<div><strong>Output Type: </strong>Exploring for the Future Extended Abstract</div><div><br></div><div><strong>Short Abstract: </strong>Groundwater geochemistry is an important and often under-appreciated medium to understand geology below surface and is a valuable tool as part of a regional mineral exploration program. This study presents an assessment of hydrogeochemical results from the Curnamona and Mundi region with respect to their insights into mineral prospectivity and characterisation of groundwater baselines. The work is a collaboration with the Mineral Exploration Cooperative Research Centre (MinEx CRC), the Geological Survey of New South Wales and the Geological Survey of South Australia as part of Geoscience Australia’s Exploring for the Future program. It combines new and legacy groundwater chemistry from 297 samples to identify multiple elevated multi-element anomalies (Ag, Pb, Cd) and signatures of sulfide mineralisation (d34S and sulfur excess), which are interpreted as potential features from subsurface Broken Hill Type mineralisation (Pb-Zn-Ag). Additional multi-element anomalies (Cu, Mo, Co, Au) may be attributable to Cu-Au, Cu-Mo and Au mineralisation. We then apply hierarchical cluster analysis to understand sample hydrostratigraphy and characterise robust hydrogeochemical baselines for the major aquifer systems in the region. This reveals that the majority of anomalies are restricted to groundwaters derived from basement fractured rock aquifer systems, with a couple anomalies observed in the Lake Eyre Basin cover, which helps narrow the search-space for future groundwater-based mineral exploration in this region (to prioritise these aquifers and anomalies). In addition, we demonstrate the capability of these local hydrogeochemical baselines to support more sensitive resolution of hydrogeochemical anomalies relating to mineralisation, as well as reveal hydrogeological processes such as mixing.</div><div><br></div><div><strong>Citation: </strong>Reid, N., Schroder, I., Thorne, R., Folkes, C., Hore, S., Eastlake, M., Petts, A., Evans, T., Fabris, A., Pinchand, T., Henne A., & Palombi, B.R., 2024. Hydrogeochemistry of the Curnamona and Mundi region. In: Czarnota, K. (ed.) Exploring for the Future: Extended Abstracts. Geoscience Australia, Canberra. https://doi.org/10.26186/149509</div>

<div>NDI Carrara 1 is a deep stratigraphic borehole that was drilled in 2020 under the MinEx CRC’s National Drilling Initiative (NDI) program in collaboration with Geoscience Australia and the Northern Territory Geological Survey. NDI Carrara 1 is the first stratigraphic test of the recently described Carrara Sub-basin, a Proterozoic aged depocentre located in the South Nicholson region of northwest Queensland and the Northern Territory. The borehole was drilled to a total depth of 1751 m and penetrated a succession of Cambrian aged Georgina Basin carbonate and siliciclastic rocks that unconformably overly a thick succession of Proterozoic age siliciclastic and carbonate-rich sediments. Although drilled on the western flank of the Carrara Sub-basin, NDI Carrara 1 did not penetrate to basement. Interpretation of the L210 deep-crustal seismic survey suggests that further Proterozoic sedimentary packages known from the northern Lawn Hill Platform in northwest Queensland are likely to be found underlying the succession intersected in NDI Carrara 1. The borehole was continuously cored from 283 m to total depth, and an extensive suite of wireline logs was acquired. Geoscience Australia and partners have undertaken an extensive analytical program to understand the depositional, structural, and diagenetic history of the sediments intersected in NDI Carrara 1. This program includes a targeted petrophysical study that aims to characterise the physical properties of these Proterozoic rocks through laboratory analysis of core samples, the results of which are summarised in this data release.</div><div><br></div><div>This data release provides data from new X-ray Computerised Tomography (XCT) scanning and gas porosity and permeability testing for 32 samples from NDI Carrara 1. Additional low permeability tests were undertaken on select samples that were identified as being ultra-tight (permeability <1 μD). These tests were performed at the CSIRO Geomechanics and Geophysics Laboratory in Perth, during January to June 2022. The full results as provided by CSIRO to Geoscience Australia are provided as an attachment to this document.&nbsp;</div>

<div>A multi-disciplinary program of geological and geophysical data collection and integration, focussed on the Delamerian Orogen, was undertaken as part of Geoscience Australia’s Exploring for the Future (EFTF) program and the Mineral Exploration Cooperative Research Centres (MinEx CRC) National Drilling Initiative (NDI).&nbsp;In this study, we integrate learnings from these data with existing geological and geophysical data to refine the basement geology of the Loch Lilly-Kars Belt, Lake Wintlow Belt and Wilcannia High. Our interpretation provides a revised geological framework for a frontier exploration region in the Delamerian Orogen.&nbsp;This product includes ESRI shape files and layer files, accompanying notes, and several appendices containing new detrital zircon U-Pb geochronology data from the map area as well as the broader Delamerian Orogen.</div>

