Isotope Geochemistry
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Australia has been, and continues to be, a leader in isotope geochronology and geochemistry. While new isotopic data is being produced with ever increasing pace and diversity, there is also a rich legacy of existing high-quality age and isotopic data, most of which have been dispersed across a multitude of journal papers, reports and theses. Where compilations of isotopic data exist, they tend to have been undertaken at variable geographic scale, with variable purpose, format, styles, levels of detail and completeness. Consequently, it has been difficult to visualise or interrogate the collective value of age and isotopic data at continental-scale. Age and isotopic patterns at continental scale can provide intriguing insights into the temporal and chemical evolution of the continent (Fraser et al, 2020). As national custodian of geoscience data, Geoscience Australia has addressed this challenge by developing an Isotopic Atlas of Australia, which currently (as of November 2020) consists of national-scale coverages of four widely-used age and isotopic data-types: 4008 U-Pb mineral ages from magmatic, metamorphic and sedimentary rocks 2651 Sm-Nd whole-rock analyses, primarily of granites and felsic volcanics 5696 Lu-Hf (136 samples) and 553 O-isotope (24 samples) analyses of zircon 1522 Pb-Pb analyses of ores and ore-related minerals These isotopic coverages are now freely available as web-services for use and download from the GA Portal. While there is more legacy data to be added, and a never-ending stream of new data constantly emerging, the provision of these national coverages with consistent classification and attribution provides a range of benefits: vastly reduces duplication of effort in compiling bespoke datasets for specific regions or use-cases data density is sufficient to reveal meaningful temporal and spatial patterns a guide to the existence and source of data in areas of interest, and of major data gaps to be addressed in future work facilitates production of thematic maps from subsets of data. For example, a magmatic age map, or K-Ar mica cooling age map sample metadata such as lithology and stratigraphic unit is associated with each isotopic result, allowing for further filtering, subsetting and interpretation. The Isotopic Atlas of Australia will continue to develop via the addition of both new and legacy data to existing coverages, and by the addition of new data coverages from a wider range of isotopic systems and a wider range of geological sample media (e.g. soil, regolith and groundwater).
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This Record presents new U–Pb geochronological data, obtained via Sensitive High Resolution Ion Micro Probe (SHRIMP), from 43 samples of predominantly igneous rocks collected from the East Riverina region of the central Lachlan Orogen, New South Wales. The results presented herein correspond to the reporting period July 2016–June 2020. This work is part of an ongoing Geochronology Project, conducted by the Geological Survey of New South Wales (GSNSW) and Geoscience Australia (GA) under a National Collaborative Framework agreement, to better understand the geological evolution and mineral prospectivity of the central Lachlan Orogen in southern NSW (Bodorkos et al., 2013; 2015; 2016, 2018; Waltenberg et al., 2019).
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Paleoproterozoic arc and backarc assemblages accreted to the south Laurentian margin between 1800 Ma and 1600 Ma, and previously thought to be indigenous to North America, more likely represent fragments of a dismembered marginal sea developed outboard of the formerly opposing Australian-Antarctic plate. Fugitive elements of this arc-backarc system in North America share a common geological record with their left-behind Australia-Antarctic counterparts, including discrete peaks in tectonic and/or magmatic activity at 1780 Ma, 1760 Ma, 1740 Ma, 1710-1705 Ma, 1690-1670 Ma, 1650 Ma and 1620 Ma. Subduction rollback, ocean basin closure and the arrival of Laurentia at the Australian-Antarctic convergent margin first led to arc-continent collision at 1650-1640 Ma and then continent-continent collision by 1620 Ma as the last vestiges of the backarc basin collapsed. Collision induced obduction and transfer of the arc and more outboard parts of the Australian-Antarctic backarc basin onto the Laurentian margin where they remained following later breakup of the Neoproterozoic Rodinia supercontinent. North American felsic rocks generally yield Nd depleted mantle model ages consistent with arc and backarc assemblages built on early Paleoproterozoic Australian crust as opposed to older Archean basement making up the now underlying Wyoming and Superior cratons. Appeared in Lithosphere (2019) 11 (4): 551–559, June 10, 2019.
