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SHRIMP U–Pb–Th xenotime (YPO4) geochronology: a novel approach for the correction of SIMS matrix effects

Xenotime (YPO4) occurs in a wide range of geological environments, but its potential to establish the timing of mineralisation and sediment diagenesis has been the focus of most recent studies. Xenotime in these settings usually has a low uranium content (typically < 1000 ppm) and occurs as microscopic crystals (< 20 μm diameter), either individually or as outgrowths on a zircon substrate. Large radius ion microprobes, such as the SHRIMP or Cameca 1270/1280, that have high sensitivity and spatial resolution, are well suited for the U–Pb–Th analysis of xenotime from such environments. SIMS U–Pb–Th analyses of xenotime, however, are prone to significant U–Pb–Th matrix effects (ME) that are related to the wide natural range of U (0–6 wt%) and rare earth element (REE) (ΣREE: 12–22 wt%) concentrations in this mineral. For SHRIMP U–Pb–Th xenotime analyses, a 1 wt% increase in U concentration, relative to the U–Pb–Th calibration reference material (RM), will on average cause a corresponding increase in the measured 206Pb/238U and 208Pb/232Th of approximately 15% and 14% respectively. Similarly, a 1 wt% contrast in ΣREE causes an increase of about 1.2% in 206Pb/238U and about 1.7% in 208Pb/232Th. Correction for these chemically-induced matrix effects requires the concurrent analysis of three xenotime reference materials (RMs) which have known ages and a range of U and ΣREE contents that have been determined accurately by electron probe microanalysis (EPMA). A least squares methodology is used to derive correction coefficients that relate the SHRIMP U–Pb–Th ME to the U and ΣREE concentrations for the RMs. Crucial to the success of this technique is the use of one dimensional (1-D) calibrations using 206Pb+/270[UO2]+ and 208Pb+/248[ThO]+. Processing is carried out in two steps: the first derives the correction coefficients to matrix correct the 206Pb+/270[UO2]+ and 208Pb+/248[ThO]+ ratios, the second processes the matrix corrected ratios to determine 206Pb/238U and 208Pb/232Th.


<b>Citation:</b> A.J. Cross, I.S. Williams, SHRIMP U–Pb–Th xenotime (YPO4) geochronology: A novel approach for the correction of SIMS matrix effects, <i>Chemical Geology</i>, Volume 484, 2018, Pages 81-108, ISSN 0009-2541,

https://doi.org/10.1016/j.chemgeo.2017.12.017.

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Date (Creation)
2017-05-19T15:50:00
Date (Publication)
2023-10-23T22:36:56
Citation identifier
Geoscience Australia Persistent Identifier/https://pid.geoscience.gov.au/dataset/ga/110588

Identifier

Codespace

Digital Object Identifier

Cited responsible party
Role Organisation / Individual Name Details
Author

Cross, A.

MEG Internal Contact
Author

Williams, I.S.

External Contact
Publisher

Elsevier B.V.

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Name

Chemical Geology

Issue identification

Volume 484, 5 May 2018

Page

81-108

Purpose

Article written for submission to Chemical Geology Journal

Status
Completed
Point of contact
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Point of contact

Commonwealth of Australia (Geoscience Australia)

Voice
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Cross, A.

MEG Internal Contact
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Minerals, Energy and Groundwater Division

External Contact
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  • Geoscientific information

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W


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As needed

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Title

Product data repository: Various Formats

Website

Data Store directory containing the digital product files

Data Store directory containing one or more files, possibly in a variety of formats, accessible to Geoscience Australia staff only for internal purposes

theme.ANZRC Fields of Research.rdf
  • EARTH SCIENCES

Keywords
  • Geochronology

Keywords
  • secondary ion mass spectrometry - SIMS

Keywords
  • sensitive high resolution ion microprobe - SHRIMP

Keywords
  • Xenotime

Keywords
  • U-Pb-Th matrix effects

Keywords
  • Published_External

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Title

Creative Commons Attribution 4.0 International Licence

Alternate title

CC-BY

Edition

4.0

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http://creativecommons.org/licenses/

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Crown Copyright © 2018

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Unclassified
Language
English
Character encoding
UTF8

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Commonwealth of Australia (Geoscience Australia)

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Link to Journal

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Article written for submission to Chemical Geology Journal

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Unclassified

Metadata

Metadata identifier
urn:uuid/d7b47b24-2130-4a18-b0a7-528ef45ef21e

Title

GeoNetwork UUID

Contact
Role Organisation / Individual Name Details
Point of contact

Commonwealth of Australia (Geoscience Australia)

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Owner

Cross, A.

MEG Internal Contact
Point of contact

Cross, A.

MEG Internal Contact

Type of resource

Resource scope
Document
Name

Journal Articles and Conference Papers

Alternative metadata reference

Title

Geoscience Australia - short identifier for metadata record with

uuid

Citation identifier
eCatId/110588

Metadata linkage

https://internal.ecat.ga.gov.au/geonetwork/srv/eng/search?uuid=d7b47b24-2130-4a18-b0a7-528ef45ef21e

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https://ecat.ga.gov.au/geonetwork/srv/eng/catalog.search#/metadata/d7b47b24-2130-4a18-b0a7-528ef45ef21e

Date info (Creation)
2017-05-19T05:43:27
Date info (Revision)
2017-05-19T05:53:04

Metadata standard

Title

AU/NZS ISO 19115-1:2014

Metadata standard

Title

ISO 19115-1:2014

Metadata standard

Title

ISO 19115-3

Edition date
2015-07-01T00:00:00
Title

Geoscience Australia Community Metadata Profile of ISO 19115-1:2014

Edition

Version 2.0, April 2015

 
 

Spatial extent

N
S
E
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Keywords

Geochronology U-Pb-Th matrix effects Xenotime secondary ion mass spectrometry - SIMS sensitive high resolution ion microprobe - SHRIMP
theme.ANZRC Fields of Research.rdf
EARTH SCIENCES

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