This Geoscience Australia Record reports the findings of the Canning Basin Petroleum Systems Modelling Project. The southern, frontier portions of the Canning Basin have numerous potential hydrocarbon play opportunities, in particular unconventional gas plays, which remain untested. Of particular interest are Ordovician-aged petroleum systems. Geoscience Australia in collaboration with the Geological Survey of Western Australia acquired an 872 km long 2D seismic line across the south and south-west Canning Basin in 2018, and drilled the 2680 m stratigraphic hole Barnicarndy 1 in the Barnicarndy Graben to further develop the understanding of hydrocarbon prospectivity in these frontier regions. As part of the Exploring for the Future program Geoscience Australia contracted GNS Science to construct ten 1D petroleum systems models and one 2D model across the frontier southern parts of the basin. The aim was to combine interpretation of the newly acquired seismic data with interpretation of legacy and new well data, in particular organic geochemical data, to improve the understanding of the burial and thermal history, trap formation, generation and migration of hydrocarbons in the southern, frontier parts of the Canning Basin. This Record is a compilation of the work completed by GNS Science International Limited and the reports containing new data collected and analyzed relevant to the petroleum systems modelling.

The Ordovician to Cretaceous Canning Basin of Western Australia is an underexplored prospective onshore petroleum basin with proven petroleum systems currently producing on a small-scale. The Canning Basin has recently become a site of interest for unconventional hydrocarbon exploration, with several formations within deeper basin depocentres being investigated for resources and estimates that suggest it may have the largest shale gas potential in Australia. Modern petroleum resource evaluation generally depends on an understanding of both local and regional stresses, which are a primary control over the formation and propagation of induced fractures. Presently, there are significant gaps in our understanding of these factors within the Canning Basin. This study characterises the regional stress regime of the onshore Canning Basin and presents detailed models of present-day stress within the subsurface. These allow for the identification of significant stress heterogeneities and natural barriers to fracture propagation. Wireline data interpretation reveals a variable present-day state of stress in the Canning Basin. An approximately NE-SW regional present-day maximum horizontal stress orientation is interpreted from observed wellbore failure in image logs, in broad agreement with both the Australian Stress Map and previously published earthquake focal mechanism data. One-dimensional mechanical earth models constructed for intervals from 15 Canning Basin petroleum wells highlight the relationship between lithology and stress. This study describes significant changes in stress within and between lithological units due to the existence of discrete mechanical units, forming numerous inter- and intra- formational stress boundaries likely to act as natural barriers to fracture propagation, particularly within units currently targeted for their unconventional resource potential. Broadly, a strike-slip faulting stress regime is interpreted through the basin, however, when analysed in detail there are three distinct stress zones identified.: 1) a transitional reverse- to strike-slip faulting stress regime in the top ~1 km of the basin, 2) a strike-slip faulting stress regime from ~1 km to ~3.0 km depth, and 3) a transitional strike-slip to normal faulting regime at depths greater than ~3.0 km. This study is a component of the Australian Government’s Exploring for the Future (EFTF) initiative, which is focused on gathering new data and information about the resource potential concealed beneath the surface across northern Australia. Appeared online in the Australian Journal of Earth Sciences 17 Feb 2021