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Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g., recognising geological provinces, studying geological processes) as well in archaeological (e.g., informing on past human migrations), palaeontological/ecological (e.g., investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g., validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa). The initial study targeted the northern parts of the Northern Territory and Queensland in Australia. The samples were taken from a depth of ~60-80 cm depth in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse grain-size fraction (<2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Preliminary results demonstrate a wide range of strontium isotopic values (0.7048 < 87Sr/86Sr < 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and gradients), large-scale (>100 km) patterns that appears to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a >500 km-long northwest-southeast trending low anomaly (87Sr/86Sr < 0.7182). Where carbonate or mafic igneous rocks dominate, a low to moderate strontium isotope signature is observed. In proximity to the outcropping Proterozoic metamorphic provinces of the Tennant, McArthur, Murphy and Mount Isa geological regions, high 87Sr/86Sr values (> 0.7655) are observed. A potential link between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g., weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations.
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The values and distribution patterns of the strontium (Sr) isotope ratio 87Sr/86Sr in Earth surface materials is of use in the geological, environmental and social sciences. Ultimately, the 87Sr/86Sr ratio of any mineral or biological material reflects its value in the rock that is the parent material to the local soil and everything that lives in and on it. In Australia, there are few large-scale surveys of 87Sr/86Sr available, and here we report on a new, low-density dataset using 112 catchment outlet (floodplain) sediment samples covering 529,000 km2 of inland southeastern Australia (South Australia, New South Wales, Victoria). The coarse (<2 mm) fraction of bottom sediment samples (depth ~0.6-0.8 m) from the National Geochemical Survey of Australia were fully digested before Sr separation by chromatography and 87Sr/86Sr determination by multicollector-inductively coupled plasma-mass spectrometry. The results show a wide range of 87Sr/86Sr values from a minimum of 0.7089 to a maximum of 0.7511 (range 0.0422). The median 87Sr/86Sr (± robust standard deviation) is 0.7199 (± 0.0112), and the mean (± standard deviation) is 0.7220 (± 0.0106). The spatial patterns of the Sr isoscape observed are described and attributed to various geological sources and processes. Of note are the elevated (radiogenic) values (≥~0.7270; top quartile) contributed by (1) the Palaeozoic sedimentary country rock and (mostly felsic) igneous intrusions of the Lachlan geological region to the east of the study area; (2) the Palaeoproterozoic metamorphic rocks of the central Broken Hill region; both these sources contribute fluvial sediments into the study area; and (3) the Proterozoic to Palaeozoic rocks of the Kanmantoo, Adelaide, Gawler and Painter geological regions to the west of the area; these sources contribute radiogenic material to the region mostly by aeolian processes. Regions of low 87Sr/86Sr (≤~0.7130; bottom quartile) belong mainly to (1) a few central Murray Basin catchments; (2) some Darling Basin catchments in the northeast; and (3) a few Eromanga geological region-influenced catchments in the northwest of the study area. The new spatial dataset is publicly available through the Geoscience Australia portal (https://portal.ga.gov.au/restore/cd686f2d-c87b-41b8-8c4b-ca8af531ae7e).
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The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the Offshore Energy Studies section. This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and facilitate exploration investment in Australia. The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018), Dorado 1 (2018), Dorado 2 (2019) and Dorado 3 (2019) wells in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata (Thompson, 2020; Thompson et al., 2015 and 2018). The current study aims to better understand this new petroleum system and establish its extent. As part of this program, a range of organic geochemical analyses were acquired on source rocks from the Roc 2 well with these data released in this report.
