Atmospheric tomography is a monitoring technique that uses an array of sampling sites and a Bayesian inversion technique to simultaneously solve for the location and magnitude of a gaseous emission. Application of the technique to date has relied on air samples being pumped over short distances to a high precision FTIR Spectrometer, which is impractical at larger scales. We have deployed a network of cheaper, less precise sensors during three recent large scale controlled CO2 release experiments; one at the CO2CRC Ginninderra site, one at the CO2CRC Otway Site and another at the Australian Grains Free Air CO2 Enrichment (AGFACE) facility in Horsham, Victoria. The purpose of these deployments was to assess whether an array of independently powered, less precise, less accurate sensors could collect data of sufficient quality to enable application of the atmospheric tomography technique. With careful data manipulation a signal suitable for an inversion study can be seen. A signal processing workflow based on results obtained from the atmospheric array deployed at the CO2CRC Otway experiment is presented.

As part of the Australian Government National CO2 Infrastructure Plan (NCIP), Geoscience Australia is undertaking CO2 storage assessment of the Vlaming Sub-basin located offshore Western Australia in the southern Perth Basin. The Vlaming Sub-basin is a Mesozoic depocentre containing up to 14 km of sediments. Close proximity of the basin to industrial polluters in the Perth area dictates the need to find CO2 storage solutions in this basin. The main reservoir unit identified as suitable for storage of CO2 is the Early Cretaceous Gage Sandstone deposited in paleo-topographic lows of the Valanginian breakup unconformity. The reservoir unit is laterally extensive (over 1,500 km2) and over most of the area reasonably thick (100 - 300 m). It lies at depths between 1400 and 2000 m below the seafloor, which is suitable for injection of the supercritical CO2 and makes it an attractive target for the long-term storage. The reservoir unit is overlain by a thick deltaic to shallow marine succession of the South Perth Shale, which represents a regional seal in the area. Carbon Storage taskforce estimated that up 1 GT of CO2 can be stored in the Gage Sandstone. The first assessment of the Vlaming Sub-basin undertaken by CO2CRC focused on evaluation of the reservoir unit and overall storage capacity. The current study is based on interpretation and integration of the seismic, well and marine datasets, both existing and acquired since the previous assessment. It includes detailed analysis of reservoir and seal properties and a comprehensive evaluation of the seal integrity risks to allow a more accurate and realistic modeling for CO2 storage.

Geoscience Australia (GA) conducted a marine survey (GA0345/GA0346/TAN1411) of the north-eastern Browse Basin (Caswell Sub-basin) between 9 October and 9 November 2014 to acquire seabed and shallow geological information to support an assessment of the CO2 storage potential of the basin. The survey, undertaken as part of the Department of Industry and Science's National CO2 Infrastructure Plan (NCIP), aimed to identify and characterise indicators of natural hydrocarbon or fluid seepage that may indicate compromised seal integrity in the region. The survey was conducted in three legs aboard the New Zealand research vessel RV Tangaroa, and included scientists and technical staff from GA, the NZ National Institute of Water and Atmospheric Research Ltd. (NIWA) and Fugro Survey Pty Ltd. Shipboard data (survey ID GA0345) collected included multibeam sonar bathymetry and backscatter over 12 areas (A1, A2, A3, A4, A6b, A7, A8, B1, C1, C2b, F1, M1) totalling 455 km2 in water depths ranging from 90 - 430 m, and 611 km of sub-bottom profile lines. Seabed samples were collected from 48 stations and included 99 Smith-McIntyre grabs and 41 piston cores. An Autonomous Underwater Vehicle (AUV) (survey ID GA0346) collected higher-resolution multibeam sonar bathymetry and backscatter data, totalling 7.7 km2, along with 71 line km of side scan sonar, underwater camera and sub-bottom profile data. Twenty two Remotely Operated Vehicle (ROV) missions collected 31 hours of underwater video, 657 still images, eight grabs and one core. This catalogue entry refers to sediment oxygen demand measurements undertaken on seabed sediments (0-2 cm).