Pyrolysis and bulk kinetic studies were used to investigate the hydrocarbon generation potential and source rock facies variability of the marine organic-rich rocks from the Middle Ordovician (Darriwilian) Goldwyer Formation in the Canning Basin, Western Australia. Rock Eval pyrolysis results for the analysed immature to mid-mature calcareous mudstones imply that the upper Goldwyer Sequence I samples contain oil-prone Type I kerogen, while the lower Goldwyer Sequence III samples comprise on average Type II/III oil- and gas-prone kerogen. This is supported by the pyrolysis gas chromatography (Py-GC) results that show the presence of homogenous organofacies in the Goldwyer Sequence I that comprise aliphatic molecular signatures, possibly attributed to the selective preservation of the lipid fraction derived from <i>Gloeocapsomorpha prisca</i> (<i>G. prisca</i>). The heterogeneous organofacies of the Goldwyer Sequence III contains aromatic moieties that are present in similar abundance as the aliphatic compounds. The calcareous claystones of the Goldwyer Sequence I have the capacity to generate paraffinic oil with low wax contents, whereas those of the Goldwyer Sequence III have generative potential for paraffinic-naphthenic-aromatic (P-N-A) low wax oils and gas and condensate. The temperature for hydrocarbon generation for the Type I kerogen, assuming a constant geological heating rate of 3^oC/Ma, is estimated to occur over a narrow interval between 145^oC and 170^oC for the Goldwyer Sequence I samples. Generation from the Type II/III kerogen occurs from 100°C to 160°C in the Goldwyer Sequence III samples which are significantly thermally less stable than observed for the Goldwyer Sequence I samples. The kinetics results for both sequences were used in standard thermal and burial history plots to evaluate their transformation ratio and hydrocarbon generative potential. This provided a basin-specific kinetic input for burial history modelling and a better constraint for kerogen transformation and hydrocarbon generation on the Broome Platform. <b>Citation:</b> Lukman M. Johnson, Reza Rezaee, Gregory C. Smith, Nicolaj Mahlstedt, Dianne S. Edwards, Ali Kadkhodaie, Hongyan Yu,; Kinetics of hydrocarbon generation from the marine Ordovician Goldwyer Formation, Canning Basin, Western Australia,<i> International Journal of Coal Geology</i>, Volume 232, <b>2020</b>, 103623, ISSN 0166-5162, https://doi.org/10.1016/j.coal.2020.103623.

The discovery of strategically located salt structures, which meet the requirements for geological storage of hydrogen, is crucial to meeting Australia’s ambitions to become a major hydrogen producer, user and exporter. The use of the AusAEM airborne electromagnetic (AEM) survey’s conductivity sections, integrated with multidisciplinary geoscientific datasets, provides an excellent tool for investigating the near-surface effects of salt-related structures, and contributes to assessment of their potential for underground geological hydrogen storage. Currently known salt in the Canning Basin includes the Mallowa and Minjoo salt units. The Mallowa Salt is 600-800 m thick over an area of 150 × 200 km, where it lies within the depth range prospective for hydrogen storage (500-1800 m below surface), whereas the underlying Minjoo Salt is generally less than 100 m thick within its much smaller prospective depth zone. The modelled AEM sections penetrate to ~500 m from the surface, however, the salt rarely reaches this level. We therefore investigate the shallow stratigraphy of the AEM sections for evidence of the presence of underlying salt or for the influence of salt movement evident by disruption of near-surface electrically conductive horizons. These horizons occur in several stratigraphic units, mainly of Carboniferous to Cretaceous age. Only a few examples of localised folding/faulting have been noted in the shallow conductive stratigraphy that have potentially formed above isolated salt domes. Distinct zones of disruption within the shallow conductive stratigraphy generally occur along the margins of the present-day salt depocentre, resulting from dissolution and movement of salt during several stages. This study demonstrates the potential AEM has to assist in mapping salt-related structures, with implications for geological storage of hydrogen. In addition, this study produces a regional near-surface multilayered chronostratigraphic interpretation, which contributes to constructing a 3D national geological architecture, in support of environmental management, hazard mapping and resource exploration. <b>Citation: </b>Connors K. A., Wong S. C. T., Vilhena J. F. M., Rees S. W. & Feitz A. J., 2022. Canning Basin AusAEM interpretation: multilayered chronostratigraphic mapping and investigating hydrogen storage potential. In: Czarnota, K (ed.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, https://dx.doi.org/10.26186/146376

Exploring for the Future is a four year $100.5 million initiative by the Australian Government conducted in partnership with state and Northern Territory government agencies and universities that aims to boost northern Australia's attractiveness as a destination for investment in resource exploration. The acquisition of deep crustal seismic reflection data in the Kidson Sub-basin (Canning Basin) between the Kiwirrkurra community and Marble Bar in northern Western Australia was a major EFTF deliverable, and was completed in August 2018. This paper presents the preliminary geological interpretation of the sedimentary succession imaged by the Kidson Sub basin seismic line.