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<div>The first ca. 2.2 billion years of Earth history saw significant change; from a water-world dominated by an anoxic atmosphere and tonalitic continents, to the exposed landmasses, oxygenated atmosphere, and granitic crust of the Paleoproterozoic. Precisely when, and how, these major changes occurred, remain some of the most important and controversial questions in modern geoscience. Here, we present an extensive new zircon U-Pb-Hf-O isotopic and trace element dataset from Earth’s largest preserved Archean continent, the Superior Craton, Canada. These data record a number of fundamental geochemical changes through time and indicate a major geological and geodynamic transition occurred toward the end of Archean, at ca. 2.7 Ga. Our data show that, at >2704–2695 Ma, the southern Superior Craton had juvenile εHf, light to mantle-like δ18O, low (Eu/Eu*)/Y (drier/shallower crust), reduced ΔFMQ, less continental initial-U (Ui)/Yb, and more mantle-like Ui/Nb. At ca. 2704–2695 Ma, there is a marked transition in multiple datasets, including increases in δ18O, (Eu/Eu*)/Y, ΔFMQ, Ui/Yb and Ui/Nb data, together with more distinct arc-like trace element trends. These data reveal that at 2.7 Ga there was an increase in: (1) continental surface weathering, supported by increased sedimentation at <2.68 Ga, (2) oxidized and hydrous magmatism, and (3) surface material in magma sources. Together, these observations suggest a major geodynamic transition from ‘vertical’ tectonics (sagduction, drips) to north-dipping subduction at 2.7 Ga. The increase in δ18O suggests that proximal continental crust, probably in the northern Superior Craton, became emergent at this time, an inference supported by detrital zircon geochronology. Hence, this dataset links major geodynamic change to the emergence of continental crust and the rise of more oxidized magmatism. These fundamental changes to the Earth’s surface environment, tectonics, and atmosphere at 2.7 Ga, provide evidence for an Earth systems turning-point at the end of the Neoarchean.</div> This Abstract was submitted/presented to the 2022 Specialist Group in Geochemistry, Mineralogy and Petrology (SGGMP) Conference 7-11 November (https://gsasggmp.wixsite.com/home/biennial-conference-2021)
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Preamble: The 'National Geochemical Survey of Australia: The Geochemical Atlas of Australia' was published in July 2011 along with a digital copy of the NGSA geochemical dataset (http://dx.doi.org/10.11636/Record.2011.020). The NGSA project is described here: www.ga.gov.au/ngsa. The present dataset contains additional geochemical data obtained on NGSA samples: the Lead Isotopes Dataset. Abstract: Over 1200 new lead (Pb) isotope analyses were obtained on catchment outlet sediment samples from the NGSA regolith archive to document the range and patterns of Pb isotope ratios in the surface regolith and their relationships to geology and anthropogenic activity. The selected samples included 1204 NGSA Top Outlet Sediment (TOS) samples taken from 0 to 10 cm depth and sieved to <2 mm (or ‘coarse’ fraction); three of these were analysed in duplicate for a total of 1207 Pb isotope analyses. Further, 12 Northern Australia Geochemical Survey (NAGS; http://dx.doi.org/10.11636/Record.2019.002) TOS samples from within a single NGSA catchment, also sieved to <2 mm, were analysed to provide an indication of smaller scale variability. Combined, we thus present 1219 new TOS coarse, internally comparable data points, which underpin new national regolith Pb isoscapes. Additionally, 16 NGSA Bottom Outlet Sediment (BOS; ~60 to 80 cm depth) samples, also sieved to <2 mm, and 16 NGSA TOS samples sieved to a finer grainsize (<75 um, or ‘fine’) fraction from selected NGSA catchments were also included to inform on Pb mobility and residence. Lead isotope analyses were performed by Candan Desem as part of her PhD research at the School of Geography, Earth and Atmospheric Sciences, University of Melbourne. After an initial ammonium acetate (AmAc) leach, the samples were digested in aqua regia (AR). Although a small number of samples were analysed after the AmAc leach, all samples were analysed after the second, AR digestion, preparation step. The analyses were performed without prior matrix removal using a Nu Instruments Attom single collector Sector