Halogen variations in the Paleoproterozoic layered mafic-ultramafic intrusions of the East Kimberley, Western Australia: Implications for platinum-group element mineralization  

Authors / CoAuthors

Boudreau, A. | Hoatson, D.M.

Abstract

A number of Paleoproterozoic layered mafic-ultramafic intrusions in the central part of the Halls Creek Orogen of East Kimberley, Western Australia, have been explored for platinum-group elements (PGE), chromium, nickel, copper, cobalt and gold. Here we report on the halogen geochemistry of apatite and biotite in a number of these intrusions. Interstitial apatite is ubiquitous in these intrusions and, in most samples, tends to be relatively enriched in F- and OH-endmembers and relatively poor in Cl (< 20 mole %). Fluorapatite occurs in the more evolved igneous rocks and in marginal samples that apparently have been contaminated by metamorphic country rock. Cl/F ratios generally increase with bulk rock molar Mg/(Mg + Fe) ratios, as observed in other intrusions. Only a few samples show Cl-enrichment as high as that seen in the Stillwater and Bushveld complexes beneath the major stratabound PGE deposits. The most Cl-rich compositions observed occur in the upper part of the Springvale intrusion, where it is associated with troctolite, and in a single sample from the McIntosh intrusion. For the former intrusion, it is suggested that volatiles migrating out of the lower part of the mafic stratigraphy stabilized olivine at the expense of pyroxene. Associated biotite tends to be low in both Cl and F, containing no more than 10 mole % of these components. It is concluded that the East Kimberley intrusions contained a low to moderate volatile component that, during the combined processes of crystallization, degassing and fractionation of interstitial halogen-bearing minerals, was able to produce a late, mobile interstitial silicate liquid or volatile-rich fluid phase of variable Cl/F content that gave rise to most of the observed variations within any given intrusion. The exceptions include some marginal samples that appear to have been affected by country rocks, either during emplacement (assimilation) or during later metamorphism. The generally low Cl/F ratio of apatite, the lack of primary amphibole and the high background sulfur concentrations of the East Kimberley intrusions suggest that these magmas were relatively dry. The possible development of high-grade, PGE-enriched horizons by late-stage hydrothermal processes that could have mobilized significant amounts of the PGE and sulfur is considered to be of low potential.

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nonGeographicDataset

eCat Id

47447

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Keywords

• External PublicationScientific Journal Paper

( Theme )

• economic geology

( Theme )

• geochemistry

( Theme )

• mineralogy

( Theme )

• mineral deposits

• AU-WA

Australian and New Zealand Standard Research Classification (ANZSRC)

• Earth Sciences

• Published_Internal

Publication Date

2003-04-30T00:00:00

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Australian Government Security ClassificationSystem    

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Creative Commons Attribution 4.0 International Licence    

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geoscientificInformation

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[-18.0, -17.0, 127.5, 129.0]

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