Noble gas isotopes
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<div>A regional hydrocarbon prospectivity assessment has been undertaken of the offshore Otway Basin by the Offshore Energy Systems Section. This program was designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the offshore Otway Basin and attract exploration investment to Australia. The inboard part of the basin is an established hydrocarbon province with onshore and shallow-water offshore discoveries, whereas the outboard deep-water region, where water depths range from 500 to 6300 m, is comparatively underexplored and considered a frontier area.</div><div><br></div><div>As part of this program, molecular and noble gas isotopic analyses were undertaken by Smart Gas Sciences, under contract to Geoscience Australia on available gas samples from the Waarre Formation in the Shipwreck Trough in the offshore eastern Otway Basin, with data from these analyses being released in this report. This report provides additional compositional information for gases in the Waarre Formation reservoirs and builds on previously established gas-gas correlations and gas-oil correlations. Noble gas isotopic data can be used in conjunction with carbon and hydrogen isotopic data to determine the origin of both inorganic and organic (hydrocarbon) gases. This information can be used in future geological programs to determine the source and distribution of hydrogen and helium in natural gases and support acreage releases by the Australian Government.</div><div><br></div><div><br></div>
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<div>The Roebuck Basin on Australia’s offshore north-western margin is the focus of regional energy exploration activity. Drilling in the Roebuck Basin resulted in oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015–2016) and Dorado 1 (2018) in the Bedout Sub-basin (Figure 1‑2) and demonstrated the presence of a petroleum system in Lower Triassic strata. These discoveries have been evaluated for development and production with infill drilling at Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018), Dorado 2 (2019), and Dorado 3 (2019). Recent drilling by Santos (2022) has resulted in the discovery of oil at Pavo 1 (2022) and hydrocarbon shows at Apus 1 (2022).</div><div><br></div><div>To complement this industry work, Geoscience Australia’s Offshore Energy Systems program produces pre-competitive information to assist with the evaluation of the energy and resource potential of the central North West Shelf, including both hydrogen and helium resources, and to attract exploration investment to Australia. As part of this program, determination of the molecular and noble gas isotopic composition of natural gases from selected petroleum wells in the Roebuck Basin were undertaken by Smart Gas Sciences, under contract to Geoscience Australia, with results from these analyses being released in this report. This report provides additional gas data to determine the sources of natural gases in the Roebuck Basin and build on previously established gas-gas correlations. Noble gas isotopic data can be used in conjunction with carbon and hydrogen isotopic data to determine the origin of both inorganic and organic (hydrocarbon) gases. This information can be used in future geological programs to determine the source and distribution of hydrogen and helium in natural gases and support acreage releases by the Australian Government.</div><div><br></div>
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<div>The onshore Canning Basin in Western Australia was the focus of a regional hydrocarbon prospectivity assessment undertaken by the Exploring for the Future (EFTF) program dedicated to increasing investment in resource exploration in northern Australia, with the objective being to acquire new data and information about the potential mineral, energy and groundwater resources concealed beneath the surface. Significant work has been carried out to deliver new pre-competitive data in the region including new seismic acquisition, drilling of a stratigraphic well, and geochemical analysis from historic exploration wells.</div><div><br></div><div>As part of this program, determination of the molecular and noble gas isotopic composition of natural gases from selected petroleum wells in the Canning Basin were undertaken by Smart Gas Sciences, under contract to Geoscience Australia, with results from these analyses being released in this report. This report provides additional data to determine the sources of natural gases in the Canning Basin and build on the availability of existing gas data, gas-gas correlations and gas-oil correlations. Noble gas isotopic data can be used in conjunction with carbon and hydrogen isotopic data to determine the origin of both inorganic and organic (hydrocarbon) gases. This information can be used in future geological programs to determine the source and distribution of hydrogen and helium in natural gases and support exploration programs.</div>
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<div>The noble gas database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for molecular and noble gas isotopic analyses on natural gases sampled from boreholes and fluid inclusion gases from rocks sampled in boreholes and field sites. Data includes the borehole or field site location, sample depths, shows and tests, stratigraphy, analytical methods, other relevant metadata, and the molecular and noble gas isotopic compositions for the natural gas samples. The molecular data are presented in mole percent (mol%) and cubic centimetres (at Standard Pressure and Temperature) per cubic centimetre (ccSTP/cc). The noble gas isotopic values that can be measured are; Helium (He, <sup>3</sup>He, <sup>4</sup>He), Neon (Ne, <sup>20</sup>Ne, <sup>21</sup>Ne, <sup>22</sup>Ne), Argon (Ar, <sup>36</sup>Ar, <sup>38</sup>Ar, <sup>40</sup>Ar), Krypton (Kr, <sup>78</sup>Kr, <sup>80</sup>Kr, <sup>82<</sup>Kr, <sup>83</sup>Kr, <sup>84</sup>Kr, <sup>86</sup>Kr) and Xenon (Xe, <sup>124</sup>Xe, <sup>126</sup>Xe, <sup>128</sup>Xe, <sup>129</sup>Xe, <sup>130</sup>Xe, <sup>131</sup>Xe, <sup>132</sup>Xe, <sup>134</sup>Xe, <sup>136</sup>Xe) which are presented in cubic micrometres per cubic centimetre (mcc/cc), cubic nanometres per cubic centimetre (ncc/cc) and cubic picometres per cubic centimetre (pcc/cc). Acquisition of the molecular compounds are by gas chromatography (GC) and the isotopic ratios by mass spectrometry (MS). Compound concentrations that are below the detection limit (BDL) are reported as the value -99999.</div><div><br></div><div>These data provide source information about individual compounds in natural gases and can elucidate fluid migration pathways, irrespective of microbial activity, chemical reactions and changes in oxygen fugacity, which are useful in basin analysis with derived information being used to support Australian exploration for energy resources and helium. These data are collated from Geoscience Australia records and well completion reports. The noble gas data for natural gases and fluid inclusion gases are delivered in the Noble Gas Isotopes web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div><div><br></div><div><br></div>