ORIGIN AND USE OF HELIUM IN AUSTRALIAN NATURAL GASES C. Boreham1, D. Edwards1. R. Poreda2, P. Henson1. 1 Geoscience Australia, Canberra, Australia; 2 University of Rochester, NY, USA Over 800 natural gases representative of Australia's hydrocarbon-producing sedimentary basins have been analyzed for their helium (He) content and around 150 gases for their helium isotopic composition, supplemented by isotopic compositions of the higher noble gases. Australian natural gases have helium abundances to over 10%, with the highest values in the Amadeus Basin, in central Australia, while 3He/4He ratios range from around 0.01 to 4.2 Ra (Figure 1). The onshore Gunnedah Basin of southeastern Australia and the offshore Bass and onshore/offshore Otway basins in southern Australia show the highest 3He/4He ratios, indicating a significant mantle contribution. Interestingly, the offshore Gippsland Basin, adjacent to the Bass Basin, has slightly lower 3He/4He ratios. In the Gunnedah Basin, the associated CO2 has a relatively low abundance compared to extreme concentrations of CO2 in some Otway Basin wells, which are associated with recent volcanism. The onshore Bowen and Cooper basins of eastern Australia, where natural gases are predominately sourced from Permian coals, show intermediate 3He/4He ratios with the former having a higher mantle contribution. At the other end of the spectrum, low 3He/4He ratios characterize natural gases of the offshore North West Shelf (Bonaparte, Browse, Carnarvon) and onshore/offshore Perth basins in northwestern and southwestern Australia, respectively, and radiogenic helium predominates. Hence the sometimes extensive volcanic activity and igneous intrusions in these western basins is not expressed in the helium isotopes. The accompanying high CO2 contents (up to 44%) of some of these North West Shelf gases, together with the carbon isotopic composition of CO2, infer an inorganic source most likely from the thermal decomposition of carbonates. The geochemical data suggest that the origin of helium in Australian natural gas accumulations is region specific and complex with the component gases originating from multiple sources. The relative low CO2/3He ratio for many natural gases indicates a systematic loss of CO2 from most basins. The process by which CO2 has been lost from the system is most likely associated with precipitation of carbonates (Prinzhofer, 2013). The age of the source (and/or reservoir) rock has a primary control on the helium content with radiogenic 4He input increasing with residence time (Figure 1). References: Prinzhofer, A., 2013. Noble gases in oil and gas accumulations. The Noble Gases as Geochemical Tracers. Springer. 225-245.

Over 800 natural gases representative of Australia's hydrocarbon-producing sedimentary basins have been analyzed for their helium abundance and around 150 gases for their helium isotopic composition (supplemented by isotopic compositions of the higher noble gases Ne, Ar, Kr and Xe). Helium shows abundance up to over 10% with the highest values in the Amadeus Basin (central Australia), while ³He/⁴He ratios range from around 0.01 to 4.2 Ra (Figure 1). The Gunnedah Basin of south-east Australia and the Bass and Otway basins in southern Australia show the highest ³He/⁴He ratios, indicating a significant mantle contribution. Interestingly the adjacent Gippsland Basin has slightly lower ³He/⁴He ratios. The associated CO₂ has a relatively low abundance in the Gunnedah Basin (highest ³He/⁴He ratio) compared to some extreme concentrations of CO₂ in the Otway Basin, which are associate with recent volcanism. The onshore Bowen and Cooper basins of eastern Australia, where natural gases are predominately sourced from Permian coals, show intermediate ³He/⁴He ratios with the former having a higher mantle contribution. At the other end of the spectrum, low ³He/⁴He ratios characterize natural gases of the Bonaparte, Browse, Carnarvon and Perth basins in northern and south-western Australia where radiogenic helium predominates. The minor mantle contribution that is inferred from the He isotopes in these regions has resulted from the limited volcanic activity and igneous intrusions throughout the basins' evolution. The accompanying high CO₂ contents of some of these gases, together with their carbon isotopic composition, infer an inorganic source most likely from thermal decomposition of carbonates. The geochemical data suggest that the origin of helium in Australian natural gas accumulations is region specific and complex with the component gases originating from multiple sources. The relative low CO₂/³He ratio for many natural gases indicates a systematic loss of CO₂ from most basins. The process by which CO₂ has been lost from the system is most likely associated with precipitation of carbonates (Prinzhofer, 2013). The age of the source (or reservoir) rock has a primary control on the helium content with radiogenic ⁴He input increasing with residence time (Figure 1). With the recent acceleration in the exploitation of Australia's enormous reserves of natural gas, the LNG processing plants in western, northern and eastern Australia offer the opportunity to commercialize helium in gases with as low as 0.1% He. However, a key factor to the gases monetary value is its inherent N₂ content. From the ¹⁵N/¹⁴N ratios, N₂ associated with mineral decomposition severely impacts the economics of helium extraction. Presented at the 2017 International Meeting in Organic Geochemistry (IMOG)

