopes (δ13C), strontium isotopes (87Sr/86Sr), sulfur hexafluoride (SF6), chlorofluorocarbon (CFC) isotopes, chlorine-36 (36Cl), noble gases, and Radon-222. The results were used to inform a range of hydrogeological questions including aquifer distribution and quality, inter-aquifer connectivity, and groundwater-surface water connectivity.&nbsp;</div><div><br></div>

<div>The Proterozoic basins of northern Australia have been the focus of regional hydrocarbon prospectivity studies undertaken by the Exploring for the Future&nbsp;program dedicated to increasing investment in resource exploration in northern Australia. As part of this program, a compilation of the compound-specific isotopic compositions of linear alkanes in source extracts, oils and oil stains from 21 boreholes&nbsp;of the greater McArthur Basin has been completed. The samples were analysed in Geoscience Australia’s Isotope and Organic Geochemistry Laboratory and the stable carbon and hydrogen isotopic data of individual alkanes are released in this report. </div>

<div>Archean greenstone belts are a vital window into the tectonostratigraphic processes that operated in the early Earth and the geodynamics that drove them. However, the majority of greenstone belts worldwide are highly-deformed, complicating geodynamic interpretations. The volcano-sedimentary sequence of the 2775-2690 Ma Fortescue Group is different in that it is largely undeformed, offering a unique insight into the architecture of greenstone sequences. In the Fortescue magmatic rocks, geochemical signatures that in deformed belts in the Superior or Yilgarn Cratons might have been interpreted as arc-like, are explained by contamination of rift-related mantle and plume-derived magmas with Pilbara basement crust; understanding the wider geological and structural setting allows a more complete interpretation.</div><div> However, contamination of Fortescue magmas by an enriched sub-continental mantle lithosphere (SCLM) is an alternative hypothesis to the crustal contamination model. If demonstrated, the addition of sediments and fluids to the SCLM, required to form enriched/metasomaytised SCLM, would suggest active subduction prior to the Neoarchean. To test this hypothesis, we collected Hf-O isotopic data on zircons from felsic volcanic rocks throughout the Fortescue Group; if the contamination had a subducted sedimentary component (δ18O>20‰), then the O-isotopes should record a heavy signature.</div><div> The results show that the ca. 2775 Ma Mt Roe Formation has εHfi from 0 to -5.6, and δ18OVSMOW of +4.8- +0.3‰, with the majority of values <+3‰. The ca. 2765 Ma Hardey Formation (mostly sediments) has highly unradiogenic εHfi of -5 to -9.4, and δ18O of +7.8- +6.6‰. The ca. 2730 Ma Boongal Formation displays similar values as for Mt Roe, with εHfi +1.9 to -5.5 and δ18O +3.0 to -0.6‰. The ca. 2720 Ma Tumbiana Formation shows the greatest range in εHfi from +4.9 to -4.6, with δ18O +7.1- +0.7‰, with the majority between +4.5 and +2.5‰. Data from the 2715 Ma Maddina Formation are more restricted, with εHfi between +4.0 and -0.1, and δ18O +5.0- +3.8‰. The youngest formation, the 2680 Ma Jeerinah Formation, has εHfi +2.3 to -6.2, and δ18O +5.1 to -2.1‰.</div><div> Importantly, these data provide little evidence of a cryptic enriched SCLM source in the Fortescue magmas. Furthermore, the dataset contains some of the lightest δ18O data known for Archean zircon, highlighting a ca. 100 Myr period of high-temperature magma-water interaction, with long-term continental emergence implied by the trend to meteoric δ18O compositions. The exception to this is the Hardey Formation, which may have formed via crustal anatexis in a period of reduced heat-flow between the 2775-2665 and 2730-2680 Ma events. Data from the other formations show a broad trend of increasing δ18O and εHf from 2775 to 2680 Ma. We suggest this represents the effects of progressive cratonic rifting, allowing mantle-derived magmas to reach the surface less impeded, and also a decreasing role of meteoric water in the rift zone as the sea invades. As a result, the εHf and δ18O data from the Fortescue Group represent the evolving nature of an Archean rift zone, from an emergent volcanic centre, to a submarine environment.</div><div><br></div>This Abstract was submitted/presented to the 2023 6th International Archean Symposium (6IAS) 25 - 27 July (https://6ias.org/)