Geoscience Australia (GA) conducted a marine survey (GA0345/GA0346/TAN1411) of the north-eastern Browse Basin (Caswell Sub-basin) between 9 October and 9 November 2014 to acquire seabed and shallow geological information to support an assessment of the CO2 storage potential of the basin. The survey, undertaken as part of the Department of Industry and Science's National CO2 Infrastructure Plan (NCIP), aimed to identify and characterise indicators of natural hydrocarbon or fluid seepage that may indicate compromised seal integrity in the region. The survey was conducted in three legs aboard the New Zealand research vessel RV Tangaroa, and included scientists and technical staff from GA, the NZ National Institute of Water and Atmospheric Research Ltd. (NIWA) and Fugro Survey Pty Ltd. Shipboard data (survey ID GA0345) collected included multibeam sonar bathymetry and backscatter over 12 areas (A1, A2, A3, A4, A6b, A7, A8, B1, C1, C2b, F1, M1) totalling 455 km2 in water depths ranging from 90 - 430 m, and 611 km of sub-bottom profile lines. Seabed samples were collected from 48 stations and included 99 Smith-McIntyre grabs and 41 piston cores. An Autonomous Underwater Vehicle (AUV) (survey ID GA0346) collected higher-resolution multibeam sonar bathymetry and backscatter data, totalling 7.7 km2, along with 71 line km of side scan sonar, underwater camera and sub-bottom profile data. Twenty two Remotely Operated Vehicle (ROV) missions collected 31 hours of underwater video, 657 still images, eight grabs and one core. This catalogue entry refers to Autonomous Underwater Vehicle (AUV) still image data acquired during survey GA0345/GA0346/TAN1411. Following mapping with the shipboard multibeam, higher-resolution multibeam data were acquired in targeted areas using a Kongsberg Simrad EM2000 system mounted to the Fugro Echo Surveyor V (ES-5) AUV. This instrument had a depth rating of 3000 m, and surveyed the seafloor according to a pre-programmed mission plan. The AUV was fitted with a camera and light system designed to produce images of equal width and height (in the context of this survey, the images comprised 8 m by 8 m of seafloor). The equipment consisted of a light sensitive NEO 11 Megapixel 35 mm monochrome CCD (4008 x 2672) camera and two LED panels, each comprising 360 LEDs. High-resolution multibeam bathymetric data was collected together with side scan sonar and sub bottom profile data at an elevation of 30 m above the seafloor, and at line spacing's of 100 m. Overlapping high-resolution still photographs (captured every second) were then acquired on the survey lines at an elevation of 8 m above the seafloor. The AUV was equipped with an advanced real-time Aided Inertial Navigation System, which calculated the position, velocity and altitude of the vehicle and a HiPAP 500 USBL system was used to acoustically position the AUV. Underwater imagery was collected from two AUV missions in study Areas 3 and 4. During the 2nd AUV mission on 22 October, the vehicle encountered an obstruction on the seabed and became trapped despite commencing an emergency ascent sequence. The AUV was subsequently recovered from the seabed during salvage operations incorporated into the ROV phase of survey operations. A total of 24 877 still images were acquired in Area 3 and 20 743 in Area 4 over 58 and 56 line kilometres, respectively. Still images (.jpg files) are located in folder 'TAN1411_AUV_STILLS' with sub-folders named according to gear code (AUV= Autonomous Underwater Vehicle), mission and study Area (e.g. AUV_M2_A3 = still images acquired during AUV mission 2 in Area 3). USBL (Ultra-short baseline) text files (`TileCam.idx) are located in each sub-folder and provide continuous navigational information on location, time (UTC) and depth of AUV still imagery transect lines.

This GHGT-12 conference paper hightlights some results of GA's work on "Regional assessment of the CO2 storage potential of the Mesozoic sucession in the Petrel Sub-basin, Northern Territory, Australia. Record 2014/11".

