In the 50 years since the first commercial discovery in 1965 at Barracouta-1, and 46 years since production commenced from the Barracouta field, a total of 16.5 TCF of gas, 4026 MMbbl of oil, 385 MMbbl of condensate and 752 MMbbl of LPG have been found in the Gippsland Basin (Estimated Ultimate Recovery, as at the end of 2012). Despite these extensive resources, all from CretaceousPaleogene Latrobe Group reservoirs, there are questions regarding the effective petroleum systems, contributing source rock units, and the migration pathways between source and reservoir. Resolution of these uncertainties is essential to improve our understanding of the remaining prospectivity and for creating new exploration opportunities, particularly in the eastern, less explored part of the basin, but also for mitigating risk for the potential sequestration of carbon dioxide along the southern and western flanks. Geochemical fingerprinting of reservoir fluids has identified that the oil and gas originate from multiple sources. The most pervasive hydrocarbon charge into the largely produced fields overlying the Central Deep has a terrestrial source affinity, originating from lower coastal plain facies (Kingfish, Halibut, Mackerel), yet the oils cannot be correlated using source-related biomarker parameters to source rocks either within the Halibut Subgroup (F. longus biozone) at Volador-1, one of the deepest penetrations of the Upper Cretaceous section, or to older sections, penetrated on the flanks of the basin. However, within the underlying SantonianCampanian Golden Beach Subgroup an oil-source correlation has been established between the Anemone-1A oil and the marginal marine Anemone Formation (N. senectus biozone) at Anemone-1/1A and Archer-1. A similar correlation is indicated for the Angler-1 condensate to the Chimaera Formation (T. lilliei biozone) in the deepest section at Volador-1 and Hermes-1. In the Longtom field, gas reservoired within the Turonian Emperor Subgroup, potentially has a source from either the lacustrine Kipper Shale or the Albian portion of the Strzelecki Group. The molecular and carbon isotopic signatures of oil and gas from the onshore Wombat field are most similar to hydrocarbons sourced from the AptianAlbian Eumeralla Formation in the Otway Basin, also implicating a Strzelecki source in the Gippsland Basin. These results imply that sediments older than the Paleocene are significant sources of petroleum within the basin. Presented at the the AAPG/SEG 2015 International Conference & Exhibition set in Melbourne

Petroleum geochemical datasets and information are essential to government for evidence-based decision making on natural resources, and to the petroleum industry for de-risking exploration. Geoscience Australia’s newly built Data Discovery Portal (https://portal.ga.gov.au/) enables digital discoverability and accessibility to key petroleum geochemical datasets. The portal’s web map services and web feature services allow download and visualisation of geochemical data for source rocks and petroleum fluids, and deliver a petroleum systems framework for northern Australian basins. The Petroleum Source Rock Analytics Tool enables interrogation of source rock data within boreholes and field sites, and facilitates correlation of these elements of the petroleum system within and between basins. The Petroleum Systems Summary Assessment Tool assists the user to search and query components of the petroleum system(s) identified within a basin. The portal functionality includes customised data searches, and visualisation of data via interactive maps, graphs and geoscientific tools. Integration of the petroleum systems framework with the supporting geochemical data enables the Data Discovery Portal to unlock the value of these datasets by affording the user a one-stop access to interrogate the data. This allows greater efficiency and performance in evaluating the petroleum prospectivity of Australia’s sedimentary basins, facilitating and accelerating decision making around exploration investment to ensure Australia’s future resource wealth <b>Citation:</b> Edwards, D.S., MacFarlane, S.K., Grosjean, E., Buckler, T., Boreham, C.J., Henson, P., Cherukoori, R., Tracey-Patte, T., van der Wielen, S., Ray, J. and Raymond, O., 2020. Australian source rocks, fluids and petroleum systems – a new integrated geoscience data discovery portal for maximising data potential. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

The purpose of this study was to constrain the processes of Paleoproterozoic crustmantle evolution by investigating the Lu-Hf, Sm-Nd and oxygen isotope systematics of igneous rocks of the Lamboo Province of the Halls Creek and King Leopold Orogens, in the Kimberley region of Western Australia. The specific objectives were to: 1. Ascertain the nature of the source rocks of the granites, and to test whether granite formation involved the reworking of ancient meta-igneous protoliths in an intra-plate environment or complex crust-mantle interaction processes typical of modern plate tectonic settings; 2. Use data from granite-hosted zircons to quantify the proportion of new crust formed during discrete magmatic events, and to link this with the longer-term record of crustal evolution preserved by detrital zircons, and 3. Constrain the tectonic setting of the Lamboo Province, and thus the geodynamic controls on global crustal growth in this key time period.

