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Detecting anomalous metal concentrations in the regolith using cross‒compositional detrending

Deciphering element associations and affinities in the regolith is important for understanding mineral hosts and geological processes, such as sorting and pedogenesis. This has implications in environmental sciences in terms of distinguishing natural vs. anthropogenic element distributions and establishing realistic remediation targets. In mineral exploration, the strongest elements associations often drive distribution patterns in geochemical maps, yet these are not always the most useful ones to consider.

In this contribution, we use National Geochemical Survey of Australia (NGSA) data to (1) identify the strongest controls of mineralogy (using major element total concentrations as a proxy) on trace metal distribution (using aqua regia Cu as an exemplar), and (2) remove the trend driven by the strongest major‒trace element association to calculate and map standardised residuals of the metals. In the coarse fraction (<2 mm) of NGSA top outlet sediments (0‒10 cm depth), which are similar to floodplain sediments, aqua regia Cu is most strongly correlated with total Fe of all the major total elements (r = 0.76 based on log‒transformed concentrations). Thus the aqua regia Cu map mostly shows regions where Fe‒oxyhydroxides in the regolith are abundant (or not) and naturally adsorb dissolved cationic metals from surrounding solutions. The predicted Cu map based purely on the total Fe concentrations and on the Fe‒Cu correlation is visually similar to the raw map. Only when calculating the standardised residuals between actual and predicted aqua regia Cu does additional information become apparent in the form of completely different geochemical patterns. These highlight areas where Cu that is not related to Fe (and therefore not in the form of Cu adsorbed onto Fe‒oxyhydroxides) is abundant (or not). For instance this Cu could be associated with silicate, carbonate or sulfate minerals. Thus this approach allows both environmental management and exploration strategies targeting different types of metal associations to be more effectively implemented, thereby reducing risk and cost.


This Abstract & Poster were presented at the 2017 Goldschmidt Conference ( https://goldschmidt.info/2017/)

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Identification info

Date (Creation)
2017-03-28T00:00:00
Date (Publication)
2023-10-26T02:00:34
Citation identifier
Geoscience Australia Persistent Identifier/https://pid.geoscience.gov.au/dataset/ga/104884

Identifier

Codespace

Digital Object Identifier

Cited responsible party
Role Organisation / Individual Name Details
Author

de Caritat, P.

MEG Internal Contact
Author

Rate, A.W.

External Contact
Publisher

Commonwealth of Australia (Geoscience Australia)

Voice
Name

Goldschmidt Conference 13-18 August 2017, Paris

Purpose

Submitted and Presented to the 2017 Goldschmidt Conference

Status
Completed
Point of contact
Role Organisation / Individual Name Details
Point of contact

Commonwealth of Australia (Geoscience Australia)

Voice
Resource provider

Minerals, Energy and Groundwater Division

External Contact
Point of contact

Main, P.

MEG Internal Contact
Spatial representation type
Topic category
  • Geoscientific information

Extent

Extent

N
S
E
W


Maintenance and update frequency
As needed

Resource format

Title

Product data repository: Various Formats

Website

Data Store directory containing the digital product files

Data Store directory containing one or more files, possibly in a variety of formats, accessible to Geoscience Australia staff only for internal purposes

theme.ANZRC Fields of Research.rdf
  • EARTH SCIENCES

Keywords
  • mineralogy

Keywords
  • trace metal distribution

Keywords
  • Cu map

Keywords
  • Published_External

Resource constraints

Title

Creative Commons Attribution 4.0 International Licence

Alternate title

CC-BY

Edition

4.0

Website

http://creativecommons.org/licenses/

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License
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© 2017 Commonwealth of Australia (Geoscience Australia)

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Unclassified
Language
English
Character encoding
UTF8

Distribution Information

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Distributor

Commonwealth of Australia (Geoscience Australia)

Voice facsimile
OnLine resource

Link to Conference Page

Link to Conference Page

Distribution format
OnLine resource

Link to Abstract

Link to Abstract

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OnLine resource

Download Poster (pdf) [6.7 MB]

Download Poster (pdf) [6.7 MB]

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  • pdf

    File decompression technique

    nil

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Submitted and Presented to the 2017 Goldschmidt Conference

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Dataset

Metadata constraints

Classification
Unclassified

Metadata

Metadata identifier
urn:uuid/e2322eaf-ac8a-4e0f-b64b-33c40e23f121

Title

GeoNetwork UUID

Contact
Role Organisation / Individual Name Details
Point of contact

Commonwealth of Australia (Geoscience Australia)

Voice
Point of contact

Main, P.

MEG Internal Contact

Type of resource

Resource scope
Document
Name

Conference Abstract and Poster

Alternative metadata reference

Title

Geoscience Australia - short identifier for metadata record with

uuid

Citation identifier
eCatId/104884

Metadata linkage

https://internal.ecat.ga.gov.au/geonetwork/srv/eng/search?uuid=e2322eaf-ac8a-4e0f-b64b-33c40e23f121

Point-of-truth metadata URL

Metadata linkage

https://ecat.ga.gov.au/geonetwork/srv/eng/catalog.search#/metadata/e2322eaf-ac8a-4e0f-b64b-33c40e23f121

Metadata linkage

https://ecat.ga.gov.au:80/geonetwork/srv/eng/catalog.search#/metadata/e2322eaf-ac8a-4e0f-b64b-33c40e23f121

Metadata linkage

https://ecat.ga.gov.au/geonetwork/accessDenied.jsp/eng/catalog.search#/metadata/e2322eaf-ac8a-4e0f-b64b-33c40e23f121

Date info (Creation)
2017-03-28T04:24:30
Date info (Revision)
2017-08-02T02:22:39

Metadata standard

Title

AU/NZS ISO 19115-1:2014

Metadata standard

Title

ISO 19115-1:2014

Metadata standard

Title

ISO 19115-3

Edition date
2015-07-01T00:00:00
Title

Geoscience Australia Community Metadata Profile of ISO 19115-1:2014

Edition

Version 2.0, April 2015

 
 

Spatial extent

N
S
E
W


Keywords

Cu map mineralogy trace metal distribution
theme.ANZRC Fields of Research.rdf
EARTH SCIENCES

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