This report provides an analysis and evaluation of fluid seepage and habitats in two targeted areas of the Petrel Sub-basin, Bonaparte Basin, northern Australia, and provides scientific information on the seabed and shallow sub-surface geology as part of a study on the potential of this area for CO2 sequestration. The Petrel Sub-basin, located beneath the modern Joseph Bonaparte Gulf, has been assessed by Geoscience Australia as part of the Australian Government funded National Low Emissions Coal Initiative (NLECI) to accelerate the development and deployment of low emissions coal technologies including geological sequestration of CO2. This study is the first undertaken by Geoscience Australia that integrates seafloor and shallow sub-surface geology data to provide information on the potential to sequester CO2 in sub-surface geological reservoirs and their suitability for purpose. In particular, this work involved the integration of data from seabed habitat characterisation studies and sub-surface geological studies to determine if evidence for fluid seepage from depth to the seabed exists at the two study sites within the Petrel Sub-basin. No evidence for hydrocarbons from depth were found. However, fluid seepage at the seabed has been and potentially is occurring; this result stemming from observations on seabe geomorphology, sedimentology, chemistry, and acoustic sub-bottom profiles.

The first large-scale projects for geological storage of carbon dioxide on the Australian mainland are likely to occur within sedimentary sequences that underlie or are within the Triassic-Cretaceous, Great Artesian Basin (GAB) aquifer sequence. Recent national1 and state2 assessments have concluded that certain deep formations within the GAB show considerable geological suitability for the storage of greenhouse gases. These same formations contain trapped methane and naturally generated CO2 stored for millions of years. In July 2010, the Queensland government released exploration permits for Greenhouse Gas Storage in the Surat and Galilee basins.An important consideration in assessing the potential economic, environmental, health and safety risks of such projects is the potential impact CO2 migrating out of storage reservoirs could have on overlying groundwater resources. The risk and impact of CO2 migrating from a greenhouse gas storage reservoir into groundwater cannot be objectively assessed without knowledge of the natural baseline characteristics of the groundwater within these systems. Due to the phase behaviour of CO2, geological storage of carbon dioxide in the supercritical state requires depths greater than 800m, but there are few hydrogeochemical studies of these deeper aquifers in the prospective storage areas. Historical hydrogeochemical data are compiled from various State and Federal Government agencies. In addition, hydrogeochemical information is compiled from thousands of petroleum well completion reports in order to obtain more information on the deeper aquifers, not typically used for agriculture or human consumption. The data are passed through a QC procedure to check for mud contamination and to ascertain whether a representative sample had been collected. The large majority of the samples proved to be contaminated but a small selection passed the QC criteria. The full dataset is available for download from GA's Virtual Dataroom. Oral presentation at "Groundwater 2010" Conference, 31 October - 4 November 2010, Canberra

Atmospheric monitoring of CO2 geological storage has developed from a concept to reality over less than a decade. Measurements of atmospheric composition and surface to air fluxes are now being made at onshore test sites, pilot projects, operational projects and likely future storage regions around the world. The motivation for atmospheric monitoring is usually to detect potential leakage from CO2 storage activities that might affect health and safety or to test the efficacy of carbon capture and storage (CCS) as a climate mitigation option. We have focused on the mitigation requirement, which involves determining whether potential leakage is below a maximum acceptable rate. Climatic considerations suggest that the maximum leakage rate of stored CO2 should be very small, of the order of 0.01% of that stored per year, globally averaged. Monitoring operational CO2 storage sites to confirm that potential leakage to the atmosphere is below this rate and to locate and quantify the any leakage flux can be a challenge, mainly because of the large and variable CO2 concentrations and fluxes in ecosystems and urban environments. We have developed and assessed atmospheric techniques during field experiments, during 4 years of monitoring the CO2CRC Otway Project, and by using model simulations. From this experience we are able to make recommendations about suitable technologies and strategies to optimise the capability of atmospheric monitoring of CCS in different environments. Abstract for paper to be presented at CO2CRC Research Symposium 2010, 1-3 December 2010, Melbourne