The Canning Basin is a large intracratonic basin in Western Australia that remains one of the least explored Paleozoic basins in the world. Recent resource assessments have renewed interest in the basin, in particular for unconventional gas within Ordovician organic-rich shales, although these proposed plays remain untested. Exploring for the Future (EFTF) is a program dedicated to exploring Australia’s resource potential and boosting investment. Launched in 2016 with $100.5 million in funding from the Australian Government, it initially focused on northern Australia. Geoscience Australia and the Geological Survey of Western Australia collected new, pre-competitive datasets in the frontier Kidson Sub-basin to better understand its energy resource potential. Here we present an overview of the regional petroleum systems with a focus on the modelled Ordovician section within the Kidson Sub-basin and Barnicarndy Graben (previously Waukarlycarly Embayment). Three Larapintine petroleum systems are recognised in the Ordovician (L2), Devonian‒earliest Carboniferous (L3), and Carboniferous (L4) successions of the Canning Basin. Integration of petroleum systems with interpretation of the Kidson Sub-basin seismic survey 18GA-KB1 shows that the Ordovician section is extensive, and hence, the Larapintine 2 Petroleum System is of most exploration interest across this frontier region. Ordovician organic-rich units are known within the Nambeet (Tremadocian–Floian), Goldwyer (Dapingian–Darriwilian) and Bongabinni (Sandbian) formations; however, only Nambeet and Goldwyer source rocks are considered to be present within the Kidson Sub-basin. Oil and gas shows occur within Ordovician and Silurian reservoirs, of which many are sub-salt. The range in the geochemical profile of shows from Goldwyer, Nita and Sahara reservoirs implies generation from numerous source units within the Goldwyer and Bongabinni formations. The origin of oil and gas shows within the Nambeet and Willara formations, including those in Patience 2 in the Kidson Sub-basin, is unknown but imply the presence of multiple lower Ordovician source units and include the Nambeet Formation. Within the Kidson Sub-basin, Kidson 1 is located closest to the main depocentre, whereas other wells are proximal to shelves and margins. In general, these latter wells return discouraging hydrocarbon potential pyrolysis parameters as a consequence of their sub-optimal location for source rock development and thermal maturation history. Kidson 1 penetrates the Goldwyer Formation and has TOC contents that are considered more representative of source rock richness (although diesel contamination is present) within the depocentre. Data paucity is the key limitation in resource evaluation for the Kidson Sub-basin, as such, an evaluation with volumetrics is not possible. 1D petroleum systems models of ten wells located in either the Kidson Sub-basin, Willara Sub-basin or Barnicarndy Graben were constructed to resolve whether potential source rocks were capable of hydrocarbon generation. The models demonstrate maturation of Ordovician source rocks resulting in near-complete transformation during Permian to Triassic deposition and burial. A 2D petroleum systems model constructed along the regional 2D seismic line 18GA-KB1 predicts full maturation of Larapintine 2 source rocks in the deeper parts of the Kidson Sub-basin. Expulsion and migration is considered to have taken place during the Permian‒Triassic, with potential accumulations trapped by evaporitic and fine-grained units of Ordovician and Silurian age.

This report presents the results of chemostratigraphic analyses for samples of the Waukarlycarly 1 deep stratigraphic well drilled in in the Waukarlycarly Embayment of the Canning Basin. The drilling of the well was funded by Geoscience Australia’s Exploring for the Future initiative to improve the understanding of the sub-surface geology of this underexplored region of the southern Canning Basin. The well was drilled in partnership with Geological Survey of Western Australia (GSWA) as project operator. Waukarlycarly 1 reached a total depth (TD) of 2680.53 m at the end of November 2019 and was continuously cored from 580 mRT to TD. The work presented in this report constitutes part of the post-well data acquisition. An elemental and isotope chemostratigraphic study was carried out on 100 samples of the well to enable stratigraphic correlations to be made across the Canning Basin within the Ordovician section known to host source rocks. Nine chemostratigraphically distinct sedimentary packages are identified in the Waukarlycarly 1 well and five major chemical boundaries that may relate to unconformities, hiatal surfaces or sediment provenance changes are identified. The Ordovician sections in Waukarlycarly 1 have different chemical signals in comparison to those in other regional wells, suggestive of a different provenance for the origin of the sediments in the Waukarlycarly Embayment compared to the Kidson Sub-basin (Nicolay 1) and Broome Platform (Olympic 1).

