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Germanium, indium, gallium and cadmium in zinc ores: a mineral system approach

Sphalerite is the main Zn ore mineral and is the primary source of Cd, Ge and In and a minor source of Ga. Owing to a shift from fossil fuel to renewable energy sources, these four minor elements have progressively become more important to the economy. Despite this, resources of Cd, Ga, Ge and In are rarely reported as these metals are not considered material to the economics of resource development. As a result, the distribution of these elements between and within deposits is poorly known, and national and international resources are largely unreported.


Following previous studies, we have compiled analytical data for Cd, Ga, Ge and In from sphalerite and used global and local ore geochemical datasets to assess geochemical controls on the concentration of these elements in Zn deposits. Our results are similar to previous studies and suggest that lower-temperature deposits are enriched in Ge whereas higher-temperature deposits are enriched in In. However, modelling of hydrothermal geochemistry indicates other factors are important in concentrating these metals. In particular, the oxidation state of the fluid (oxidised versus reduced) and the depositional mechanisms also have a strong influence in Ga, Ge and In enrichment. Reduction of oxidised fluids is particularly effective in depositing Ge, whereas cooling very effectively deposits In and, in some cases, Ge. As a consequence, some higher-temperature deposits (e.g. high sulfidation epithermal and some volcanic-hosted massive sulfide) deposits can be Ge-enriched, and some lower-temperature deposits (e.g. siliciclastic-carbonate shale-hosted deposits) can be enriched in In.


Using the existing ore geochemical data and calculated characteristic Ge/Zn and In/Zn ratios, indicative estimates have been made on the endowment of Australian Zn deposits of Ge and In. These estimates highlight the potential of the North Australian Zinc Belt for Ge and for VHMS deposits for In. Although there is a large amount of uncertainty in the estimates, they are indicative of the potential for these metals in Australia.


This dataset accompanies a paper published in the Australian Journal of Earth Sciences (AJES) (See Associated Records)

Simple

Identification info

Date (Creation)
2023-07-10T13:49:00
Date (Publication)
2024-12-04T23:20:07
Citation identifier
Geoscience Australia Persistent Identifier/https://pid.geoscience.gov.au/dataset/ga/148619

Citation identifier
Digital Object Identifier/https://dx.doi.org/10.26186/148619

Cited responsible party
Role Organisation / Individual Name Details
Publisher

Commonwealth of Australia (Geoscience Australia)

Voice
Author

Huston, D.

MEG Internal Contact
Author

Bastrakov, E.

MEG Internal Contact
Purpose

Dataset to accompany publication in peer-reviewed journal

Status
Completed
Point of contact
Role Organisation / Individual Name Details
Point of contact

Commonwealth of Australia (Geoscience Australia)

Voice
Point of contact

Hawkins, S.

MEG Internal Contact
Resource provider

Minerals, Energy and Groundwater Division

External Contact
Spatial representation type
Topic category
  • Geoscientific information

Extent

N
S
E
W


Maintenance and update frequency
As needed

Resource format

Title

Product data repository: Various Formats

Website

Data Store directory containing the digital product files

Data Store directory containing one or more files, possibly in a variety of formats, accessible to Geoscience Australia staff only for internal purposes

theme.ANZRC Fields of Research.rdf
  • EARTH SCIENCES

  • Inorganic Geochemistry

  • GEOLOGY

  • GEOCHEMISTRY

Feature type
  • Sphalerite

Feature type
  • Zinc deposits

Feature type
  • Cadmium

Feature type
  • Gallium

Feature type
  • Germanium

Feature type
  • Indium

Keywords
  • Published_External

Resource constraints

Title

Creative Commons Attribution 4.0 International Licence

Alternate title

CC-BY

Edition

4.0

Website

http://creativecommons.org/licenses/

Access constraints
License
Use constraints
License
Other constraints

(c) Commonwealth of Australia (Geoscience Australia) 2024

Resource constraints

Title

Australian Government Security Classification System

Edition date
2018-11-01T00:00:00
Website

https://www.protectivesecurity.gov.au/Pages/default.aspx

Classification
Unclassified

Associated resource

Association Type
Informed
Title

Germanium, indium, gallium and cadmium in zinc ores: a mineral system approach

Citation identifier
150175

Citation identifier
503db95d-1373-4984-830f-0c12999f96f2

Website

http://pid.geoscience.gov.au/dataset/ga/150175

Link to eCat metadata record landing page

Language
English
Character encoding
UTF8

Distribution Information

Distributor contact
Role Organisation / Individual Name Details
Distributor

Commonwealth of Australia (Geoscience Australia)

Voice facsimile
OnLine resource

Download the dataset (zip) [6.4 MB]

Download the dataset (zip) [6.4 MB]

Distribution format
  • zip

    File decompression technique

    unzip

Resource lineage

Statement

This dataset was developed to accompany a peer-reviewed journal paper.

Metadata constraints

Title

Australian Government Security Classification System

Edition date
2018-11-01T00:00:00
Website

https://www.protectivesecurity.gov.au/Pages/default.aspx

Classification
Unclassified

Metadata

Metadata identifier
urn:uuid/3665cf13-a425-40be-862e-f902eecb7457

Title

GeoNetwork UUID

Language
English
Character encoding
UTF8
Contact
Role Organisation / Individual Name Details
Point of contact

Commonwealth of Australia (Geoscience Australia)

Voice
Point of contact

Hawkins, S.

MEG Internal Contact

Type of resource

Resource scope
Dataset

Alternative metadata reference

Title

Geoscience Australia - short identifier for metadata record with

uuid

Citation identifier
eCatId/148619

Metadata linkage

https://ecat.ga.gov.au/geonetwork/srv/eng/catalog.search#/metadata/5167d912-6784-4371-9938-3931e84ca6f1

Metadata linkage

https://ecat.ga.gov.au/geonetwork/srv/eng/catalog.search#/metadata/3665cf13-a425-40be-862e-f902eecb7457

Metadata linkage

https://ecat.ga.gov.au/geonetwork/dashboard/eng/catalog.search#/metadata/3665cf13-a425-40be-862e-f902eecb7457

Date info (Creation)
2019-04-08T01:55:29
Date info (Revision)
2019-04-08T01:55:29

Metadata standard

Title

AU/NZS ISO 19115-1:2014

Metadata standard

Title

ISO 19115-1:2014

Metadata standard

Title

ISO 19115-3

Title

Geoscience Australia Community Metadata Profile of ISO 19115-1:2014

Edition

Version 2.0, September 2018

Citation identifier
https://pid.geoscience.gov.au/dataset/ga/122551

 
 

Spatial extent

N
S
E
W


Keywords

Cadmium Gallium Germanium Indium Sphalerite Zinc deposits
theme.ANZRC Fields of Research.rdf
EARTH SCIENCES GEOCHEMISTRY GEOLOGY Inorganic Geochemistry

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Associated resources

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