Inorganic Geochemistry
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Carbon Capture and Storage (CCS) is a technique for mitigating anthropogenic climate change by separating CO2 from industrial flue gas, transporting it to and storing it in a subsurface geological storage reservoir. The low-salinity (TDS<3 000 mg/L) Jurassic sandstone formations in Australia's Surat Basin have been identified as a potential reservoir system for geological CO2 sequestration. However, given the prevailing use of saline reservoirs in CCS projects elsewhere, limited data are available on CO2-water-rock dynamics during geological sequestration in such low-salinity formations. Here, a combined batch experiment and numerical modelling approach is used to characterise potential CO2-water-rock reaction pathways, to assess potential impacts of CCS on groundwater chemistry, and to identify geochemical tracers of inter- and intra-formational CO2 migration during geological sequestration within the Jurassic sandstones. Mineralogy and physical properties of the prospective reservoir are characterized for 66 core samples from stratigraphic well GSQ Chinchilla 4. Representative samples are reacted with synthetic formation water and high-purity CO2 for up to 27 days at a range of pressures to simulate conditions during carbon sequestration in the Jurassic sandstones. Results show the low formation water salinity, temperature, and mineralization in the reservoirs yield high solubility trapping capacity (1.18 mol/L at 45°C, 100 bar), while the paucity of divalent cations in groundwater and the silicate reservoir matrix result in very low mineral trapping capacity within the footprint of the supercritical CO2 (scCO2) plume. Though alkalinity buffers formation water pH under elevated CO2 pressure, the acidic pH significantly enhances mineral dissolution in reactors with heterogeneous Hutton and Boxvale Sandstone samples. Smaller TDS changes are observed for samples of the mature Precipice Sandstone than for the other formations. Non-radiogenic, regional groundwater-like 87Sr/86Sr values (0.704845 - 0.706600) in batch reactors indicate carbonate and authigenic clay dissolution as the primary reaction pathways regulating solution composition in all formations during carbon sequestration. Slightly higher Sr isotope ratios in felsic samples than in calcitic samples, and dissolved Si concentrations in mature Precipice Sandstone reactors show detrital silicate dissolution to be an ancillary process. Batch reactor degassing at the end of the incubation period was simulated to assess geochemical changes in formation waters during transport away from a scCO2 plume. Model results suggest geological sequestration in the Jurassic sandstone formations would increase regional groundwater alkalinity and redistribute carbonate minerals outside the scCO2 footprint, but is unlikely to result in net mineral trapping of CO2. Several elements are mobilised in concentrations greater than found in regional groundwater, making them viable tracers of CO2 migration. Most notable is cobalt, concentrations of which are significantly elevated regardless of CO2 pressure or sample mineralogy. Experimental results indicate manganese and cadmium concentrations may locally exceed drinking water quality guidelines, but further modelling of intra aquifer mixing is required to quantify the potential risk to regional groundwaters from trace element mobilisation.
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<b>IMPORTANT NOTICE: </b>This web service has been deprecated. The Australian Onshore and Offshore Boreholes OGC service at https://services.ga.gov.au/gis/boreholes/ows should now be used for accessing Geoscience Australia borehole data. This is an Open Geospatial Consortium (OGC) web service providing access to a subset of Australian geoscience samples data held by Geoscience Australia. The subset currently relates specifically to Australian Boreholes.
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This database contains geochemical data for samples analysed both for inorganic and organic geochemistry. Analytical data are sourced from Geoscience Australia's Inorganic Geochemistry Database (OZCHEM) and Organic Geochemistry Database (ORGCHEM), respectively. The data are joined on a unique sample number. Inorganic geochemical data cover the majority of the periodic table, with metadata on analytical methods and detection limits. Organic geochemical data include results of pyrolysis, derivative calculated values, and, where available, isotopic composition of carbonates (D13C) and isotopic composition of rock nitrogen (D15N). Further, there are provisions for delivery of isotopic data for kerogen (H, C, N) and oxygen (O) for carbonates. Where available, sample descriptions include stratigraphic unit names and ages, and lithology. Location information includes coordinates of the sampled feature (eg, borehole), coordinates of the sample and sample depth. Interpretation of the combined inorganic and organic geochemistry for organic-rich shales will facilitate comprehensive characterisation of hydrocarbons source rocks and mineral commodities source and trap environments. All are achieved within the frameworks of petroleum and mineral systems analysis. The initial data delivered by this service include 1785 samples from 35 boreholes from 14 geological provinces, including recently released data for 442 samples from the South Nicholson National Drilling Initiative Carrara 1 stratigraphic drill hole (Butcher et al., 2021; Carson et al., 2021). Many sampled boreholes are located within the polygon of the Exploring for the Future Barkly-Isa-Georgetown project. This dataset will be updated periodically as more data become available.