High-precision radiometric dating using Chemical Abrasion-Isotope Dilution Thermal Ionisation Mass Spectrometry (CA-IDTIMS) has allowed the recalibration of the numerical ages of Permian and Triassic spore-pollen palynozones in Australia. These changes have been significant, with some zonal boundaries in the Permian shifting by as much as six million years, and some in the Triassic by more than twice that. Most of the samples analysed came from eastern Australian coal basins (Sydney, Gunnedah, Bowen, Galilee) where abundant volcanic ash beds occur within the coal-bearing successions. The recalibrations of these widely used palynozones have implications for the dating of geological events outside the basins from where samples were obtained. Our revised dates for the Permian palynozones can now be applied to all Permian basins across Australia, including the Perth, Carnarvon, Canning and Bonaparte basins (along the western and northern continental margins), the Cooper and Galilee basins (in central Australia), and the Bowen, Gunnedah and Sydney basins (in eastern Australia). Revised regional stratigraphic frameworks are presented here for some of these basins. The impact of an improved calibration of biostratigraphic zones to the numerical timescale is broad and far-reaching. For example, the more accurate stratigraphic ages are the more closely burial history modelling will reflect the basin history, thereby providing control on the timing of kerogen maturation, and hydrocarbon expulsion and migration. These improvements can in turn be expected to translate in to improved exploration outcomes. We have initially focused on the Permian and provide preliminary results for the Triassic, but intend to expand recalibrations to include Jurassic, Cretaceous and Paleozoic successions beyond the Permian. Preliminary data indicates that significant changes to these calibrations are also likely.

The Ordovician is an important period in Earth’s history with exceptionally high sea levels that facilitated the Great Ordovician Biodiversification Event. This crucial biological event is regarded as the second most significant evolutionary event in the history of Paleozoic life, after the Cambrian radiation. The present study integrates palynological, petrographic, molecular and stable isotopic (δ13C of biomarkers) analyses of cores from five boreholes that intersected the Goldwyer Formation, Canning Basin, Western Australia, to determine depositional environments and microbial diversity within a Middle Ordovician epicontinental, tropical sea. A major transgression was detected in the laminated shales of the lower Goldwyer Formation (Units 1+2) which were deposited in anoxic bottom waters, as confirmed by low (<1) Pristane/Phytane ratios, and elevated dibenzothiophene and gammacerane indices. A second, less extensive, flooding event is recorded by shallow marine sediments of the upper Goldwyer Formation (Unit 4). Cores of these sediments, from two wells (Solanum-1 and Santalum-1A) are bioturbated and biomarkers indicate relatively oxygenated conditions, as well as the presence of methanotrophic bacteria, as determined from the high 3-methylhopane indices. Typical Ordovician marine organisms including acritarchs, chitinozoans, conodonts and graptolites were present in the lower and upper Goldwyer Formation, whereas the enigmatic organism Gloeocapsomorpha prisca (G. prisca) was only detected in Unit 4. The presence of G. prisca was based on microfossils and specific biosignatures presenting an odd-over-even predominance in the C15 to C19 n-alkane range. Cryptospores were identified in Unit 4 in the Theia-1 well and are most likely derived from bryophytes, making this is the oldest record of land plants in Australian Middle Ordovician strata. Biomarkers in some samples from Unit 4 that also support derivation from terrestrial organic matter include retene, benzonaphthofurans and δ13C-depleted mid-chain n-alkanes. This research contributes to understanding Ordovician marine environments from a molecular perspective since few biomarker studies have been undertaken on age-equivalent sections. Furthermore, the identification of the oldest cryptospores in Australia and their corresponding terrestrial biomarkers contributes to understanding the geographical evolution of early land plants.