Geoscience Australia (GA) conducted a marine survey (GA0345/GA0346/TAN1411) of the north-eastern Browse Basin (Caswell Sub-basin) between 9 October and 9 November 2014 to acquire seabed and shallow geological information to support an assessment of the CO2 storage potential of the basin. The survey, undertaken as part of the Department of Industry and Science's National CO2 Infrastructure Plan (NCIP), aimed to identify and characterise indicators of natural hydrocarbon or fluid seepage that may indicate compromised seal integrity in the region. The survey was conducted in three legs aboard the New Zealand research vessel RV Tangaroa, and included scientists and technical staff from GA, the NZ National Institute of Water and Atmospheric Research Ltd. (NIWA) and Fugro Survey Pty Ltd. Shipboard data (survey ID GA0345) collected included multibeam sonar bathymetry and backscatter over 12 areas (A1, A2, A3, A4, A6b, A7, A8, B1, C1, C2b, F1, M1) totalling 455 km2 in water depths ranging from 90 - 430 m, and 611 km of sub-bottom profile lines. Seabed samples were collected from 48 stations and included 99 Smith-McIntyre grabs and 41 piston cores. An Autonomous Underwater Vehicle (AUV) (survey ID GA0346) collected higher-resolution multibeam sonar bathymetry and backscatter data, totalling 7.7 km2, along with 71 line km of side scan sonar, underwater camera and sub-bottom profile data. Twenty two Remotely Operated Vehicle (ROV) missions collected 31 hours of underwater video, 657 still images, eight grabs and one core. This catalogue entry refers to grain size data and carbonate concentrations of the upper ~2cm of seabed sediment. Sediment samples were first wet sieved to determine the proportions of mud, sand and gravel as a percentage. By wet sieving fine particles are removed from the sand and gravel fractions, allowing an accurate measurement each component. The mud, sand, gravel percentages were also used to derive Folk sediment texture classifications for each sample (Folk, 1980). The grain size of the mud fraction (<63 m) was determined using a Mastersizer laser granulometer. Sediment > 63 um diameter were dried, and dry sieved at values between 4 and -4 phi corresponding to the Wentworth (1922) grain size boundaries between the major sediment classes. The samples were then submitted for measurement of carbonate content by mass using the carbonate digestion method described in Müller and Gastner (1971).

Geoscience Australia and CO2CRC have constructed a greenhouse gas controlled release reference facility to simulate surface emissions of CO2 (and other GHG gases) from an underground slotted horizontal well into the atmosphere under controlled conditions. The facility is located at an experimental agricultural station maintained by CSIRO Plant Industry at Ginninderra, Canberra. The design of the facility is modelled on the ZERT controlled release facility in Montana. The facility is equipped with a 2.5 tonne liquid CO2 storage vessel, vaporiser and mass flow controller unit with a capacity for 6 individual metered CO2 gas streams (up to 600 kg/d capacity). Injection of CO2 into soil is via a shallow (2m depth) underground 120m horizontally drilled slotted HDPE pipe. This is equipped with a packer system to partition the well into six CO2 injection chambers. The site is characterised by the presence of deep red and yellow podsolic soils with the subsoil containing mainly kaolinite and subdominant illite. Injection is above the water table. The choice of well orientation based upon the effects of various factors such as topography, wind direction, soil properties and ground water depth will be discussed. An above ground release experiment was conducted from July - October 2010 leading to the development of an atmospheric tomography technique for quantifying and locating CO2 emissions1. This technique will be applied to the first sub-surface experiment held in January-March 2012 in addition to soil flux surveys, microbiological surveys, and tracer studies. An overview of monitoring experiments conducted during the subsurface release and preliminary results will be presented. Additional CO2 releases are planned for late 2012 and 2013. Abstract for "11th Annual Conference on Carbon Capture Utilization & Sequestration" April 30 - May 3, 2012, Pittsburgh, Pennsylvania