Product catalogue
A spectroscopic study of the stability of uranyl-carbonate complexes at 25–150 °C and re-visiting the data available for uranyl-chloride, uranyl-sulfate, and uranyl-hydroxide species
The stabilities of uranyl-carbonate and uranyl-hydroxide aqueous complexes were experimentally determined at temperatures ranging from 25 to 125 °C using in situ UV–vis and Raman spectroscopic techniques. Combined with earlier determinations of the stability of chloride, sulfate, and hydroxide complexes at temperatures up to 250 °C, these data permit to create a consolidated dataset suitable for modeling of U(VI) mobilization in natural systems. The parameters of the Modified Ryzhenko-Bryzgalin and the Helgeson-Kirkham-Flowers (HKF) Equations of State (EoS) were derived based on this dataset and used for thermodynamic modeling different scenarios of U(VI) mobilization. These models suggest that at conditions relevant to natural systems, carbonate-mediated transport of U(VI) is likely suppressed by the high stability of solid UO2(OH)2 and Na2U2O7. In contrast, sulfate-mediated mobilization mechanisms are highly efficient at acidic and near-neutral pH conditions and can lead to effective hydrothermal mobilization of U(VI).
<b>Citation:</b> A. Migdisov, E. Bastrakov, C. Alcorn, M. Reece, H. Boukhalfa, F.A. Capporuscio, C. Jove-Colon, A spectroscopic study of the stability of uranyl-carbonate complexes at 25–150 °C and re-visiting the data available for uranyl-chloride, uranyl-sulfate, and uranyl-hydroxide species, <i>Geochimica et Cosmochimica Acta</i>, 2024, ISSN 0016-7037, https://doi.org/10.1016/j.gca.2024.04.023.
Simple
Identification info
- Date (Creation)
- 2023-08-17T22:00:00
- Date (Publication)
- 2024-05-28T22:36:44
- Citation identifier
- Geoscience Australia Persistent Identifier/https://pid.geoscience.gov.au/dataset/ga/148694
- Cited responsible party
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Role Organisation / Individual Name Details Publisher Commonwealth of Australia (Geoscience Australia)
Voice Author Migdisov, A.
External Contact Author Bastrakov, E.
Internal Contact Author Alcorn, C.
External Contact Author Reece, M.
External Contact Author Boukhalfa, H.
External Contact Author Capporuscio, F.A.
External Contact Author Jove-Colon, C.
External Contact Publisher Elsevier Ltd
External Contact
- Name
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Geochimica et Cosmochimica Acta
- Purpose
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Release of a new dataset of thermodynamic properties of aqueous uranium species for mineral systems modelling.
- Status
- Completed
- Point of contact
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Role Organisation / Individual Name Details Resource provider Minerals, Energy and Groundwater Division
External Contact Point of contact Commonwealth of Australia (Geoscience Australia)
Voice Point of contact Bastrakov, E.
Internal Contact
- Spatial representation type
- Topic category
-
- Geoscientific information
Extent
))
- Maintenance and update frequency
- Not planned
Resource format
- Title
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Product data repository: Various Formats
- Website
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Data Store directory containing the digital product files
Data Store directory containing one or more files, possibly in a variety of formats, accessible to Geoscience Australia staff only for internal purposes
- Project
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Critical Minerals
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- Keywords
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mineral systems
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- Keywords
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Geochemistry
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- Keywords
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hydrogeochemistry
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- theme.ANZRC Fields of Research.rdf
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Inorganic Geochemistry
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- Keywords
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hydrothermal
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- Keywords
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uranyl
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- Keywords
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thermodynamic stability
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- Keywords
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Published_External
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Resource constraints
- Title
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All rights reserved
- Access constraints
- License
- Use constraints
- License
- Other constraints
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(c) 2024 Elsevier Ltd.
Resource constraints
- Title
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Australian Government Security Classification System
- Edition date
- 2018-11-01T00:00:00
- Classification
- Unclassified
- Classification system
-
Australian Government Security Classification System
- Language
- English
- Character encoding
- UTF8
Distribution Information
- Distributor contact
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Role Organisation / Individual Name Details Distributor Commonwealth of Australia (Geoscience Australia)
Voice facsimile
- OnLine resource
-
Link to Journal
Link to Journal
- Distribution format
-
Resource lineage
- Statement
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<div>Mineral systems modelling and concepts</div>
Metadata constraints
- Title
-
Australian Government Security Classification System
- Edition date
- 2018-11-01T00:00:00
- Classification
- Unclassified
Metadata
- Metadata identifier
-
urn:uuid/bd6489e0-ec4f-455b-afd9-f00457f8e489
- Title
-
GeoNetwork UUID
- Language
- English
- Character encoding
- UTF8
- Contact
-
Role Organisation / Individual Name Details Point of contact Commonwealth of Australia (Geoscience Australia)
Voice Point of contact Bastrakov, E.
Internal Contact
Type of resource
- Resource scope
- Document
- Name
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Journal Article / Conference Paper
Alternative metadata reference
- Title
-
Geoscience Australia - short identifier for metadata record with
uuid
- Citation identifier
- eCatId/148694
- Date info (Creation)
- 2024-04-22T01:48:06
- Date info (Revision)
- 2024-04-22T01:48:06
Metadata standard
- Title
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AU/NZS ISO 19115-1:2014
Metadata standard
- Title
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ISO 19115-1:2014
Metadata standard
- Title
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ISO 19115-3
- Title
-
Geoscience Australia Community Metadata Profile of ISO 19115-1:2014
- Edition
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Version 2.0, September 2018
- Citation identifier
- http://pid.geoscience.gov.au/dataset/ga/122551