<div>This study was commissioned by Geoscience Australia (GA) to produce a report on seal capacity of select samples from the deep stratigraphic hole NDI Carrara 1, located in the Proterozoic Carrara Sub-basin in the Northern Territory. Plugs were taken from depths of interest and analysed via mercury injection capillary pressure testing. Results were provided as two reports, Part A and Part B and demonstrate that the analysed samples are capable of sealing very large columns of both methane and carbon dioxide.</div>

<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources.</div><div><br></div><div>In order to gain insights into the resource potential of the South Nicholson region, a key region of focus for EFTF, National Drilling Initiative (NDI) Carrara&nbsp;1 stratigraphic drill hole was completed in late 2020, as a collaboration between Geoscience Australia, the Northern Territory Geological Survey (NTGS), and the MinEx CRC. NDI Carrara&nbsp;1 is the first drill hole to intersect the, as yet, undifferentiated Proterozoic rocks of the newly defined Carrara Sub-Basin within the South Nicholson region. NDI Carrara&nbsp;1 is located on the western flank of the Carrara Sub-basin, reaching a total depth of 1751&nbsp;m, intersecting ca. 630&nbsp;m of Cambrian Georgina Basin overlying ca. 1100&nbsp;m of Proterozoic carbonates, black shales and minor siliciclastics.</div><div><br></div><div>Geoscience Australia is undertaking a range of investigations on the lithology, stratigraphy and geotechnical properties of NDI Carrara&nbsp;1 based on wireline data, as well as undertaking a range of analyses of over 400 physical samples recovered through the entire core. These analyses include geochronology, isotopic studies, mineralogy, inorganic and organic geochemistry, petrophysics, geomechanics, thermal maturity, and petroleum systems investigations. Hylogger™ data is available at the NTGS Geoscience Exploration and Mining Information System (GEMIS) webpage.</div><div><br></div><div>This data release presents results for analyses on selected rock samples from NDI Carrara 1, conducted by the Mawson Analytical Spectrometry Services, University of Adelaide, under contract to Geoscience Australia. These results include:</div><div><br></div><div>1.&nbsp;&nbsp;&nbsp;&nbsp;Carbon (δ13C), oxygen (δ18O) and strontium (87Sr/86Sr) isotopes on carbonate bearing samples, and</div><div>2.&nbsp;&nbsp;&nbsp;&nbsp;Trace element data on the leachates prepared for 87Sr/86Sr ratio analyses.</div><div><br></div>

<div>The South Nicholson National Drilling Initiative (NDI) Carrara 1 stratigraphic drill hole was completed in late 2020, as a collaboration between Geoscience Australia, the Northern Territory Geological Survey (NTGS), and the MinEx CRC. The drilling aimed to gather new subsurface data on the potential mineral and energy resources in the newly identified Carrara Sub-basin. NDI Carrara 1 is located in the eastern Northern Territory, on the western flanks of the Carrara Sub-basin on the South Nicholson Seismic line, reaching a total depth of 1751 m, intersecting ca. 630 m of Cambrian Georgina Basin overlying ca. 1100 m of Proterozoic carbonates, black shales and minor siliciclastics (https://portal.ga.gov.au/bhcr/minerals/648482).</div><div>&nbsp;</div><div>Following a public data release of the borehole completion report, CSIRO was contracted by Geoscience Australia (GA) under the Exploring for the Future program to analyse samples from NDI Carrara 1 for quantitative bulk and clay fraction analysis. This report presents results for quantitative bulk and clay (<2 µm) fraction analysis by X-ray powder diffraction (XRD) on 32 bulk core samples from the NDI Carrara 1. Samples were prepared and analysed at the CSIRO’s Waite Laboratories in South Australia.</div><div><br></div>

<div>NDI Carrara 1 is a deep stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first test of the Carrara Sub-Basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) recently acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1100 m of Proterozoic sedimentary rocks uncomformably overlain by 630 m of Cambrian Georgina Basin carbonates. A comprehensive geochemical program designed to provide information about the region’s resource potential was carried out on samples collected at up to 4 meter intervals. This report presents data from Rock-Eval pyrolysis analyses undertaken by Geoscience Australia on selected rock samples to establish their total organic carbon content, hydrocarbon-generating potential and thermal maturity.</div>