<div>The Roebuck Basin on Australia’s offshore north-western margin is the focus of regional energy exploration activity. Drilling in the Roebuck Basin resulted in oil and gas discoveries at Phoenix South&nbsp;1 (2014), Roc&nbsp;1 (2015–2016) and Dorado&nbsp;1 (2018) in the Bedout Sub-basin (Figure 1‑2) and demonstrated the presence of a petroleum system in Lower Triassic strata. These discoveries have been evaluated for development and production with infill drilling at Roc&nbsp;2 (2016), Phoenix South&nbsp;2 (2016), Phoenix South&nbsp;3 (2018), Dorado&nbsp;2 (2019), and Dorado&nbsp;3 (2019). Recent drilling by Santos (2022) has resulted in the discovery of oil at Pavo&nbsp;1 (2022) and hydrocarbon shows at Apus&nbsp;1 (2022).</div><div><br></div><div>To complement this industry work, Geoscience Australia’s Offshore Energy Systems program produces pre-competitive information to assist with the evaluation of the energy and resource potential of the central North West Shelf, including both hydrogen and helium resources, and to attract exploration investment to Australia. As part of this program, determination of the molecular and noble gas isotopic composition of natural gases from selected petroleum wells in the Roebuck Basin were undertaken by Smart Gas Sciences, under contract to Geoscience Australia, with results from these analyses being released in this report. This report provides additional gas data to determine the sources of natural gases in the Roebuck Basin and build on previously established gas-gas correlations. Noble gas isotopic data can be used in conjunction with carbon and hydrogen isotopic data to determine the origin of both inorganic and organic (hydrocarbon) gases. This information can be used in future geological programs to determine the source and distribution of hydrogen and helium in natural gases and support acreage releases by the Australian Government.</div><div><br></div>

<div>Lithospheric and crustal architecture — the framework of major tectonic blocks, terranes and their boundaries — represents a fundamental first-order control on major geological systems, including the location of world-class mineral camps. Traditionally, lithospheric and crustal architecture are constrained using predominantly geophysical methods. However, Champion and Cassidy (2007) pioneered the use of regional Sm–Nd isotopic data from felsic igneous rocks to produce isotopic contour maps of the Yilgarn Craton, demonstrating the effectiveness of ‘isotopic mapping’, and the potential to map ‘time-constrained’ crustal architecture. Mole et al. (2013) demonstrated the association between lithospheric architecture and mineral systems, highlighting the potential of isotopic mapping as a greenfield area selection tool. Additional work, using Lu-Hf isotopes (Mole et al., 2014), demonstrated that the technique could constrain a range of temporal events via ‘time-slice mapping’, explaining how Ni-Cu-PGE mineralized komatiite systems migrated with the evolving lithospheric boundary of the Yilgarn Craton from 2.9 to 2.7 Ga. Similar studies have since been conducted in West Africa (Parra-Avila et al., 2018), Tibet (Hou et al., 2015), and Canada (Bjorkman, 2017; Mole et al., 2021; 2022). This work continues in Geoscience Australia’s $225 million Exploring for the Future program (2016-present). Isotopic mapping, which forms an integral part of a combined geology-geophysics-geochemistry approach, is currently being applied across southeast Australia, covering the eastern Gawler Craton, Delamerian Orogen, and western Lachlan Orogen, encompassing more than 3 Gyrs of Earth history with demonstrable potential for large mineral systems.</div><div> <b>Reference(s):</b></div><div> Bjorkman, K.E., 2017. 4D crust-mantle evolution of the Western Superior Craton: Implications for Archean granite-greenstone petrogenesis and geodynamics. University of Western Australia, PhD Thesis, 134 pp.</div><div> Champion, D.C. and Cassidy, K.F., 2007. An overview of the Yilgarn Craton and its crustal evolution. In: F.P. Bierlein and C.M. Knox-Robinson (Editors), Proceedings of Geoconferences (WA) Inc. Kalgoorlie '07 Conference. Geoscience Australia Record 2007/14, Kalgoorlie, Western Australia, pp. 8-13.</div><div> Hou, Z., Duan, L., Lu, Y., Zheng, Y., Zhu, D., Yang, Z., Yang, Z., Wang, B., Pei, Y., Zhao, Z. and McCuaig, T.C., 2015. Lithospheric architecture of the Lhasa terrane and its control on ore deposits in the Himalayan-Tibetan orogen. Economic Geology, 110(6): 1541-1575.</div><div> Mole, D.R., Fiorentini, M.L., Cassidy, K.F., Kirkland, C.L., Thebaud, N., McCuaig, T.C., Doublier, M.P., Duuring, P., Romano, S.S., Maas, R., Belousova, E.A., Barnes, S.J. and Miller, J., 2013. Crustal evolution, intra-cratonic architecture and the metallogeny of an Archaean craton. Geological Society, London, Special Publications, 393: pp. 23-80.</div><div> Mole, D.R., Fiorentini, M.L., Thebaud, N., Cassidy, K.F., McCuaig, T.C., Kirkland, C.L., Romano, S.S., Doublier, M.P., Belousova, E.A., Barnes, S.J. and Miller, J., 2014. Archean komatiite volcanism controlled by the evolution of early continents. Proceedings of the National Academy of Sciences, 111(28): 10083-10088.</div><div> Mole, D.R., Thurston, P.C., Marsh, J.H., Stern, R.A., Ayer, J.A., Martin, L.A.J. and Lu, Y., 2021. The formation of Neoarchean continental crust in the south-east Superior Craton by two distinct geodynamic processes. Precambrian Research, 356: 106104.</div><div> Mole, D.R., Frieman, B.M., Thurston, P.C., Marsh, J.H., Jørgensen, T.R.C., Stern, R.A., Martin, L.A.J., Lu, Y.J. and Gibson, H.L., 2022. Crustal architecture of the south-east Superior Craton and controls on mineral systems. Ore Geology Reviews, 148: 105017.</div><div> Parra-Avila, L.A., Belousova, E., Fiorentini, M.L., Eglinger, A., Block, S. and Miller, J., 2018. Zircon Hf and O-isotope constraints on the evolution of the Paleoproterozoic Baoulé-Mossi domain of the southern West African Craton. Precambrian Research, 306: 174-188.</div><div> This Abstract was submitted/presented to the Target 2023 Conference 28 July (https://6ias.org/target2023/)