The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the Offshore Energy Studies section. This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and facilitate exploration investment in Australia. The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018), Dorado 1 (2018), Dorado 2 (2019) and Dorado 3 (2019) wells in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata (Thompson, 2020; Thompson et al., 2015 and 2018). The current study aims to better understand this new petroleum system and establish its extent. As part of this program, a range of organic geochemical analyses were acquired on petroleum fluids from the Roc 1 and Roc 2 wells with these data released in this report.

The accessory mineral zircon is the most widely used geological timekeeper and tracer of crustal growth processes. Specifically, U-Pb isotopes in zircon offer a means to accurately determine the timing of magmatic events and their Hf isotopic composition provides a means to constrain magma source composition and potentially approximate source age. The high spatial resolution provided by in situ techniques such as secondary ion mass spectrometry (SIMS) and laser ablation inductively coupled mass spectrometry (LA-ICP-MS) have the advantage of being able to target different growth zones within individual zircon crystals, and unravel complex magmatic histories. However, utilising this power effectively requires calculation of accurate initial Hf compositions, which are founded on the assumption that the information obtained via the U-Pb and Lu-Hf systems are correctly integrated. A typical Hf isotope LA-ICP-MS analysis ablates a sample volume that is two orders of magnitude greater than a typical SIMS analysis. Thus, when age determination has been carried out by SIMS it is necessary to demonstrate that each subsequent Hf isotope analysis has sampled a similar isotopically homogeneous volume. Here, we use a combined SIMS and laser ablation split stream (LASS)-ICP-MS approach, whereby U-Pb isotopic measurement concurrently on the same sample volume as the Hf isotope measurement is compared to prior lower volume SIMS measurements. Using a suite of new drill core magmatic rock samples from the comparatively unexplored Coompana Province in South Australia, we demonstrate how such an approach can be used to filter Hf isotope datasets by identifying LA-ICP-MS analyses that sampled mixtures of different zircon growth domains. The robust initial 176Hf/177Hf compositions obtained from the filtered Coompana data set indicate that the province represents part of a juvenile Paleoproterozoic-Mesoproterozoic arc system formed through hyperextension of the margin of the Archean Gawler Craton, which can be correlated to the Musgrave Province and Madura Province in central and western Australia respectively. This hyperextension process is temporally similar to that on the now-adjacent Archean Yilgarn Craton margin.

<p>The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the North West Margin Energy Studies Section (NWMES). This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and attract exploration investment to Australia. <p>The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018) and Dorado 1 (2018) in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata. The current study aims to better understand this new petroleum system and establish its extent. <p>As part of this program, compositional and isotopic analyses were undertaken by Geoscience Australia on gas samples from the wells Roc 1 and Roc 2 and data from these analyses are released in this dataset.

A major concern for regulators and the public with geological storage of CO2 is the potential for the migration of CO2 via a leaky fault or well into potable groundwater supplies. Given sufficient CO2, an immediate effect on groundwater would be a decrease in pH which could lead to accelerated weathering, an increase in alkalinity, release of major and minor ions and heavy metals (particularly Pd, Ni and Cr) as well as CO2 mobilisation of trace organic contaminants. These scenarios potentially occur in a high CO2 leakage event, therefore detection of a small leak, although barely perceptible, could provide an important early warning for a subsequent and more substantial impact. Different approaches are required for the detection and quantification of these low level leaks and are the subject of this paper. A 3 year groundwater survey was recently completed in the Surat Basin, which provided comprehensive water and isotopic analysis of groundwaters together with their exsolved gases. The gases were analysed for composition, -13CCO2, -13CCH4 and -2HCH4. Methane is prevalent in the major Surat Basin aquifers (e.g. Mooga, Gubberamunda and Hutton sandstones) and is invariably associated with a bacterial (methanogenic) carbonate reduction source, evident from its isotopic signature ('13CCH4 ~ -70', '2HCH4 ~ -220'). In addition to methane and low levels of CO2, trace ethane is common. Two neighbouring wells, however, were quite different to the other 85 wells surveyed. Their exsolved gases contained comparatively high ethane, but also C1-C6 hydrocarbons in addition to methane. Methane isotope systematics were significantly different from other groundwater wells completed in the same formation. The -13C of the CO2 was similar to the surrounding groundwater wells, but the relative proportion of CO2 in the gas was significantly higher. Combined, these characteristics are consistent with hydrocarbon biodegradation. There was little difference in the groundwater chemistry for these wells compared to the regional baseline. The study provides a useful analogue study for detection, at various scales, of a leaky well associated with a geological storage site. Compositional and isotopic analysis of exsolved gases from groundwater samples could be used to demonstrate non-equilibrium conditions and intrusion of exogenic CO2. Abstract for the 2013 International Association of Hydrologist Congress, Perth