Australia is about to become the premier global exporter of liquefied natural gas (LNG), bringing increased opportunities for helium extraction. Processing of natural gas to LNG necessitates the exclusion and disposal of nonhydrocarbon components, principally carbon dioxide and nitrogen. Minor to trace hydrogen, helium and higher noble gases in the LNG feed-in gas become concentrated with nitrogen in the non-condensable LNG tail gas. Helium is commercially extracted worldwide from this LNG tail gas. Australia has one helium plant in Darwin where gas (containing 0.1% He) from the Bayu-Undan accumulation in the Bonaparte Basin is processed for LNG and the tail gas, enriched in helium (3%), is the feedstock for helium extraction. With current and proposed LNG facilities across Australia, it is timely to determine whether the development of other accumulations offers similar potential. Geoscience Australia has obtained helium contents in ~800 Australian natural gases covering all hydrocarbon-producing sedimentary basins. Additionally, the origin of helium has been investigated using the integration of helium, neon and argon isotopes, as well as the stable carbon (13C/12C) isotopes of carbon dioxide and hydrocarbon gases and isotopes (15N/14N) of nitrogen. With no apparent loss of helium and nitrogen throughout the LNG industrial process, together with the estimated remaining resources of gas accumulations, a helium volumetric seriatim results in the Greater Sunrise (Bonaparte Basin) > Ichthys (Browse Basin) > Goodwyn–North Rankin (Northern Carnarvon Basin) accumulations having considerably more untapped economic value in helium extraction than the commercial Bayu-Undan LNG development.

<div>The soil gas database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for gas analyses undertaken by Geoscience Australia's laboratory on soil samples taken from shallow (down to 1 m below the surface) percussion holes. Data includes the percussion hole field site location, sample depth, analytical methods and other relevant metadata, as well as the molecular and isotopic compositions of the soil gas with air included in the reported results. Acquisition of the molecular compounds are by gas chromatography (GC) and the isotopic ratios by gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS). The concentrations of argon (Ar), carbon dioxide (CO₂), nitrogen (N₂) and oxygen (O₂) are given in mole percent (mol%). The concentrations of carbon monoxide (CO), helium (He), hydrogen (H₂) and methane (C₁, CH₄) are given in parts per million (ppm). Compound concentrations that are below detection limit (BDL) are reported as the value -99999. The stable carbon (¹³C/¹²C) and nitrogen (¹⁵N/¹⁴N) isotopic ratios are presented in parts per mil (‰) and in delta notation as δ¹³C and δ¹⁵N, respectively.</div><div><br></div><div>Determining the individual sources and migration pathways of the components of natural gases found in the near surface are useful in basin analysis with derived information being used to support exploration for energy resources (petroleum and hydrogen) and helium in Australian provinces. These data are collated from Geoscience Australia records with the results being delivered in the Soil Gas web services on the Geoscience Australia Data Discovery portal at https://portal.ga.gov.au which will be periodically updated.</div>

<b>Organic Geochemistry (ORGCHEM) Schema. Australian Source Rock and Fluid Atlas</b> The databases tables held within Geoscience Australia's Oracle Organic Geochemistry (ORGCHEM) Schema, together with other supporting Oracle databases (e.g., Borehole database (BOREHOLE), Australian Stratigraphic Units Database (ASUD), and the Reservoir, Facies and Shows (RESFACS) database), underpin the Australian Source Rock and Fluid Atlas web services and publications. These products provide information in an Australia-wide geological context on organic geochemistry, organic petrology and stable isotope data related primarily to sedimentary rocks and energy (petroleum and hydrogen) sample-based datasets used for the discovery and evaluation of sediment-hosted resources. The sample data provide the spatial distribution of source rocks and their derived petroleum fluids (natural gas and crude oil) taken from boreholes and field sites in onshore and offshore Australian provinces. Sample depth, stratigraphy, analytical methods, and other relevant metadata are also supplied with the analytical results. Sedimentary rocks that contain organic matter are referred to as source rocks (e.g., organic-rich shale, oil shale and coal) and the organic matter within the rock matrix that is insoluble in organic solvents is named kerogen. The data in the ORGCHEM schema are produced by a wide range of destructive analytical techniques conducted on samples submitted by industry under legislative requirements, as well as on samples collected by research projects undertaken by Geoscience Australia, state