<div>The Yilgarn Craton of Western Australia represents one of the largest pieces of Precambrian crust on Earth, and a key repository of information on the Meso-Neoarchean period. Understanding the crustal, tectonic, thermal, and chemical evolution of the craton is critical in placing these events into an accurate geological context, as well as developing holistic tectonic models for the Archean Earth. In this study, we collected a large U-Pb (420 collated samples) and Hf isotopic (2163 analyses) dataset on zircon to investigate the evolution of the craton. These data provide strong evidence for a Hadean-Eoarchean origin for the Yilgarn Craton from mafic crust at ca. 4000 Ma. This ancient cratonic nucleus was subsequently rifted, expanded and reworked by successive crustal growth events at ca. 3700 Ma, ca. 3300 Ma, 3000-2900 Ma, 2825-2800 Ma, and ca. 2730-2620 Ma. The <3050 Ma crustal growth events correlate broadly with known komatiite events, and patterns of craton evolution, revealed by Hf isotope time-slice mapping, image the periodic break-up of the Yilgarn proto-continent and the formation of rift-zones between the older crustal blocks. Crustal growth and new magmatic pulses were focused into these zones and at craton margins, resulting in continent growth via internal (rift-enabled) expansion, and peripheral (crustal extraction at craton margins) magmatism. Consequently, we interpret these major geodynamic processes to be analogous to plume-lid tectonics, where the majority of tonalite-trondhjemite-granodiorite (TTG) felsic crust, and later granitic crust, was formed by reworking of hydrated mafic rocks and TTGs, respectively, via a combination of infracrustal and/or drip-tectonic settings. While this process of crust formation and evolution is not necessarily restricted to a specific geodynamic system, we find limited direct evidence that subduction-like processes formed a major tectonic component, aside from re-docking the Narryer Terrane to the craton at ca. 2740 Ma. Overall, these 'rift-expansion' and 'craton margin' crustal growth process led to an intra-cratonic architecture of younger, juvenile terranes located internal and external to older, long-lived, reworked crustal blocks. This framework provided pathways that localized later magmas and fluids, driving the exceptional mineral endowment of the Yilgarn Craton.</div> This Abstract/Poster was submitted to & presented at the 2023 6th International Archean Symposium (6IAS) 25 - 27 July (https://6ias.org/)