The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the Offshore Energy Studies section. This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and facilitate exploration investment in Australia. The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018), Dorado 1 (2018), Dorado 2 (2019) and Dorado 3 (2019) wells in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata (Thompson, 2020; Thompson et al., 2015 and 2018). The current study aims to better understand this new petroleum system and establish its extent. As part of this program, a range of organic geochemical analyses were acquired on source rocks from the Roc 2 well with these data released in this report.

<div>Poster for the Specialist Group in Geochemistry, Mineralogy & Petrology (SGGMP) conference in Yallingup WA in November 2022.</div><div><br></div>This Poster was presented to the 2022 Specialist Group in Geochemistry, Mineralogy and Petrology (SGGMP) Conference 7-11 November (https://gsasggmp.wixsite.com/home/biennial-conference-2021)

This study assesses the effect of chemical abrasion on in-situ mass spectrometric isotopic and elemental analyses in zircon. Chemical abrasion improves the U-Pb systematics of SIMS (Secondary Ion Mass Spectrometry) analyses of reference zircons, while leaving other isotopic systems largely unchanged. SIMS ²⁰⁶Pb/²³⁸U ages of chemically abraded reference materials TEMORA-2, 91500, QGNG, and OG1 are precise to within 0.25 to 0.4%, and are within uncertainty of chemically abraded TIMS reference ages, while SIMS ²⁰⁶Pb/²³⁸U ages of untreated zircons are within uncertainty of TIMS reference ages where chemical abrasion was not used. Chemically abraded and untreated zircons appear to cross-calibrate within uncertainty using all but one possible permutations of reference materials, provided that the corresponding chemically abraded or untreated reference age is used for the appropriate material. In the case of reference zircons QGNG and OG1, which are slightly discordant, the SIMS U-Pb ages of chemically abraded and untreated material differ beyond their respective 95% confidence intervals. SIMS U-Pb analysis of chemically abraded zircon with multiple growth stages are more difficult to interpret. Treated igneous rims on zircon crystals from the S-type Mount Painter Volcanics are much lower in common Pb than the rims on untreated zircon grains. However, the analyses of chemically abraded material show excess scatter. Chemical abrasion also changes the relative abundance of the ages of zircon cores inherited from the sedimentary protolith, presumably due to some populations being more likely to survive the chemical abrasion process than others. We consider these results from inherited S-type zircon cores to be indicative of results for detrital zircon grains from unmelted sediments. Trace element, &delta;¹⁸O, and εHf analyses were also performed on these zircons. None of these systems showed substantial changes as a result of chemical abrasion. The most discordant reference material, OG1, showed a loss of OH as a result of chemical abrasion, presumably due to dissolution of hydrous metamict domains, or thermal dehydration during the annealing step of chemical abrasion. In no case did zircon gain fluorine due to exchange of lattice-bound substituted OH or other anions with fluorine during the HF partial dissolution phase of the chemical abrasion process. As the OG1, QGNG, and TEMORA-2 zircon samples are known to be compositionally inhomogenous in trace element composition, spot-to-spot differences dominated the trace element results. Even the 91500 megacrystic zircon pieces exhibited substantial chip-to-chip variation. The LREE in chemically abraded OG1 and TEMORA-2 were lower than in the untreated samples. Ti concentration and phosphorus saturation ((Y+REE)/P) were generally unchanged in all samples. <b>Citation:</b> Kooymans, C., Magee Jr., C. W., Waltenberg, K., Evans, N. J., Bodorkos, S., Amelin, Y., Kamo, S. L., and Ireland, T.: Effect of chemical abrasion of zircon on SIMS U–Pb, &delta;¹⁸O, trace element, and LA-ICPMS trace element and Lu–Hf isotopic analyses, Geochronology, 6, 337–363, https://doi.org/10.5194/gchron-6-337-2024, 2024.