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This report presents the results of an elemental and carbon and oxygen isotope chemostratigraphy study on three historic wells; Kidson-1, Willara-1 and Samphire Marsh-1, from the southern Canning Basin, Western Australia. The objective of this study was to correlate the Early to Middle Ordovician sections of the three wells to each other and to wells with existing elemental and carbonate carbon isotope chemostratigraphy data from the Broome Platform, Kidson and Willara sub-basins, and the recently drilled and fully cored stratigraphic Waukarlycarly 1 well from the Waukarlycarly Embayment.
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A comprehensive compilation of rock, regolith and groundwater geochemistry across the Curnamona Province and overlying basins. This product is part of the Curnamona Geochemistry module of GA's Exploring for the Future program, which is seeking to understand geochemical baselines within the Curnamona Province to support mineral exploration under cover. Data is sourced from GA, CSIRO and state databases, and run through a quality control process to address common database issues (such as unit errors). The data has been separated by sample type and migrated into a standard data structure to make the data internally consistent. A central source for cleaned geochemical data in the same data format is a valuable resource for further research and exploration in the region.
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As part of Geoscience Australia's Exploring for the Future program, the East Tennant region, which is centred on the Barkly Roadhouse in the Northern Territory, was identified as having favourable geological and geophysical indicators of mineral systems potential. Potentially prospective stratigraphy in the East Tennant region is completely concealed beneath Mesoproterozoic to Quaternary cover sequences. Prior to 2020 basement rocks in the East Tennant region were only known from a handful of legacy boreholes, supported by geophysical interpretation. In order to test geophysical interpretations and obtain additional samples of basement rocks for detailed analysis, a stratigraphic drilling campaign was undertaken in the East Tennant region as part of the MinEx CRC’s National Drilling Initiative. Ten stratigraphic boreholes were drilled through the cover sequences and into basement for a total of nearly 4000 m, including over 1500 m of diamond cored basement rocks to be used for scientific purposes. Inorganic geochemical samples from East Tennant National Drilling Initiative boreholes were taken to characterise cover and basement rocks intersected during drilling. Two sampling approaches were implemented based on the rocks intersected: 1) Borehole NDIBK04 contained localised sulphide mineralisation and elevated concentrations of several economically-significant elements in portable X-ray fluorescence data. In order to understand the geochemical variability and distribution of elements important for mineral system characterisation, the entire basement interval was sampled at nominal one metre intervals. This spacing was reduced to between 0.5 and 0.25 m from 237 m to 263 m to better understand a more intense zone of mineralisation, and 2) Samples from boreholes NDIBK01, NDIBK02, NDIBK03, NDIBK05, NDIBK06, NDIBK07, NDIBK08, NDIBK09 and NDIBK10 were selected to capture lithological and geochemical variability to establish bulk rock geochemical compositions for further interpretation. Attempts were made to sample representative, lithologically consistent intervals. A total of 402 samples were selected for analysis. Sample preparation was completed at Geoscience Australia and Bureau Veritas, with all analyses performed by Bureau Veritas in Perth. All samples were submitted for X-ray fluorescence (XRF), laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), FeO determination, and loss on ignition (LOI). Samples from borehole NDIBK04 also underwent total combustion C and S, and Pb collection fire assay by ICP-MS for determination of Au, Pt and Pd concentrations. This data release presents inorganic geochemistry data acquired on rock samples from the ten East Tennant National Drilling Initiative boreholes.
