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Evaluating the performance of soil flux surveys and inversion methods for quantification of CO2 leakage

Understanding the near surface migration patterns and rates of efflux of CO<sub>2</sub> is important for developing effective monitoring and verification programs for the geological storage of CO<sub>2</sub>. Soil flux surveys are a well-established technique for characterising surface CO<sub>2</sub> emission sources from controlled release sites, CO<sub>2</sub>storage sites or natural CO<sub>2</sub>seeps. The performance of four interpolation methods; arithmetic mean (AM), two minimum variance unbiased estimators (MVUE), and a newly developed geostatistical cubic surface were evaluated using 21 soil flux surveys conducted over two controlled release experiments in 2012 and 2013, at the Ginninderra controlled release facility, Australia. Data was binned to approximate a regular sampling grid for improved performance of the whole-of-field AM and MVUE averaging techniques. The AM and MVUE methods were highly sensitive to deviations in the statistical distribution of the data, and performed inconsistently across the two experiments. These two methods proved ill-suited for application to CO<sub>2</sub> leak quantification due to their inflexible sampling and distribution requirements. The cubic technique provided the best net emission estimates across both experiments, and when applied at different bin sizes, estimating the true release rate to within 20% for the 2012 experiment and 45% below the release rate for the 2013 experiment. The cubic method is well-suited for CO<sub>2</sub> leak quantification because it is not limited by assumptions of the data’s spatial or statistical distribution. Net H<sub>2</sub>O emissions of 29 kg/d were observed coincident with the high CO<sub>2</sub> flux zones in the field. The interpolation methods were applied with similar results on soil flux surveys taken from a natural seepage site in Qinghai, China. Gravity currents appear to describe the observed soil flux and soil gas behavior at Ginninderra, i.e. the observed lateral migration of CO<sub>2</sub>in the subsurface. Subsurface migration was also strongly influenced by the relative depth of the groundwater. Thus the low water table and greater vadose zone in the 2013 experiment is suspected to facilitate greater lateral CO<sub>2</sub> migration and explain the poor closure of the CO<sub>2</sub> balance.


<b>Citation:</b> I.F. Schroder, P. Wilson, A.F. Feitz, J. Ennis-King, <i>Evaluating the Performance of Soil Flux Surveys and Inversion Methods for Quantification of CO2 Leakage</i>, Energy Procedia, Volume 114, 2017, Pages 3679-3694, ISSN 1876-6102, https://doi.org/10.1016/j.egypro.2017.03.1499.

Simple

Identification info

Date (Publication)
2016-01-01T00:00:00
Date (Revision)
2024-10-17T03:44:24
Citation identifier
Geoscience Australia Persistent Identifier/https://pid.geoscience.gov.au/dataset/ga/90000

Cited responsible party
Role Organisation / Individual Name Details
Publisher

Elsevier Ltd

External Contact
Author

Schroder, I.

MEG Internal Contact
Author

Wilson, P.

External Contact
Author

Feitz, A.

MEG Internal Contact
Author

Ennis-King, J.

External Contact
Name

Energy Procedia

Issue identification

Volume 114, July 2017

Page

3679-3694

Purpose

Journal article communicating science conducted monitoring for CCS

Status
Completed
Point of contact
Role Organisation / Individual Name Details
Point of contact

Commonwealth of Australia (Geoscience Australia)

Voice
Resource provider

Minerals, Energy and Groundwater Division

External Contact
Point of contact

Schroder, I.

MEG Internal Contact
Topic category
  • Climatology, meteorology, atmosphere

Extent

Extent

N
S
E
W


Maintenance and update frequency
As needed

Resource format

Title

Product data repository: Various Formats

Website

Data Store directory containing the digital product files

Data Store directory containing one or more files, possibly in a variety of formats, accessible to Geoscience Australia staff only for internal purposes

theme.ANZRC Fields of Research.rdf
  • EARTH SCIENCES

Keywords
  • Carbon Dioxide - CO2

Keywords
  • emissions

Keywords
  • flux

Keywords
  • monitoring

Keywords
  • interpolation

Keywords
  • quantification

Keywords
  • controlled release

Keywords
  • Published_External

Resource constraints

Title

Creative Commons Attribution 4.0 International Licence

Alternate title

CC-BY

Edition

4.0

Website

http://creativecommons.org/licenses/

Access constraints
License
Use constraints
License
Other constraints

© 2017 The Author(s)

Resource constraints

Title

Australian Government Security ClassificationSystem

Edition date
2018-11-01T00:00:00
Website

https://www.protectivesecurity.gov.au/Pages/default.aspx

Classification
Unclassified
Language
English
Character encoding
UTF8

Distribution Information

Distributor contact
Role Organisation / Individual Name Details
Distributor

Commonwealth of Australia (Geoscience Australia)

Voice facsimile
OnLine resource

Link to Journal

Link to Journal

Distribution format

Resource lineage

Statement

prepared for GHGT13 by Ivan Schroder (coauthor Andrew Feitz) using data acquired from the Ginninderra controlled release facility in partnership with the CO2CRC (and collaborators within).

Hierarchy level
Non geographic dataset
Other

External Publication

Description

Source data not available.

Metadata constraints

Title

Australian Government Security ClassificationSystem

Edition date
2018-11-01T00:00:00
Website

https://www.protectivesecurity.gov.au/Pages/default.aspx

Classification
Unclassified

Metadata

Metadata identifier
urn:uuid/2b50274f-30b0-0f74-e053-10a3070a242f

Title

GeoNetwork UUID

Language
English
Character encoding
UTF8
Contact
Role Organisation / Individual Name Details
Point of contact

Commonwealth of Australia (Geoscience Australia)

Voice
Point of contact

Schroder, I.

MEG Internal Contact

Type of resource

Resource scope
Document
Name

Journal Articles

Alternative metadata reference

Title

Geoscience Australia - short identifier for metadata record with

uuid

Citation identifier
eCatId/90000

Metadata linkage

https://ecat.ga.gov.au/geonetwork/srv/eng/catalog.search#/metadata/2b50274f-30b0-0f74-e053-10a3070a242f

Metadata linkage

https://ecat.ga.gov.au/geonetwork/ofmJ3/eng/catalog.search#/metadata/2b50274f-30b0-0f74-e053-10a3070a242f

Metadata linkage

https://ecat.ga.gov.au/geonetwork/ofmj3/eng/catalog.search#/metadata/2b50274f-30b0-0f74-e053-10a3070a242f

Date info (Revision)
2018-04-11T02:47:07
Date info (Creation)
2016-02-09T00:00:00

Metadata standard

Title

AU/NZS ISO 19115-1:2014

Metadata standard

Title

ISO 19115-1:2014

Metadata standard

Title

ISO 19115-3

Title

Geoscience Australia Community Metadata Profile of ISO 19115-1:2014

Edition

Version 2.0, September 2018

Citation identifier
https://pid.geoscience.gov.au/dataset/ga/122551

 
 

Spatial extent

N
S
E
W


Keywords

Carbon Dioxide - CO2 controlled release emissions flux interpolation monitoring quantification
theme.ANZRC Fields of Research.rdf
EARTH SCIENCES

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