and territory geological organisations and scientific institutions including the Commonwealth Scientific and Industrial Research Organisation (CSIRO) and universities. Data entered into the database tables are commonly sourced from both the basic and interpretive volumes of well completion reports (WCR) provided by the petroleum well operator to either the state and territory governments or, for offshore wells, to the Commonwealth Government under the Offshore Petroleum and Greenhouse Gas Storage Act (OPGGSA) 2006 and previous Petroleum (submerged Lands) Act (PSLA) 1967. Data are also sourced from analyses conducted by Geoscience Australia’s laboratory and its predecessor organisations, the Australian Geological Survey Organisation (AGSO) and the Bureau of Mineral Resources (BMR). Other open file data from company announcements and reports, scientific publications and university theses are captured. The ORGCHEM database was created in 1990 by the BMR in response to industry requests for organic geochemistry data, featuring pyrolysis, vitrinite reflectance and carbon isotopic data (Boreham, 1990). Funding from the Australian Petroleum Cooperative Research Centre (1991–2003) enabled the organic geochemical data to be made publicly available at no cost via the petroleum wells web page from 2002 and included BOREHOLE, ORGCHEM and the Reservoir, Facies and Shows (RESFACS) databases. Investment by the Australian Government in Geoscience Australia’s Exploring for the Future (EFTF) program facilitated technological upgrades and established the current web services (Edwards et al., 2020). The extensive scope of the ORGCHEM schema has led to the development of numerous database tables and web services tailored to visualise the various datasets related to sedimentary rocks, in particular source rocks, crude oils and natural gases within the petroleum systems framework. These web services offer pathways to access the wealth of information contained within the ORGCHEM schema. Web services that facilitate the characterisation of source rocks (and kerogen) comprise data generated from programmed pyrolysis (e.g., Hawk, Rock-Eval, Source Rock Analyser), pyrolysis-gas chromatography (Py-GC) and kinetics analyses, and organic petrological studies (e.g., quantitation of maceral groups and organoclasts, vitrinite reflectance measurements) using reflected light microscopy. Collectively, these data are used to establish the occurrence of source rocks and the post-burial thermal history of sedimentary basins to evaluate the potential for hydrocarbon generation. Other web services provide data to characterise source rock extracts (i.e., solvent extracted organic matter), fluid inclusions and petroleum (e.g., natural gas, crude oil, bitumen) through the reporting of their bulk properties (e.g., API gravity, elemental composition) and molecular composition using gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS). Also reported are the stable isotope ratios of carbon, hydrogen, nitrogen, oxygen and sulfur using gas chromatography-isotope ratio mass spectrometry (GC-IRMS) and noble gas isotope abundances using ultimate high-resolution variable multicollection mass spectrometry. The stable isotopes of carbon, oxygen and strontium are also reported for sedimentary rocks containing carbonate either within the mineral matrix or in cements. Interpretation of these data enables the characterisation of petroleum source rocks and identification of their derived petroleum fluids, which comprise two key elements of petroleum systems analysis. Understanding a fluid’s physical properties and molecular composition are prerequisites for field development. The composition of petroleum determines its economic value and hence why the concentration of hydrocarbons (methane, wet gases, light and heavy oil) and hydrogen, helium and argon are important relative to those of nitrogen, carbon dioxide and hydrogen sulfide for gases, and heterocyclic compounds (nitrogen, oxygen or sulfur) found in the asphaltene, resin and polar fractions of crude oils. The web services and tools in the Geoscience Australia Data Discovery Portal (https://portal.ga.gov.au/), and specifically in the Source Rock and Fluid Atlas Persona (https://portal.ga.gov.au/persona/sra), allow the users to search, filter and select data based on various criteria, such as basin, formation, sample type, analysis type, and specific geochemical parameters. The web map services (WMS) and web feature services (WFS) enable the user to download data in a variety of formats (csv, Json, kml and shape file). The Source Rock and Fluid Atlas supports national resource assessments. The focus of the atlas is on the exploration and development of energy resources (i.e., petroleum and hydrogen) and the evaluation of resource commodities (i.e., helium and graphite). Some data held in the ORGCHEM tables are used for enhanced oil recovery and carbon capture, storage and utilisation projects. The objective of the atlas is to empower people to deliver Earth science excellence through data and digital capability. It benefits users who are interested in the exploration and development of Australia's energy resources by: • Providing a comprehensive and