<div>NDI Carrara&nbsp;1 is a 1751 m stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI). This campaign was a collaboration between Geoscience Australia under the Exploring for the Future program, together with MinEx CRC and the Northern Territory Geological Survey. It is the first drillhole to intersect Proterozoic rocks of the Carrara Sub-basin, a recently discovered depocentre in the South Nicholson region. The drill hole intersected ~625 m of the Paleozoic Georgina Basin, which overlies ~1120 m of Proterozoic carbonates, black shales and siliciclastic rocks, with hydrocarbon shows encountered in both the Paleozoic and Proterozoic sections. Following the completion of the drillhole, a comprehensive analytical program was carried out by Geoscience Australia to better understand the geology of the Carrara Sub-basin and its resource potential.</div><div><br></div><div>Here we present new high-resolution strontium (87Sr/86Sr), carbon (δ13C) and oxygen (δ18O) isotope data from carbonate bearing samples of the Paleozoic Georgina Basin and the Proterozoic Lawn Hill Formation intersected in NDI Carrara&nbsp;1. The aim of this data acquisition was to provide an improved understanding of the paleo-depositional environments and local/global chemostratigraphy trends recorded in the Carrara Sub-basin. </div><div><br></div><div>The majority of samples show significant alteration and thus caution should be exercised when using this data for assessing primary depositional conditions and contemporary sea-water chemistry. Despite the altered nature of most samples, samples belonging to undifferentiated Georgina Basin preserve 87Sr/86Sr ratios close to that of mid-Cambrian seawater, indicating the sampled intervals of Georgina Basin were likely connected to the global Cambrian ocean.&nbsp;Two small positive δ13C excursions (with positive shift in δ18O) within Georgina Basin samples may coincide with reported mid-Cambrian positive δ13C global marine excursions. </div><div><br></div><div>The least altered samples from the Proterozoic Lawn Hill Formation show more radiogenic 87Sr/86Sr values than the expected value of coeval mid-Proterozoic ocean at ~1600 Ma. These radiogenic 87Sr/86Sr values may reflect (i) influx of terrigenous material into a restricted basin with reduced interaction with the global ocean, or (ii) secondary overprinting by more radiogenic diagenetic fluids.</div> Abstract/Poster submitted and presented at 2023 Australian Earth Science Convention (AESC), Perth WA (https://2023.aegc.com.au/)

<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to a low emissions economy, strong resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, is an eight year, $225 m investment by the Australian Government. </div><div>As part of this program, Geoscience Australia led two deep crustal reflection seismic surveys in the South Nicholson region, revealing the existence of the Carrara Sub-basin, a large sedimentary depocentre up to 8 km deep, beneath the Georgina Basin (Carr et al., 2019; 2020). The depocentre is believed to contain thick sequences of highly prospective Proterozoic rocks for base metals and unconventional hydrocarbons. To confirm geological interpretations and assess resource potential, the National Drilling Initiative, NDI Carrara 1 stratigraphic drill hole was completed in late 2020, as a collaboration between Geoscience Australia, the Northern Territory Geological Survey (NTGS) and the MinEx CRC (Geoscience Australia, 2021). NDI Carrara 1 is located on the western flank of the Carrara Sub-basin on the South Nicholson seismic line (17GA-SN1) (Figure 1.1; Figure 1.2), reaching a total depth of 1751 m, intersecting sedimentary rocks comprising ca. 630 m of Cambrian calcareous shales of the Georgina Basin and ca. 1100 m of Proterozoic carbonates and siliciclastics that include black shales of the Carrara Sub-basin.</div><div>This report presents data on selected rock samples from NDI Carrara&nbsp;1, conducted by the Mawson Analytical Spectrometry Services, University of Adelaide, under contract to Geoscience Australia. These results include bulk carbon isotope ratios (δ13C) of bitumens and isolated kerogens. In addition, a selection of 10 samples was analysed at Geoscience Australia for comparison purposes.</div><div><br></div>

<div>The Carrara Sub-basin, discovered in 2017 based on interpretation of 2D deep seismic surveys acquired by Geoscience Australia, is a large sedimentary depocentre in the South Nicholson region straddling the Northern Territory and Queensland. It was interpreted to contain up to 8 km of Paleoproterozoic to Cambrian rocks including stratigraphic equivalents to the Isa Superbasin, South Nicholson Group and Georgina Basin. In order to validate these stratigraphic interpretations and assess the resource prospectivity of the Carrara Sub-basin, the South Nicholson National Drilling Initiative (NDI) Carrara 1 stratigraphic drill hole was completed in late 2020 as a collaboration between the MinEx Cooperative Research Centre, Geoscience Australia and the Northern Territory Geological Survey. NDI Carrara 1 was drilled on the western flanks of the Carrara Sub-basin and reached a total depth of 1751&nbsp;m, intersecting ca. 630&nbsp;m of Cambrian Georgina Basin overlying ca. 1100&nbsp;m of Proterozoic carbonates, black shales and minor siliciclastics. More than 400 NDI Carrara&nbsp;1 physical samples were analysed as part of an extensive geochemical program, including Rock-Eval pyrolysis and compositional analyses of hydrocarbon shows, whose results and implications for energy prospectivity are summarised here.</div> This Abstract was submitted/presented to the 2022 Australian Organic Geochemistry Conference 27-29 November (https://events.csiro.au/Events/2022/October/5/Australian-Organic-Geochemistry-Conference)