Field-Inductively Coupled Plasma-Mass Spectrometer (SF-ICP-MS). The dried soil digests were redissolved in 2% HNO3 run solutions containing high-purity thallium (1 ppb Tl) and diluted to provide ~1 ppb Pb in solution. Admixture of natural, Pb-free Tl (with a nominal 205Tl/203Tl of 2.3871) allowed for correction of instrumental mass bias effects. Concentrations of matrix elements in the diluted AR digests are estimated to be in the range of 1–2 ppm. The SF-ICP-MS was operated in wet plasma mode using a Glass Expansion cyclonic spray chamber and glass nebuliser with an uptake rate of 0.33 mL/min. The instrument was tuned for maximum sensitivity and provided ~1 million counts per second/ppb Pb while maintaining flat-topped peaks. Each analysis, performed in the Attom’s ‘deflector peak jump’ mode, consists of 30 sets of 2000 sweeps of masses 202Hg, 203Tl, 204Pb, 205Tl, 206Pb, 207Pb and 208Pb, with dwell times of 500 μs and a total analysis time of 4.5 min. Each sample acquisition was preceded by a blank determination. All corrections for baseline, sample Hg interference (202Hg/204Pb ratios were always <0.043) and mass bias were performed online, producing typical in-run precisions (2 standard errors) of ±0.047 for 206Pb/204Pb, ±0.038 for 207Pb/204Pb, ±0.095 for 208Pb/204Pb, ±0.0012 for 207Pb/206Pb and ±0.0026 for 208Pb/206Pb. A small number of samples with low Pb concentrations exhibited very low signal sizes during analysis resulting in correspondingly high analytical uncertainties. Samples producing within-run uncertainties of >1% relative (measured on the 207Pb/204Pb ratio) were discarded as being insufficiently precise to contribute meaningfully to the dataset. Data quality was monitored using interspersed analyses of Tl-doped ~1 ppb solutions of the National Institute of Standards and Technology (NIST) SRM981 Pb standard, and several silicate reference materials: United States Geological Survey ‘BCR-2’ and ‘AGV-2’, Centre de Recherches Pétrographiques et Géochimiques ‘BR’ and Japan Geological Survey ‘JB-2’. In a typical session, up to 50 unknowns plus 15 standards were analysed using an ESI SC-2 DX autosampler. Although previous studies using the Attom SF-ICP-MS used sample-standard-bracketing techniques to correct for instrumental Pb mass bias, Tl doping was found to produce precise, accurate and reproducible results. Based upon the data for the BCR-2 and AGV-2 secondary reference materials, for which we have the most analyses, deviations from accepted values (accuracy) were typically <0.17%. Data for the remaining silicate standards appear slightly less accurate but these results may, to some extent, reflect uncertainty in the assigned literature values for these materials. Replicate runs of selected AR digests yielded similar reproducibility estimates. The results show a wide range of Pb isotope ratios in the NGSA (and NAGS) TOS <2 mm fraction samples across the continent (N = 1219): 206Pb/204Pb: Min = 15.558; Med ± Robust SD = 18.844 ± 0.454; Mean ± SD = 19.047 ± 1.073; Max = 30.635 207Pb/204Pb; Min = 14.358; Med ± Robust SD = 15.687 ± 0.091; Mean ± SD = 15.720 ± 0.221; Max = 18.012 208Pb/204Pb; Min = 33.558; Med ± Robust SD = 38.989 ± 0.586; Mean ± SD = 39.116 ± 1.094; Max = 48.873 207Pb/206Pb; Min = 0.5880; Med ± Robust SD = 0.8318 ± 0.0155; Mean ± SD = 0.8270 ± 0.0314; Max = 0.9847 208Pb/206Pb; Min = 1.4149; Med ± Robust SD = 2.0665 ± 0.0263; Mean ± SD = 2.0568 ± 0.0675; Max = 2.3002 These data allow the construction of the first continental-scale regolith Pb isotope maps (206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, 207Pb/206Pb, and 208Pb/206Pb isoscapes) of Australia and can be used to understand contributions of Pb from underlying bedrock (including Pb-rich mineralisation), wind-blown dust and possibly from anthropogenic sources (industrial, transport, agriculture, residential, waste handling). The complete dataset is available to download as a comma separated values (CSV) file from Geoscience Australia's website (http://dx.doi.org/10.26186/5ea8f6fd3de64). Isoscape grids (inverse distance weighting interpolated grids with a power coefficient of 2 prepared in QGis using GDAL gridding tool based on nearest neighbours) are also provided for the five Pb isotope ratios (IDW2NN.TIF files in zipped folder). Alternatively, the new Pb isotope data can be downloaded from and viewed on the GA Portal (https://portal.ga.gov.au/).
