Authors / CoAuthors
Mernagh, T.P.
Abstract
Micro-Raman spectroscopy has become an important, versatile, non-destructive technique that is well-suited for the study of minerals and the inclusions they may contain. This technique is particularly useful in cases where the more common techniques (e.g. electron microprobe or X-ray diffraction analysis) cannot be used, for example, because of the impossibility to separate or prepare the sample to be studied. Another advantage of micro-Raman spectroscopy is that polymorphs with the same chemical composition can be easily distinguished. Furthermore, the Raman mapping technique can be used to generate a spectroscopic map of the sample. The wealth of detailed spectral information produced during Raman mapping has made this an extremely valuable technique for detailed studies of internally heterogeneous minerals. Because of the ability to perform analyses non-destructively, the micro-Raman technique has become an extremely valuable tool in the study of gemstones, which includes their identification and the identification of inclusions, and the detection of potential treatments done to enhance their colour and clarity. For example Millsteed et al. (2005) used micro-Raman spectroscopy for the characterisation of rhodonite from Broken Hill and also the solid and fluid inclusions trapped within the rhodonite. Raman analysis has also been applied to the study of minerals that were fully or partially amorphised due to the effects of radioactivity, as for instance in radiation-damaged zircon, monazite and biotite. The Raman spectra provide information on the degree of short-range order and crystallinity, respectively. Another application based on crystillinity has been the characterisation of carbonaceous materials ranging from kerogens to granulite-facies graphite. This has led to the development of new geothermometers based on the Raman spectra of carbonaceous materials in metasediments (e.g. Beyssac et al., 2002).
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nonGeographicDataset
eCat Id
70007
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- External PublicationAbstract
- ( Theme )
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- mineralogy
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- petrography
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- geochemistry
- Australian and New Zealand Standard Research Classification (ANZSRC)
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- Earth Sciences
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- Published_Internal
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2010-01-01T00:00:00
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