The Exploring for the Future (EFTF) program is an initiative by the Australian Government dedicated to boosting investment in resource exploration in Australia. Geoscience Australia’s EFTF Energy program is aimed at improving the understanding of the petroleum resource potential of Australia. A key to understanding resource potential and basin evolution is a reliable time frame to correlate rock units. This palynological reconnaissance study focusses on the acid-resistant organic-walled microfossils (or palynomorphs) recovered from 42 samples taken within the fully cored Lower Ordovician Nambeet Formation (1354.80–2435.04 mRT) in the Barnicarndy 1 stratigraphic well, located in the Barnicarndy Graben, Canning Basin. The lack of palynomorph recovery from the Barnicarndy Formation, Yapukarninjarra Formation, and Neoproterozoic Yeneena Basin, also intersected in this well, means that the age of those units remain undated using micropalaeontological methods. The purpose of this study is to assess the yield and preservation of recovered palynomorphs, and determine their utility for regional, and international, correlation of the Lower Ordovician sedimentary section. Although the total organic matter content of the sampled Lower Ordovician core is typically low (average ≤0.2 wt%), reflecting sediment deposition in an oxidising, open marine environment, a diverse suite of palynomorphs has been identified and includes: acritarchs (of probable algal origin); other algal microfossils (including green algae, or prasinophytes); probable cyanobacteria; cryptospores (derived from the earliest land plants); graptolites and chitinozoans (both from extinct marine groups); scolecodonts (detached elements of worm jaws); and organic-walled tubes, some of which are of either probable fungal or cyanobacterial origin. Digital images accompany this record and include examples of all of these aforementioned microfossils. Microfossil yield per sample is, mostly, low; and preservation ranges from poor, where specimens are either fragmentary and/or distorted by pyrite crystal growth, to good; and commonly both preservation states occur together within the same sample. As with the admixture of preservation states per sample, palynomorph colour, typically used as an indicator of thermal maturity of organic matter, commonly ranges from thermally mature (brown) to over mature (black), often within the same Lower Ordovician core sample. This is tempered by the fact that these observations are based, mostly, on oxidised kerogen preparations, but, the relative maturity indicators remain valid. The occurrence of acritarchs assigned to the Rhopaliophora pilata–R. palmata complex, together with Athabascaella playfordii, and Aryballomorpha grootaertii, allows correlation with assemblages previously recovered from the Nambeet Formation intersected in two petroleum exploration wells in the Canning Basin (Samphire Marsh 1, type section; and Acacia 2). These species also occur globally, with A. grootaertii recovered from sedimentary rocks in southern China and Canada that have been independently dated as Early Ordovician, late Tremadocian–early Floian (about 475–482 Ma). Conodont faunas from cores in Barnicarndy 1 record the same (late Tremadocian–early Floian) age, which enhances the utility of A. grootaertii for age dating. The dates also demonstrate that the Barnicarndy 1 well intersects some of the oldest Paleozoic sedimentary rocks in the Canning Basin. There are compositional differences between the palynological assemblages from the younger Samphire Marsh Member and underlying Fly Flat Member of the Nambeet Formation which, despite difficulties in sample processing, are genuine and reflect changes in the depositional environment. Most obvious is the record of Gloeocapsomorpha prisca and ?Eomerismopedia maureeniae, both of probable cyanobacterial affinity, with in situ occurrences in the Lower Ordovician Samphire Marsh Member. Earlier studies suggested that G. prisca was confined to younger (Middle) Ordovician palynological assemblages in the Canning Basin, and its common abundance was used as a biozone marker, but the occurrences reported here and in unpublished studies, have shown that this is no longer applicable. In younger Ordovician formations in the Canning Basin (notably the upper Goldwyer Formation), and globally, G. prisca is an important organism contributing to the hydrocarbon potential of Paleozoic marine source rocks. If present in greater abundance elsewhere in the basin, it could increase the petroleum prospectivity of the Nambeet Formation. A distinctively shaped acritarch, of probable algal origin, assigned to the genus Dactylofusa is restricted to an assemblage from the Fly Flat Member, and may be useful for future basinal biozone correlation. Most samples from the Samphire Marsh Member contain early land-plant spores, of probable bryophyte affinity, that sometimes occur together with irregularly-shaped spore clusters, likely derived from aeroterrestrial charophyte algae; both of which are collectively known as cryptospores. In addition, Grododowon orthagonalis, superficially similar to E. maureeniae and recorded in some samples from the Samphire Marsh Member, is also considered to be of charophyte algal origin. The cryptospores include the species Dyadospora murusattenuata, Tetraplanarisporites sp., and Laevolancis divellomedium. Collectively, these cryptospores are important as they herald the first emergence of plants onto wetlands during the Early Ordovician; and being of late Tremadocian–early Floian age, they are amongst the oldest land-plant spores known in Australia and globally. The record of cryptospores from Barnicarndy 1 enhances those recently reported from the Nambeet Formation in Samphire Marsh 1, and from the lower Goldwyer Formation in Theia 1. Locally, the cryptospore record demonstrates a supply of terrestrial material into the marine environment during deposition of the Samphire Marsh Member. Globally, records of these cryptospores contribute to the understanding of the evolution and geographic distribution of the earliest land flora. Inevitably, there are microfossils found in this study that could be described as new species, and a detailed systematic study of all fossil groups is recommended to realise their utility for zonal correlation and age dating. The palynological data presented here provide complementary information to the conodont age dating, organic petrological, and organic geochemical studies conducted on the Barnicarndy 1 core. Collectively, these studies contribute to a better understanding of the depositional history and hydrocarbon prospectivity of the Canning Basin.