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<div>The Australian continent comprises a broad dichotomy of crustal settings; from the Archean–Proterozoic cratonic core in the centre and west, to the accretionary margin of the Tasmanides in the east. These continental blocks meet at the Tasman Line, where successive arc systems built the eastern third of Australia in ca. 250 Myrs. This interface represents one of Australia’s most fundamental crustal boundaries and is marked by the ca. 520–490 Ma Delamerian Orogen in south-eastern Australia. Despite its first-order crustal control on tectonism, magmatism, deformation, and mineral systems in the area, the Delamerian Orogen remains poorly understood. Here, we present new zircon Hf-O isotopic and trace element data on 32 samples across the south-east Tasman Line. This initial dataset, which will grow over the next 12 months as part of Geoscience Australia’s Exploring for the Future program, will be used to constrain the time-space crustal architecture and evolution of Australia’s south-eastern Precambrian cratonic margin. These first samples include Paleoarchean to Devonian felsic magmatic rocks from the eastern Gawler Craton, across the Delamerian Orogen, to the Central Lachlan Orogen, and show that the crust of south-east Australia has a significant pre-history, with crustal reworking a major feature across the region. Delamerian arc magmatism appears to have involved significant reworking of Australia’s south-eastern Precambrian margin, as recorded by sub-chondritic Hf-isotope data. Assuming a significant mantle-component in the initial arc magmas, contamination by the ancient overlying continental rocks, some as old as ca. 3250 Ma, resulted in less juvenile compositions. This observation suggests Australia’s south-eastern Gondwanan margin may have consisted of a west-dipping continental arc, rather than an offshore island arc. The ‘heavy’ supracrustal δ18O of magmatic rocks across the area since the Paleoproterozoic is testament to the long-lived terrestrial nature of this continental margin, and its influence on magmatism across >1 billion years of Earth history. </div> This Abstract was submitted/presented to the 2022 Specialist Group in Geochemistry, Mineralogy and Petrology (SGGMP) Conference 7-11 November (https://gsasggmp.wixsite.com/home/biennial-conference-2021)
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An Isotopic Atlas of Australia (Fraser et al., 2020) provides a convenient visual overview of age and isotopic patterns reflecting geological processes that have led to the current configuration of the Australian continent, including progressive development of continental crust from the mantle. This poster provides example maps produced from compiled data of multiple geochronology and isotopic tracer datasets from this Isotopic Atlas, now publicly available and downloadable via Geoscience Australia’s (GA) Exploring for the Future (EFTF) <a href="https://portal.ga.gov.au/persona/geochronology">Geochronology and Isotopes Data Portal</a> and Mineral Resources Tasmania’s <a href="https://www.mrt.tas.gov.au/mrt_maps/app/list/map">Listmap</a>. These datasets and maps unlock the collective value of several decades of geochronological and isotopic studies conducted across Australia. Compiled geochronology, which commenced with coverage of northern Australia (Jones et al., 2018), is now much more comprehensive across Victoria (Waltenberg et al., 2021) and Tasmania (Jones et al., in press), with New South Wales and South Australia updates well underway. Available data include: Sm–Nd model ages of magmatic rocks; Lu–Hf isotopes from zircon and associated O-isotope data; Pb–Pb isotopes from ore-related minerals such as galena and pyrite; Rb–Sr isotopes from soils; U–Pb ages of magmatic, metamorphic and sedimentary rocks; and K–Ar, Ar–Ar, Re–Os, Rb–Sr and fission-track ages from minerals and whole rocks. <b>To view the associated poster see <a href="https://dx.doi.org/10.26186/147420">eCat 147420</a>. This Abstract & Poster were presented to the 2022 Specialist Group in Tectonics & Structural Geology(SGTSG) Conference 22-24 November (https://www.sgtsg.org/). </b> <i>Fraser, G.L., Waltenberg, K., Jones, S.L., Champion, D.C., Huston, D.L., Lewis, C.J., Bodorkos, S., Forster, M., Vasegh, D., Ware, B., Tessalina, S. 2020. An Isotopic Atlas of Australia. Geoscience Australia, Canberra. https://doi.org/10.11636/133772. Geoscience Australia. 2021. Geoscience Australia Exploring for the Future portal, viewed 13 September 2022. https://portal.ga.gov.au/persona/geochronology. Jones, S.L., Anderson, J.R., Fraser, G.L., Lewis, C.J., McLennan, S.M. 2018. A U-Pb Geochronology Compilation for Northern Australia: Version 2, 2018. Geoscience Australia Record 2018/49. https://doi.org/10.11636/Record.2018.049. Jones, S.L., Waltenberg, K., Ramesh, R., Cumming, G., Everard, J.L., Vicary, M.J., Bottrill, R.S., Knight, K., McNeill, A.W., Bodorkos, S., Meffre, S. in press. Isotopic Atlas of Australia: Geochronology compilation for Tasmania Version 1.0. Geoscience Australia Record. Mineral Resources Tasmania. 2022. Mineral Resources Tasmania Listmap, viewed 19 September 2022. https://www.mrt.tas.gov.au/mrt_maps/app/list/map. Waltenberg, K., Jones, S.L., Duncan, R.J., Waugh, S., Lane, J. 2021. Isotopic Atlas of Australia: Geochronology compilation for Victoria Version 1.0. Geoscience Australia Record 2021/24. https://doi.org/10.11636/Record.2021.024. </i>