reliable source of information on the organic geochemistry of Australian source rocks • Enhancing the understanding of the spatial distribution, quality, and maturity of petroleum source rocks. • Facilitating the mapping of total petroleum and hydrogen systems and the assessment of the petroleum and hydrogen resource potential and prospectivity of Australian basins. • Facilitating the mapping of gases (e.g., methane, helium, carbon dioxide) within the geosphere as part of the transition to clean energy. • Enabling the integration and comparison of data from diverse sources and various acquisition methods, such as geological, geochemical, geophysical and geospatial data. • Providing data for integration into enhanced oil recovery and carbon capture, storage and utilisation projects. • Improving the accessibility and usability of data through user-friendly and interactive web-based interfaces. • Promoting the dissemination and sharing of data among Government, industry and community stakeholders. <b>References</b> Australian Petroleum Cooperative Research Centre (APCRC) 1991-2003. Australian Petroleum CRC (1991 - 2003), viewed 6 May 2024, https://www.eoas.info/bib/ASBS00862.htm and https://www.eoas.info/biogs/A001918b.htm#pub-resources Boreham, C. 1990. ORGCHEM Organic geochemical database. BMR Research Newsletter 13. Record 13:10-10. Geoscience Australia, Canberra. https://pid.geoscience.gov.au/dataset/ga/90326 Edwards, D.S., MacFarlane, S., Grosjean, E., Buckler, T., Boreham, C.J., Henson, P., Cherukoori, R., Tracey-Patte, T., van der Wielen, S.E., Ray, J., Raymond, O. 2020. Australian source rocks, fluids and petroleum systems – a new integrated geoscience data discovery portal for maximising data potential. Geoscience Australia, Canberra. http://dx.doi.org/10.11636/133751. <b>Citation</b> Edwards, D., Buckler, T. 2024. Organic Geochemistry (ORGCHEM) Schema. Australian Source Rock and Fluid Atlas. Geoscience Australia, Canberra. https://pid.geoscience.gov.au/dataset/ga/149422

<div>Exploring for the Future (2016-2024) was an Australian Government program led by Geoscience Australia (GA), in partnership with state and Northern Territory governments. The program aim was to drive industry investment in resource exploration in frontier regions of Australia by providing new precompetitive data and information about energy, mineral and groundwater resource potential. To address this overarching objective, GA led a key element of the Australian Government’s commitment to achieve net zero by 2050. The energy transition to an ever decreasing carbon emission economy will involve the increasing use of hydrogen gas (hydrogen). The key benefit of using hydrogen is that it is a clean fuel, emitting only water vapour and heat when combusted. However, hydrogen today is manufactured at a relatively high cost. The recent discovery of a 98% per cent pure natural hydrogen field in Mali (Africa) has led to low cost hydrogen production. It has also captured the imagination of explorers and the search is now on for new natural hydrogen accumulations across the world. Australia is considered one of the most prospective locations for sub-surface natural hydrogen due to our ancient geology and potential presence of suitable hydrogen traps. A review of occurrences of hydrogen in natural sub-surface rocks found high concentrations of hydrogen in central western, New South Wales (NSW). Helium is extracted in commercial quantities from natural gas and Australia currently has no local production. This project, in collaboration with the Geological Survey of NSW (GSNSW), built on the desktop review and has identified new occurrences of natural hydrogen and helium through soil gas surveys in various locations across central and far west, NSW. To support the Exploring for the Future program, six soil gas surveys for natural hydrogen and helium were jointly undertaken by staff from GA and GSNSW across central and western NSW during 2022-23. The project also included sites near the Tumut township to test various soil gas sampling techniques as well as the major focus in the Curnamona Province and Delamerian Orogen in far west New South Wales. In the first phase of the project, conceptual geological models for natural hydrogen and helium generation and accumulation were developed using pre-existing geoscientific data, including electromagnetic, magnetotelluric, magnetic, gravity, radiometric, drilling, seismic and satellite-derived data. The selected sites represented various concepts for natural hydrogen and helium generation, such as granite rocks rich in potassium, thorium, and uranium, banded iron formations, ultramafic rocks, and diatremes. The second phase of the project was the collection of soil gases from shallow (1 m deep) installations and subsequent molecular and isotopic compositional analysis at the GA Laboratory. Maximum hydrogen and helium concentrations in the soil gases are 309.5 ppm and 35.3 ppm, respectively, which is comparable to and even exceeds previously reported soil gas surveys both in Western Australia and overseas. The final phase was the integration of all datasets within a GIS platform for the interpretation and presentation of maps within this report.</div>