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Carbon Geochemistry of Cold Seeps: Methane Fluxes and Transformation in Sediments from Kazan Mud Volcano, Eastern Mediterranean Sea

Despite growing concerns about potential enhancement of global warming and slope failure by methane produced by gas hydrate dissociation, much uncertainty surrounds estimates of gas hydrate reservoir sizes, as well as methane fluxes and oxidation rates at the sea floor. For cold seep sediments of the eastern Mediterranean Sea, depth-dependent methane concentrations and rates of anaerobic oxidation of methane (AOM) are constrained by modeling the measured pore-water sulfate profile. The calculated dissolved methane distribution and flux are sensitive to the advective flow velocity, which is estimated from the depth distributions of conservative pore-water constituents (Na, B). Near-complete anaerobic oxidation of the upward methane flux is supported by the depth distributions of indicative biomarkers, and the carbon isotopic compositions of organic matter and dissolved inorganic carbon. Pore-water and solid-phase data are consistent with a narrow depth interval of AOM, 14-18 cm below the sediment-water interface. Based on an isotopic mass balance, the biomass of the microbial population carrying out oxidation of methane coupled to sulfate reduction at the given methane flux represents about 20% of the total organic carbon, which is a significant pool of in situ formed organic matter. Model results indicate that the asymptotic methane concentration is reached a few meters below the sediment surface. The predicted asymptotic concentration is close to the in situ saturation value with respect to gas hydrate, suggesting that the rate of shallow gas hydrate formation is controlled by the ascending methane flux. The proposed model approach can be used to predict the formation of gas hydrate, and to quantify methane fluxes plus transformation rates in surface sediments where fluid advection is an important transport mechanism.

Simple

Identification info

Date (Publication)
2003-01-01T00:00:00
Citation identifier
Geoscience Australia Persistent Identifier/https://pid.geoscience.gov.au/dataset/ga/69612

Citation identifier
Digital Object Identifier/http://dx.doi.org/10.1016/S0012-821X(03)00226-7

Cited responsible party
Role Organisation / Individual Name Details
Author

Haese, R.R.

1
Author

Meile, C.

2
Author

Van Cappellen, P.

3
Author

de Lange, G.J.

4
Point of contact
Role Organisation / Individual Name Details
Custodian

EGD

Owner

Commonwealth of Australia (Geoscience Australia)

Custodian

Commonwealth of Australia (Geoscience Australia)

Voice
Topic category
  • Geoscientific information

Extent

N
S
E
W


Maintenance and update frequency
Unknown
Keywords
  • External Publication

  • Scientific Journal Paper

Theme
  • model

  • marine

Australian and New Zealand Standard Research Classification (ANZSRC)
  • Earth Sciences

Keywords
  • Published_External

Resource constraints

Title

Creative Commons Attribution 4.0 International Licence

Alternate title

CC-BY

Edition

4.0

Website

http://creativecommons.org/licenses/

Access constraints
License
Use constraints
License

Resource constraints

Title

Australian Government Security ClassificationSystem

Edition date
2018-11-01T00:00:00
Website

https://www.protectivesecurity.gov.au/Pages/default.aspx

Classification
Unclassified
Language
English
Character encoding
UTF8

Distribution Information

Distributor contact
Role Organisation / Individual Name Details
Distributor

Commonwealth of Australia (Geoscience Australia)

Voice
OnLine resource

Link to Publication

Link to Publication

Resource lineage

Statement

Unknown

Hierarchy level
Non geographic dataset
Other

External Publication

Description

Source data not available.

Metadata constraints

Title

Australian Government Security ClassificationSystem

Edition date
2018-11-01T00:00:00
Website

https://www.protectivesecurity.gov.au/Pages/default.aspx

Classification
Unclassified

Metadata

Metadata identifier
urn:uuid/a05f7892-ee2e-7506-e044-00144fdd4fa6

Title

GeoNetwork UUID

Language
English
Character encoding
UTF8
Contact
Role Organisation / Individual Name Details
Point of contact

Commonwealth of Australia (Geoscience Australia)

Voice

Type of resource

Resource scope
Document
Name

nonGeographicDataset

Alternative metadata reference

Title

Geoscience Australia - short identifier for metadata record with

uuid

Citation identifier
eCatId/69612

Metadata linkage

https://ecat.ga.gov.au/geonetwork/srv/eng/catalog.search#/metadata/a05f7892-ee2e-7506-e044-00144fdd4fa6

Date info (Revision)
2018-04-22T08:25:46
Date info (Creation)
2009-10-07T00:00:00

Metadata standard

Title

AU/NZS ISO 19115-1:2014

Metadata standard

Title

ISO 19115-1:2014

Metadata standard

Title

ISO 19115-3

Title

Geoscience Australia Community Metadata Profile of ISO 19115-1:2014

Edition

Version 2.0, September 2018

Citation identifier
https://pid.geoscience.gov.au/dataset/ga/122551

 
 

Spatial extent

N
S
E
W


Keywords

marine model

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Associated resources

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