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Paleoproterozoic arc and backarc assemblages accreted to the south Laurentian margin between 1800 Ma and 1600 Ma, and previously thought to be indigenous to North America, more likely represent fragments of a dismembered marginal sea developed outboard of the formerly opposing Australian-Antarctic plate. Fugitive elements of this arc-backarc system in North America share a common geological record with their left-behind Australia-Antarctic counterparts, including discrete peaks in tectonic and/or magmatic activity at 1780 Ma, 1760 Ma, 1740 Ma, 1710-1705 Ma, 1690-1670 Ma, 1650 Ma and 1620 Ma. Subduction rollback, ocean basin closure and the arrival of Laurentia at the Australian-Antarctic convergent margin first led to arc-continent collision at 1650-1640 Ma and then continent-continent collision by 1620 Ma as the last vestiges of the backarc basin collapsed. Collision induced obduction and transfer of the arc and more outboard parts of the Australian-Antarctic backarc basin onto the Laurentian margin where they remained following later breakup of the Neoproterozoic Rodinia supercontinent. North American felsic rocks generally yield Nd depleted mantle model ages consistent with arc and backarc assemblages built on early Paleoproterozoic Australian crust as opposed to older Archean basement making up the now underlying Wyoming and Superior cratons. Appeared in Lithosphere (2019) 11 (4): 551–559, June 10, 2019.
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Hydrochemistry data for Australian groundwater, including field and laboratory measurements of chemical parameters (electrical conductivity (EC), potential of hydrogen (pH), redox potential, and dissolved oxygen), major and minor ions, trace elements, nutrients, pesticides, isotopes and organic chemicals. < <b>Value: </b>The chemical properties of groundwater are key parameters to understand groundwater systems and their functions. Groundwater chemistry information includes the ionic and isotopic composition of the water, representing the gases and solids that are dissolved in it. Hydrochemistry data is used to understand the source, flow, and interactions of groundwater samples with surface water and geological units, providing insight into aquifer characteristics. Hydrochemistry information is key to determining the quality of groundwater resources for societal, agricultural, industrial and environmental applications. Insights from hydrochemical analyses can be used to assess a groundwater resource, the impact of land use changes, irrigation and groundwater extraction on regional groundwater quality and quantity, assess prospective mineral exploration targets, and determine how groundwater interacts with surface water in streams and lakes. <b>Scope: </b>The database was inaugurated in 2016 with hydrochemical data collected over the Australian landmass by Geoscience Australia and its predecessors, and has expanded with regional and national data. It has been in the custodianship of the hydrochemists in Geoscience Australia's Minerals, Energy and Groundwater Division and its predecessors. Explore the <b>Geoscience Australia portal - https://portal.ga.gov.au/</b>
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<b> Legacy service retired 29/11/2022</b> This is an Open Geospatial Consortium (OGC) web service providing access to Australian onshore and offshore borehole data conforming to the GeoSciML version 4.0 specification. The borehole data includes Mineral Drillholes, Petroleum Wells and Water Bores along with a variety of others types. The dataset has been restricted to onshore and offshore Australian boreholes, and bores that have the potential to support geological investigations and assessment of a variety of resources.
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<div>The Exploring for the Future (EFTF) program is an Australian government initiative aimed at stimulating investment in resource exploration and development. It operates multiple interconnected projects, such as the Australia’s Resources Framework (ARF), a continental-scale endeavor to enhance understanding of Australia's geology and resource potential. A module of ARF, the Geochemistry for Basin Prospectivity (G4BP), studies Australian basins with prospective base metal mineral systems. </div><div><br></div><div>The current report focuses on the Neoproterozoic segment of the Stuart Shelf region in South Australia, a part of the Adelaide Rift Complex. This research is conducted collaboratively with the Geological Survey of South Australia, examining sediment-hosted copper potential in the rift complex.</div><div><br></div><div>The Adelaide Rift Complex is a geological formation that underwent extensive sedimentation from the Neoproterozoic to early Cambrian, particularly within the rift zone. Stuart Shelf sediments overlay Mesoproterozoic magmatic and Paleoproterozoic metasediment layers. The complex hosts multiple copper deposits, which are usually associated with movement of basinal brines that leach metals from lower basinal layers or rift-related volcanic rocks.</div><div><br></div><div>To improve understanding of the geology of the Stuart Shelf and related copper mineralisation, two primary objectives were set: </div><div><br></div><div>1. Geochemical fingerprinting and baseline data collection: This involves compilation and reanalysis of existing data, along with new data collection aimed at providing comprehensive geochemical data for stratigraphic units within the Stuart Shelf.</div><div><br></div><div>2. Identification of mineral system components: Utilising data from the first objective, this phase aims to identify potential metal and fluid sources and potential sites of metal deposition. </div><div>In conjunction with these efforts, a GA-GSSA geochemical sampling project is underway, tying geochemistry to lithostratigraphic units and facies. The newly acquired geochemical data will be integrated into the overall GSSA-CSIRO project to contribute to a more comprehensive understanding of the sediment-hosted stratabound mineral system.</div><div><br></div>